A new bathymetric model for the central Fram Strait

Based on data from R/V Polarstern multibeam sonar surveys between 1984 and 1997 high resolution bathymetry has been generated for the central Fram Strait. The area insonified covers approx. 36,500 km² between 78–80°N and 0–7.5°E allowing the creation of a Digital Terrain Model (DTM) with 100 m grid spacing. The DTM was utilized for contouring and generation of a new series of bathymetric charts (AWI Bathymetric Charts of the Fram Strait, AWI BCFS) at a scale of 1:100,000. The paper starts with a brief introduction to the regional setting of the study area comprising information on the local links between bathymetry, sea ice transport and water mass exchange. The bathymetric feature names used in this article and how they were chosen is outlined. Next, the input data and processing applied are described. Thereafter the newly created grid and contour data are put into context with existing data sets. Finally the main bathymetric features of the area are characterized and the generated data products available for public disposal are specified.     

Continental slope sedimentation adjacent to an ice margin I. Seismic facies of Labrador Slope

Sleeve-gun, 3.5-kHz, and 12-kHz profiles from the Labrador Slope provide the basis for an analysis of sedimentary facies, processes, and evolution of a continental slope adjacent to an ice margin. The upper slope is deeply incised by numerous canyons reflecting headward canyon branching. The less rugged middle-slope topography has fewer canyons and large slide and slump scars followed downslope by debris-flow deposits. Echo character of seismic profiles reflects the difference in sediment types supplied from mud-dominated sources and sand-, gravel- and till-dominated sources. On the rise, debris-flow deposits are largely confined to canyons. Intercanyon areas are dominated by spill-over turbidites alternating with hemipelagic sediments, which on some of the southern to southwestern levees occur in sediment-wave fields formerly attributed to bottom-current activity.     

Kinetics of redox cycling of iron coupled with fulvic acid

The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10^–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > Fe^III-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)₃(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity.     

Site occupation and electric field gradient in acentric neptunite-measurements and evaluations concerning powder- and single crystal – Mössbauer spectroscopy and x-ray diffractometry

Mössbauer measurements on neptunite (KNa₂Li(Fe,Mn,Mg)₂Ti₂Si₈O₂₄) at 400?K reveal the distribution of Fe-ions on the crystallographic sites in agreement with neutron diffraction results published elsewhere. Even the previously postulated small amount of Fe-ions on the Ti(2) site has been detected, combined with a charge transfer which is in agreement with optical absorption investigations by other authors. A qualitative site occupation model is able to explain the different features of our observations. Single crystal Mössbauer measurements with the k-vector of incident γ-rays parallel to the crystallographic b-axis (space group Cc) of neptunite at different temperatures yield the angle β between the main component of the electric field gradient (EFG), V _zz and b. This angle is in close accordance with a calculated value of β for the Fe(1) position from electron density maps. The latter also reveal an absolute value of V _zz which is in satisfactory agreement with V _zz derived from Mössbauer spectroscopy.     

Phosphine absorption in the 5-μm window of Jupiter

Since the original suggestion by Gillett et al. (1969) it has generally been assumed that the region of partial transparency near 5 μm in Jupiter's atmosphere (the 5-μm window) is bounded by the v₄ NH₃ at 6.1 μm and the v₃ CH₄ band at 3.3 μm. New measurements of Jupiter and of laboratory phosphine (PH₃) samples show that PH₃ is a significant contributor to the continuum opacity in the window and in fact defines its short-wavelength limit. This has important implications for the use of 5-mu;m observations as a means to probe the deep atmospheric structure of Jupiter. The abundance of PH₃ which results from a comparison of Jovian and laboratory spectra is about 3 to 5 cm-am. This is five to eight times less than that found by Larson et al. [Astrophys. J. (1977) 211, 972–979] in the same spectral region, but is in good agreement with the result of Tokunaga et al. [Astrophys. J. (1979) 232, 603–615] from 10-μm observations.     

Über Den Aufbau Der Stern- Und Galaxienhaufen

In star clusters and in galaxy clusters the exponentn of the generalized law of Schuster statistically decreases with increasing masses of the clusters or increasing numbersL of their members. In most casesn(gal. cl.) is smaller thann(st. cl.). It is confirmed, that in larger galaxy clusters the brighter members are somewhat more concentrated at the center than the fainter members.

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Mitteilungen Serie A.     

Coherence analysis of granular intensity

A high resolution spectrogram of the Mg b₂ line from the quiet Sun disc centre is subjected to a coherence analysis. We find that the coherence between intensity fluctuations in the continuum and the wings of the line breaks down at a distance = 0.35 Å from line centre. From this and the r.m.s. intensity contrast as a function of we are led to the following simple model of temperature fluctuation T in the solar photosphere: A lower part (below 50 km, or ₅₀₀₀ > 0.25) with strongly inward increasing T and an upper part (above 50 km) with constant T = 75 K. The two parts are supposed to fluctuate incoherently.Mitteilungen aus dem Kiepenheuer Institut Nr. 166.     

Coalification and thermal histories of Tertiary basins in relation to late Alpidic evolution of the Eastern Alps

The thermal histories of Tertiary basins situated around and within the Eastern Alps are examined using coalification data.Waples' method is used to estimate paleogeothermal conditions. The data suggest that the basins' thermal histories are intimately related to late Alpidic geodynamics of the Eastern Alps.Basins situated near the thrust front (Eastern Alpine foredeep, Vienna basin) are characterized by hypothermal histories and low coalification gradients. This is a consequence of relatively thick crust, high paleosedimentation rates in the Alpine foredeep, and Oligocene to Early Miocene stacking of cool sediments along the southern margin of the Eastern Alpine foredeep. Extension in the Vienna basin region is restricted mainly to shallow crustal levels and did not change the thermal pattern beneath the Alpine nappes. Major hyperthermal events of Oligocene age and local coalification maxima in the central Slovenian basin date from magmatic activity along the Periadriatic lineament, caused by Oligocene subduction. In Miocene times subduction migrated eastward and magmatic activity shifted to the northern Slovenian and Styrian basins, resulting in a strong hyperthermal phase of Ottnangian to Lower Badenian age in these basins.Rapid uplift of the Tauern window in the central part of the Eastern Alps, due to buoyancy, is related to E-W directed crustal stretching and resulted in raised heat flow in Miocene times in the Tauern window region, and in relatively high rank in adjacent Tertiary basins (Wagrain, Tamsweg).Present geothermal patterns are controlled primarily by raised heat flow along the south-eastern margin of the Alps, a consequence of thinned crust beneath the Pannonian basin.

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Zusammenfassung Die Inkohlungsbilder von tertiären Sedimentbecken, die im Bereich der Ostalpen situiert sind, werden hinsichtlich der thermischen Geschichte diskutiert. In einigen Becken erfolgt eine Abschätzung der paläogeothermischen Verhältnisse mit Hilfe derWaples-Methode. Die Inkohlungsbilder der Tertiärbecken belegen eine enge Beziehung zwischen der thermischen Geschichte dieser Becken und der jungalpidischen Geodynamik der Ostalpen.In der Nähe der Überschiebungsfront gelegene Becken (Molassebecken, Wiener Becken) werden durch hypothermische Verhältnisse und geringe Inkohlung charakterisiert. Dies ist eine Folge relativ dicker Kruste, hoher Paläo-Sedimentationsraten in der alpinen Vortiefe und des Übereinanderstapelns kühler Sedimente am Südrand des Molassebeckens während Oligozän und frühem Miozän. Die Extension im Wiener Becken war auf den obersten Krustenabschnitt beschränkt und hat die thermischen Verhältnisse unterhalb der alpinen Decken nicht beeinflußt.Die magmatische Aktivität entlang der Periadriatischen Naht steht in Zusammenhang mit der oligozänen Subduktion und ist für hyperthermische Ereignisse und lokale Inkohlungsmaxima in oligozänen Sedimenten des zentralen Slowenischen Beckens verantwortlich. Im Miozän wanderte die Subduktion ostwärts und die magmatische Aktivität verlagerte sich in das nördliche Slowenische und Steirische Becken. Dadurch wurde in diesen Becken eine starke hyperthermische Phase während Ottnang bis Unterbaden initiiert.Der rasche isostatische Aufstieg des Tauernfensters in den zentralen Ostalpen steht mit miozäner, E-W gerichteter Dehnungstektonik in Zusammenhang. Er ist für erhöhten Wärmefluß im Miozän im Bereich des Tauernfensters und für die relativ hohe Inkohlung des Wagrainer und Tamsweger Beckens verantwortlich.Die heutigen geothermischen Verhältnisse werden vor allem durch erhöhten Wärmefluß am Südostrand der Alpen geprägt. Dieser ist eine Folge der Krustenausdünnung unter dem Pannonischen Becken.

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Résumé La houillification des bassins sédimentaires tertiaires des Alpes orientales est discutée dans la perspective de leur histoire thermique. Les conditions paléogéothermiques sont estimées au moyen de la méthode deWaples. L'étude de la houillification de ces bassins montre une relation étroite entre leur histoire thermique et la géodynamique des Alpes orientales à la fin du Tertiaire.Ces bassins, situés à proximité du front de charriage — il sagit du Bassin molassique et du Bassin viennois —, se caractérisent par leur condition «hypothermique» et leur faible gradient de houillification; cette propriété provient de l'épaississement de la croute terrestre due à une sédimentation rapide en avant des Alpes et à l'empilement tectonique des sédiments froids les uns sur les autres le long de la bordure méridionale du Bassin molassique au cours de l'Oligocène et du Miocène inférieur. L'extension, dans la région du Bassin viennois, s'est limitée à un niveau crustal peu profond et n'a pas influencé la situation thermique dans les nappes alpines.L'activité magmatique le long du linéament périadriatique, due à la subduction oligocène, est contemporaine des événements «hyperthermiques» et des maxima locaux de houillification dans les sédiments oligocènes du bassin central de Slovénie.Pendant le Miocène, la subduction progressa vers l'est et l'activité magmatique se déplaça vers les bassins de Slovénie septentrionale et de Styrie, avec comme conséquence, dans ces bassins, une phase «hyperthermique» marquée à l'Ottnangien et au Badenien inférieur.La montée isostatique rapide de la Fenêtre des Tauern dans la partie centrale des Alpes orientales est en relation avec l'extension tectonique est-ouest au Miocène; elle est responsable d'un flux thermique élevé dans la région de la Fenêtre et d'une houillification relativement importante dans les bassins tertiaires adjacents de Wagrain et de Tamsweg.La géothermie actuelle de la bordure sud-est des Alpes est régie par un flux thermique élevé, conséquence de l'amincissement crustal sous le bassin Pannonique.

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Seasonal Diatom Variability and Paleolimnological Inferences – A Case Study

The seasonality of physical, chemical, and biological water variables is a major characteristic of temperate, dimictic lakes. Yet, few investigations have considered the potential information that is encoded in seasonal dynamics with respect to the paleolimnological record. We used a one-year sequence of diatoms obtained from sediment traps and water samples, as well as the sedimentary diatom record covering the past ca. 1000 years in Bates Pond, Connecticut (USA), to investigate which variables influence the seasonal distribution of diatoms and how this can be used for the interpretation of the fossil record. The seasonal patterns in diatom assemblages were related to stratification and, to a lesser extent, to nitrate, silica, and phosphorus. During mixing periods in spring and autumn, both planktonic and benthic species were collected in the traps, while few lightly silicified, spindle-shaped planktonic diatoms dominated during thermal stratification in summer. Changes in fossil diatom assemblages reflected human activity in the watershed after European settlement and subsequent recovery in the 20th century. A long-term trend in diatom assemblage change initiated before European settlement was probably related to increased length of mixing periods during the Little Ice Age, indicated by the increase of taxa that presently grow during mixing periods and by application of a preliminary seasonal temperature model. We argue that the analysis of seasonal diatom dynamics in temperate lakes may provide important information for the refinement of paleolimnological interpretations. However, investigations of several lakes and years would be desirable in order to establish a more robust seasonal data set for the enhancement of paleolimnological interpretations.