Intercalibration of Solar Soft X-Ray Broad Band Measurements from SOLRAD 9 through GOES-12

The two-band soft X-ray observations of solar flares made by the Naval Research Laboratory’s (NRL) SOLar RADiation (SOLRAD) satellites and by the Geostationary Orbiting Environmental Satellites (GOES) operated by the National Oceanic and Atmospheric Administration’s (NOAA) Space Weather Prediction Center have produced a nearly continuous record of solar flare observations over a period of more than forty years (1969 – 2011). However, early GOES observations (i.e., GOES-2) and later (GOES-8 and subsequent missions) are not directly comparable due to changes in the conversion of measured currents to integrated fluxes in the two spectral bands that were adopted: 0.05 – 0.3 (or 0.4) nm, which we refer to as XS and 0.1 – 0.8 nm (XL). Furthermore, additional flux adjustments, using overlapping data sets, were imposed to provide consistency of flare-flux levels from mission to mission. This article evaluates the results of these changes and compares experimental GOES-8/GOES-2 results with changes predicted from modeled flare spectra. The factors by which recent GOES observations can be matched to GOES-2 are then optimized by adapting a technique first used to extrapolate GOES X-ray fluxes above saturation using ionospheric VLF radio phase enhancements. A nearly 20% increase in published GOES-8 XL data would be required to match to GOES-2 XL fluxes, which were based on observed flare spectra. On the other hand, a factor of 1.07 would match GOES-8 and later flat-spectrum 0.1 – 0.8 nm fluxes to GOES-2 XL if the latter data were converted to a flat-spectrum basis. Finally, GOES-8 observations are compared to solar soft X-ray estimates made concurrently with other techniques. Published GOES-8 0.1 – 0.8 nm fluxes are found to be 0.59 of the mean of these other determinations. Rescaling GOES to a realistic flare spectrum and removing a 30% downward adjustment applied to the GOES-8 measurements during initial data processing would place GOES-8 and later GOES XL fluxes at 0.94 of this XL mean. GOES-2 on the same scale would lie at about 0.70 of this mean. Significant uncertainties in the absolute levels of broad band soft X-ray fluxes still remain, however.     

Emulating the OPAL equation of state

The equation of state for the structure of the Sun and stars has to be precise to allow comparisons with observations, i.e., helioseismic inversions of thermodynamic quantities. Among the two of the most popular formalisms are (1) the OPAL equation of state developed at Livermore and (2) the Mihalas-Hummer-Däppen (MHD) equation of state. While OPAL has a solid theoretical foundation, and matches the observational data better, the MHD formalism is more intuitive, easy to realize, and has the possibility of adjustable parameters. Furthermore, it an open-source product in contrast to the proprietary OPAL. Recently a version of MHD has been obtained by including the so-called “Plank-Larkin partition function” and by adding scattering-state terms. The resulting formalism matches OPAL rather well. Here, we report on the next logical step, the implementation of this MHD upgrade into the simple and popular CEFF equation of state. Such an implementation will make it a flexible and convenient tool, allowing an approximative on-line implementation of OPAL in solar and stellar models.     

EC 11481–2303—a peculiar subdwarf OB star revisited

EC?11481–2303 is a peculiar, hot, high-gravity pre-white dwarf. Previous optical spectroscopy revealed that it is a sdOB star with T _eff=41?790 K, log?g=5.84, and He/H = 0.014 by number. We present an on-going spectral analysis by means of non-LTE model-atmosphere techniques based on high-resolution, high-S/N optical (VLT-UVES) and ultraviolet (FUSE, IUE) observations.We are able to reproduce the optical and UV observations simultaneously with a chemically homogeneous NLTE model atmosphere with a significantly higher effective temperature and lower He abundance (T _eff=55?000 K, log?g=5.8, and He/H=0.0025 by number). While C, N, and O appear less than 0.15 times solar, the iron-group abundance is strongly enhanced by at least a factor of ten.     

Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.     

Devitrite (Na2Ca3Si6O16)—structural, spectroscopic and computational investigations on a crystalline impurity phase in industrial soda-lime glasses

Single crystals of devitrite (Na₂Ca₃Si₆O₁₆) were synthesized as pale-yellow transparent needle shaped crystals using a Na₂MoO₄-flux. Experiments aiming to prepare the K-equivalent of devitrite from the corresponding K₂MoO₄-flux were unsuccessful. The crystal structure of devitrite was determined from single-crystal X-ray diffraction data (Mo-K_α radiation, 2θ_max.?=?25.34°, R_int?=?2.66%) and refined in space group P $ \bar{1} $ (no. 2) to R(|F|)?=?3.08% using 2,513 observed reflections with I?>?2σ(I). Unit-cell parameters are: a?=?7.2291(8), b?=?10.1728(12), c?=?10.6727(12) Å, α?=?95.669(9), β?=?109.792(10), γ?=?99.156(9)°, V?=?719.19(14) ų, Z?=?2. The structure belongs to the group of multiple chain silicates consisting of dreier quadruple chains, i.e. the crystallochemical formula can be written as $ {\hbox{N}}{{\hbox{a}}_2}{\hbox{C}}{{\hbox{a}}_3}\left\{ {{\mathbf{uB}}{,4}_\infty^1} \right\}\left[ {^3{\hbox{S}}{{\hbox{i}}_6}} \right.\left. {{{\hbox{O}}_{16}}} \right\} $ . Linkage between the bands running along [100] is provided by double chains of edge sharing CaO₆-octahedra as well as additional more irregularly coordinated Na- and Ca-cations located in the tunnel-like cavities of the mixed tetrahedral-octahedral framework. Structural investigations were completed by Raman and infrared spectroscopical studies. The allocation of the bands to certain vibrational species was aided by density functional theory (DFT) calculations.     

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.     

Sedimentary pigments as indicators of cyanobacterial dynamics in a hypereutrophic lake

Lac Saint-Augustin is an urban lake located on the outskirts of Quebec City, one of North America’s oldest cities. Anthropogenic inputs from land clearing, agriculture, highway development and urbanization in the surrounding catchment have resulted in strong impacts on the limnology of the lake throughout the past three centuries. In recent years, this lake has experienced severe eutrophication, including persistent cyanobacterial blooms. In winter 2011, a sediment core was extracted from the deepest area of the lake. A detailed paleopigment analysis was used to assess eutrophication processes in the lake and to determine the timing and appearance of cyanobacterial blooms and their subsequent variability. Extracted chlorophyll a, its degradation products and 11 carotenoid pigments were identified and quantified via reverse-phase high performance liquid chromatography to examine relative changes in the phytoplankton. The results revealed large variations in the phytoplankton community structure of Lac Saint-Augustin over the past 356 years. Chlorophyll a concentrations per unit organic matter (OM) increased significantly from the base of the core to present day, rising more than 15-fold from 18.4 µg (g OM)^?1 at the base of the core to 287 µg (g OM)^?1 in the most recent strata. Biostratigraphical analysis revealed three major periods of enrichment, with episodes of cyanobacterial abundance from the 1890s onwards. The greatest changes occurred in the most recent period (from the 1960s to the present) relative to earlier periods, with pigment increases for all phytoplankton groups. The cyanobacterial pigments canthaxanthin, echinenone and zeaxanthin (also a marker for green algae) showed concentrations in the surface sediments that were significantly above values at the bottom of the core, and these differences were large, even giving consideration to the lesser pigment degradation near the surface. Overall, the results indicate that cyanobacterial blooms are not a recent feature of Lac Saint-Augustin but began to occur soon after catchment modification 150 years ago. The pigment records also imply that cyanobacterial and associated algal populations have risen to unprecedented levels over the last few decades of ongoing development of the Lac Saint-Augustin catchment. This study highlights the utility of multiple pigment analysis of lake sediments for identifying the timing and magnitude of anthropogenic impacts.     

Hydrochemistry and hydrogen sulfide generating processes in the Malm aquifer,Bavarian Molasse Basin,Germany

Knowledge about the hydrochemical conditions of deep groundwater is crucial for the design and operation of geothermal facilities. In this study, the hydrochemical heterogeneity of the groundwaters in the Malm aquifer, Germany, is assessed, and reasons for the extraordinarily high H₂S concentrations in the central part of the Bavarian Molasse Basin are proposed. Samples were taken at 16 sites, for a total of 37 individual wells, to analyze cations, anions, gas loading and composition. The hydrochemical characteristics of the Malm groundwater in the center of the Molasse Basin are rather heterogeneous. Although the groundwater in the central basin is dominated by meteoric waters, there is a significant infiltration of saline water from higher strata. Care has to be taken in the interpretation of data from geothermal sites, as effects of chemical stimulation of the boreholes may not be fully removed before the final analyses. The distribution of H₂S in the gas phase is correlated to the gas loading of the water which increases in the central basin. Temperatures, isotopic data and the sulfur mass balance indicate that H₂S in the central basin is related to thermochemical sulfate reduction (south of Munich) and bacterial sulfate reduction (north of Munich).     

A new physically based stochastic event catalog for hail in Europe

Hailstorms represent one of the major sources of damage and insurance loss to residential, commercial, and agricultural assets in several parts of Central Europe. However, there is little knowledge of hail risk across Europe beyond local historical damage reports due to the relative rarity of severe hail events and the lack of uniform detection methods. Here we present a new stochastic catalog of hailstorms for Europe. It is based on satellite observations of overshooting cloud tops (OT) that indicate very strong convective updrafts and hail reports from the European Severe Weather Database (ESWD). Historic hail events are defined based on OT detections from satellite infrared brightness temperatures between 2004 and 2011 for the warm seasons (April–September). The satellite-based historical event properties are complemented by hailstone observations from ESWD to stochastically simulate more than 1 million individual events with an event footprint resolution of 10 km. The final hail event catalog presented in this paper is the first one with a spatial event distribution that is based on a single homogeneous observation source over Europe. Areas of high hail probability or hail risk are found over Central and Southern Europe, including mountainous regions such as the Alps or the Pyrenees. Another region of relatively high hail risk is present over central Eastern Europe.