Occurrence and distribution of “moganite” in agate/chalcedony: a combined micro-Raman, Rietveld, and cathodoluminescence study

Agate/chalcedony samples of different origin were investigated by performing Raman, X-ray diffraction (using Rietveld refinement), and cathodoluminescence measurements. These analyses were performed to measure the content and spatial distribution of the silica polymorph moganite, which is considered to represent periodic Brazil-law twinning of α-quartz at the unit-cell scale in agate/chalcedonies. Homogeneous standard samples including the nearly α-quartz free moganite type material from Gran Canaria were analysed in order to compare results of the X-ray diffractometry and Raman spectroscopy techniques and to provide a calibration curve for the Raman results. However, due to the different length scales analysed by the two techniques, the “moganite content” in microcrystalline SiO₂ samples measured by Raman spectroscopy (short-range order) was found to be considerably higher than the “moganite content” measured by X-ray diffractometry (long-range order). The difference is explained by the presence of moganite nanocrystals, nano-range moganite lamellae, and single Brazil-law twin-planes that are detected by vibrational spectroscopy but that are not large enough (in the sense of coherently scattering lattice domains) to be detected by X-ray diffractometry. High resolution Raman analysis provides a measure of the moganite content and its spatial variation in microcrystalline silica samples with a lateral resolution in the μm-range. Variations in the moganite-to-quartz ratio are revealed by varying intensity ratios of the main symmetric stretching-bending vibrations (A₁ modes) of α-quartz (465 cm⁻¹) and moganite (502 cm⁻¹), respectively. Traces of Raman microprobe analyses perpendicular to the rhythmic zoning of agates revealed that the moganite-to-quartz ratio is often not uniform but shows a cyclic pattern that correlates with the observed cathodoluminescence pattern (colour and intensity). Data obtained from an agate sample from a fluorite deposit near Okorusu, Namibia and from a volcanic agate from Los Indios, Cuba were selected for detailed presentation. Variations of cathodoluminescence and Raman data between single bands in agates suggest alternating formation of fine-grained, highly defective chalcedony intergrown with moganite, and coarse-grained low-defect quartz. Multiple zones indicate dynamic internal growth during a self-organizational crystallization process from silica-rich fluids. Received: 4 December 1997 / Accepted 19 June 1998     

The metamorphic evolution of migmatites from the Ötztal Complex (Tyrol,Austria) and constraints on the timing of the pre-Variscan high-T event in the Eastern Alps

Within the Ötztal Complex (ÖC), migmatites are the only geological evidence of the pre-Variscan metamorphic evolution, which led to the occurrence of partial anatexis in different areas of the complex. We investigated migmatites from three localities in the ÖC, the Winnebach migmatite in the central part and the Verpeil- and Nauderer Gaisloch migmatite in the western part. We determined metamorphic stages using textural relations and electron microprobe analyses. Furthermore, chemical microprobe ages of monazites were obtained in order to associate the inferred stages of mineral growth to metamorphic events. All three migmatites show evidence for a polymetamorphic evolution (pre-Variscan, Variscan) and only the Winnebach migmatite shows evidence for a P-accentuated Eo-Alpine metamorphic overprint in the central ÖC. The P-T data range from 670–750 °C and < 2.8 kbar for the pre-Variscan event, 550–650 °C and 4–7 kbar for the Variscan event and 430–490 °C and ca. 8.5 kbar for the P-accentuated Eo-Alpine metamorphic overprint. U-Th-Pb electron microprobe dating of monazites from the leucosomes from all three migmatites provides an average age of 441 ± 18 Ma, thus indicating a pervasive Ordovician-Silurian metamorphic event in the ÖC.     

Geophysical investigation of buried Pleistocene subglacial valleys in Northern Germany

Buried Pleistocene subglacial valleys are extensively used as groundwater reservoirs by waterworks in northern Germany, although little is known about the locations and size of these valleys and the internal structure of the sediment fill. This lack of knowledge about important groundwater reservoirs is a challenge for geophysics.This paper summarizes the geophysical investigation of two buried Pleistocene subglacial valleys in northern Germany—the Ellerbeker Rinne and the Bremerhaven–Cuxhavener Rinne—including seismic, gravity, and airborne electromagnetic (AEM) surveys. Seismic sections show the detailed structure of the paleovalleys. The reliability of interpretation is enhanced by vertical seismic profiles in wells. The maximum depths of the Ellerbeker Rinne and the Bremerhaven–Cuxhavener Rinne were found to be 360 and about 400 m, respectively. Gravity survey revealed Bouguer anomalies above the sediment fill of both buried valleys. The Ellerbeker Rinne produces a negative residual anomaly of −0.5 mGal, whereas the sediments of the Bremerhaven–Cuxhavener Rinne produce a positive anomaly. The latter one is superimposed by negative gravity anomalies due to near-surface structures. The Bremerhaven–Cuxhavener Rinne can be mapped by airborne electromagnetics at locations without saltwater intrusion, which would affect the measurements. The electrical conductivity of the clay layer at the top of the valley fill differs significantly from that of the surrounding sand. The combined use of these three geophysical methods, which measure different physical parameters, leads to a better understanding of the subsurface geology and the hydrogeology of the Pleistocene subglacial valleys.     

Asymmetrical turbid surface-plume deposition near ice-outlets of the Pleistocene Laurentide ice sheet in the Labrador Sea

 Ice-sheet drainage of glacial detritus into the sea involves size fractionation by ice-margin winnowing on a giant scale caused by the lower density of meltwater entering cold seawater. Despite its load of suspended sediment, the fresh water rises to or stays at the sea surface forming turbid surface plumes, whereas the coarse-grained sediment forms bed load. On the Labrador Slope south of the Hudson Strait turbid plumes were supplied by meltwater from the Pleistocene ice sheet (LIS). Sediments with the seismic characteristics of plume deposits occur in a 200-km-long slope sector up to 130 km seawards from the strait. The widespread distribution of these deposits is attributed to entrainment of the surface plumes by the south-flowing Labrador Current and suppressed flocculation due to the high detrital carbonate-content of the suspended sediment. Deposits with typical characteristics of surface plume deposits have been recovered within 20 km from former ice margin south of or in front of outlets, but not north of outlets. They consist of 1 to 2-cm-thick alternations of fine sandy silt/coarse silt layers with finer-grained clayey silt/silty clay, and for brevity are called plumites. Received: 6 August 1996/Revision received: 21 January 1997     

10 μm imaging of the nucleus of NGC 1068: The bell tolls for parsec-scale tori?

The potential of mid-infrared imaging, at a resolution of 0.5 or better, as a powerful tool in unravelling the complex environments in the vicinity of active galactic nuclei is discussed in the light of new data on the Seyfert nucleus in NGC 1068. In particular, we examine the growing body of evidence that the extinction of the broad-line region in NGC 1068 has its origins in an extended molecular disk and is the result of obscuration at 100 pc from the AGN.     

Taking stock of Climate Change Acts in Europe: living policy processes or symbolic gestures?

Since the UK introduced a Climate Change Act (CCA) in 2008, similar legislation has followed in a number of states, with each having a slightly different take. What unites these examples is that they all represent framework legislation that aims to facilitate climate change mitigation by creating continuous policy processes whereby mechanisms for the reduction of greenhouse gas (GHG) emissions are developed and implemented. This article is concerned with the extent to which they are living policy processes or rather symbolic gestures. We analyse seven European CCAs with regard to GHG emission reduction targets, planning/implementation mechanisms, and feedback/evaluations prescribed by the laws. These three features correspond with three aspects of climate policy integration (CPI): interpretations of CPI as a norm; CPI as a process of governing; CPI as a policy outcome. We show that CCAs address all three aspects of CPI and constitute living policy processes, although to varying extents. However, CCAs are also policy processes in that they are part of a political system, affected by political forces external to the legislation, positively and negatively.

Key policy insights

• CCAs can provide a normative basis for policymaking on climate change at the national level, especially through quantitative emission reduction targets.

• Whilst CCAs can bring some stability and predictability to policymaking on climate change (mainly because legislation is more difficult to amend or remove than policy strategies), they are still vulnerable to political developments.

• Most CCAs lack either short/medium-term (Denmark, Finland, Ireland, Sweden) or long-term (Austria) targets. Given EU Member States’ aim to decarbonise in the next three decades and the Paris Agreement's global goal of pursuing efforts to limit warming to 1.5°C, states need to find ways to guide this process. One approach could be the inclusion of short-term, medium-term and long-term targets in their CCAs.

• Since sanctioning mechanisms are lacking across all the CCAs analysed here, it is not clear what will happen if legally binding targets are not met. Just as it is difficult to imagine speed limits and speed cameras without accompanying penalties, it is hard to imagine how CCAs without sanctions can deliver decarbonization.

     

Urban development in East Germany — specific features of urban transformation processes

The aim of this paper is to analyse the main characteristics of post-socialist urban development in East Germany, especially the differences compared to urban development in other East and Central European countries. In spite of the many similar problems and processes in urban development, specific features of East Germany are characterised by the rapid growth of suburbia, especially in the first phase of transition, by the proceeding activities of urban renewal and revitalisation, and by a lower level of social polarisation and socio-spatial segregation as compared to other post-socialist countries. Important conditions for urban development in East Germany exist in special support programmes, high subsidies and other financial transfers as well as in engaged planning conceptions of the local authorities. This revised version was published online in July 2006 with corrections to the Cover Date.     

Statistical Investigations of Earthquake Swarms within the Vogtland/NW-Bohemian Area

The microseismicity of the Vogtland/NW-Bohemian region has been continually recorded since 1962. Earthquakes mostly occur in single clusters as swarms. The long-term data set has been analysed by statistical methods dividing the whole seismic region into significant clusters. The b-value and fractal dimension D of epicentre distribution, as well as the distribution of times between events for particular swarms has been determined for each cluster to find the parameters characteristic for swarm-like occurrence. The correlation between b and D is discussed with a view to the changing data quality of location and magnitude calculation.