How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.     

Effects of climate change on snow accumulation and melting in the Broye catchment (Switzerland)

The study used a daily step conceptual hydrological model to examine the effects of climate change on snowfall accumulation and on snow cover melting in the Broye catchment (moderate relief- altitude from 400 to 1500 m a.s.l.). Five elevation bands representing a range of climatic conditions were used together with three realistic climate change scenarios based loosely on GCM's predictions and which reflect feasible changes by extending time periods. For a very moderate climate change (rise in air temperature of ca 1 °C), possibly in a near future, the reduction of snow cover duration, mean water equivalent and monthly maximum water equivalent is the most sensitive in the lower part of the catchment and during the first and last months of the snow season. In the higher part of the basin and during the colder months January and February, similar reduction rates can be expected in case of larger climate changes. The floods due to the melting of snow cover are lower. Sometimes rainfall, considered as snow in the present day conditions, generates additional floods during the winter season. For winter sports resorts below 1500 m a.s.l., even the very moderate climatic change scenario (temperature rise around 1 °C) leads to economically very difficult conditions. Finally, a climatic change detection index based on snow cover duration is proposed.     

Petrographische und Kalium-Argon-Untersuchungen an basischen tertiären Vulkaniten zwischen Westerwald und Vogelsberg

Between the upper tertiary volcanic areas of Westerwald and Vogelsberg (central Western Germany) occur more than 40 isolated tertiary volcanic dikes, eroded necks, plugs and domes. Twelve of these volcanic rocks have been investigated petrographically and chemically and classified by means of their modal and chemical composition. Additional modal analyses have been performed on seven other volcanics. On seventeen volcanic occurences K-Ar-whole rock age determinations have been made. The K-Ar age determinations yield- with the exception of an olivine-nephelinite — values between 27 and 15 Ma. Regarding the known intervals of volcanic activities of the Westerwald- and Voge1sberg-areas, most of the examined volcanics can be related genetically with one of the adjacent volcanic areas. There seems to be no geographical overlapping of volcanics showing Westerwaldages and Vogelsberg-ages. A possible influence of excess-Ar-bearing phases (e. g. mantle xenoliths) and an Ar-loss of constituent matter of the groundmass have been estimated by additional age determinations of enriched samples. These influences — partially compensating each other — may shift the K-Ar whole rock age to a maximum of 5 % and thus do not exceed the dimension of the standard deviations. A distinct NNE-SSW-striking fault in the region between Marburg and Gießen is situated parallel with the eastern border of the “Rheinisches Schiefergebirge”. Volcanics showing Westerwald-age and Vogelsberg-age respectively reach this fault, but obviously do not overlap it. Relations between rock-type an rock age, as it has been observed for the volcanics of the northern Hessian Depression (Kreuzer et al. 1973;Wedepohl 1982) cannot be proved certainly. On the other hand, similar to the basaltic rocks of the northern Hessian Depression, the youngest volcanic product is an olivine-nephelinite (9 Ma).     

A deuterium-hydrogen fractionation mechanism in magnesium oxide

Water dissolved in a nominally anhydrous oxide like MgO forms not only OH^? ions, as is usually assumed, but also molecular H₂ and peroxy anions O₂^2?. The specific lattice site where this reaction occurs has been identified for the model-type MgO structure: it is the fully OH^? compensated cation vacancy. In partially deuterated synthetic MgO, molecular D₂ forms preferentially to H₂, by a factor of the order of 4. Three methods have been used to study this very large D/H fractionation experimentally: mass spectrometry, electron spin resonance and infrared spectroscopy. All give consistent results and confirm that internal D/H fractionation occurs and is a function of the temperature. Theoretically the D/H fractionation is explained by the lower zeropoint energy of D₂ with respect to H₂, amplified by secondary processes through which the molecular hydrogen species become mobilized and eventually lost via diffusion. The possible consequences of such internal D/H fractionation processes are indicated for the interpretation of water and hydrogen release patterns, with varying D/H ratios, from terrestrial and extraterrestrial samples.     

Recent climate change: Rethinking drought in the context of Forest Fire Research in Ticino, South of Switzerland

Summary We analyse trends over the past 32 years in drought variables in the context of forest fire research and climate change in Ticino, Southern Switzerland. January to April and in particular the month of March have become drier. This is the time of the year when forest fires are most frequent. Our results show an increasing trend in all climatic variables favourable to drought and forest fires, including the length of episodes without precipitation, sunshine duration and temperature, and a decrease in relative humidity. The only exception is the number of “foehn” days, which have not significantly increased.     

Tectonics and sedimentation in the Fohnsdorf-Seckau Basin (Miocene, Austria): from a pull-apart basin to a half-graben

The Miocene intramontane Fohnsdorf-Seckau Basin is situated at the junction of the sinistral Mur-Mürz-fault system and the dextral Pöls-Lavanttal fault system. The basin comprises a 2,400-m-thick coal-bearing fluviodeltaic-lacustrine succession (Lower to Middle Miocene, Upper Karpatian?/Lower Badenian) which is overlain by a 1,000-m-thick alluvio-deltaic conglomeratic succession (Apfelberg Formation, ?Middle/Upper Badenian) in the south. A three-stage model for the basin evolution has been reconstructed from structural analysis and basin fill geometries. During a first pull-apart phase, subsidence occurred along ENE-trending, sinistral strike-slip faults of the Mur-Mürz fault system and NE-SW to N-S-trending normal faults, forming a composite pull-apart basin between overstepping en-echelon strike-slip faults. The Seckau and Fohnsdorf sub-basins are considered as two adjacent pull-aparts which merged into one basin. During the second phase, N-S to NNW-SSE extension and normal faulting along the southern basin margin fault formed a half-graben, filled by wedge-shaped alluvial strata (Apfelberg Formation). During the third phase, after the end of basin sedimentation, the dextral Pöls-Lavanttal fault system reshaped the western basin margin into a positive flower structure.     

Syn- and post-collisional heat flow in the Cenozoic Eastern Alps

The heat flow evolution of a continental collisional zone is exemplified by the Eastern Alps. Heat flow maps for the syn-collision (Oligocene), syn-extrusion (Early/Middle Miocene), and post-extrusion (Late Miocene, Recent) stages are presented, and are discussed in relation to the orogenic evolution. Continental collision during Paleogene time was characterized by extremely low heat flow (<40 mW/m²) along the orogenetic front, and very high heat flow (>150 mW/m²) a few hundred kilometers south of it. The former was a result of crustal thickening and of thermal blanketing due to rapid sedimentation and nappe stacking. The latter was caused by slab break-off and magmatic activity. The Early/Middle Miocene syn-extrusion stage was characterized by rapid exhumation of metamorphic core complexes (Tauern and Rechnitz Windows), and by magmatic activity (Styrian Basin). Both mechanisms caused extremely high heat flow (>200 mW/m²). In contrast, the orogenetic front remained cold. Thereafter, magmatic activity ended and uplift rates decreased. Thus, Late Miocene heat flow is characterized by low to moderately high values. Heat flow values >75 mW/m² were restricted to the transition zone of the Pannonian Basin characterized by thinned crust, and to the Tauern Window area. Recent temperature data indicate a subtle post-Miocene increase in heat flow.     

Element budgets of pine stands on lignite and pyrite containing mine soils

To analyze the development of pine ecosystems on lignite and pyrite containing mine soils, four pine stands with ages of 3–35 years were investigated in a chronosequence approach. Bulk precipitation, throughfall and soil solution in depths of 20, 40, 70 and 100 cm were studied over a three-year period to determine element fluxes in these forest ecosystems on extreme acidic and saline soils.Element budgets are controlled by the processes induced by pyrite oxidation such as intensive weathering of primary minerals, precipitation and leaching of secondary phases.Despite low water fluxes, element outputs can reach extraordinary high values due to very high concentrations in the soil solution. Although element outputs decrease drastically with stand age, respectively, site age, they exceed those of comparable pine stands on non-mine sites. Nitrogen release from the lignite fraction represents a special characteristic of the examined substrates. Nitrogen losses beneath the rooted zone can be 34 kg N ha⁻¹ yr⁻¹ in 100 cm depth. Element input and output in the examined ecosystems are far from balance. Closed cycling of nutrients seems to be recognizable in the case of potassium.