Li isotopes and trace elements as a petrogenetic tracer in zircon: insights from Archean TTGs and sanukitoids

We report δ⁷Li, Li abundance ([Li]), and other trace elements measured by ion probe in igneous zircons from TTG (tonalite, trondhjemite, and granodiorite) and sanukitoid plutons from the Superior Province (Canada) in order to characterize Li in zircons from typical Archean continental crust. These data are compared with detrital zircons from the Jack Hills (Western Australia) with U–Pb ages greater than 3.9 Ga for which parent rock type is not known. Most of the TTG and sanukitoid zircon domains preserve typical igneous REE patterns and CL zoning. [Li] ranges from 0.5 to 79 ppm, typical of [Li] in continental zircons. Atomic ratios of (Y + REE)/(Li + P) average 1.0 ± 0.7 (2SD) for zircons with magmatic composition preserved, supporting the hypothesis that Li is interstitial and charge compensates substitution of trivalent cations. This substitution results in a relatively slow rate of Li diffusion. The δ⁷Li and trace element data constrain the genesis of TTGs and sanukitoids. [Li] in zircons from granitoids is significantly higher than from zircons in primitive magmas in oceanic crust. TTG zircons have δ⁷Li (3 ± 8‰) and δ¹⁸O in the range of primitive mantle-derived magmas. Sanukitoid zircons have average δ⁷Li (7 ± 8‰) and δ¹⁸O higher than those of TTGs supporting genesis by melting of fluid-metasomatized mantle wedge. The Li systematics in sanukitoid and TTG zircons indicate that high [Li] in pre-3.9-Ga Jack Hills detrital zircons is a primary igneous composition and suggests the growth in proto-continental crust in magmas similar to Archean granitoids.     

Ion tracks in apatite at high pressures: the effect of crystallographic track orientation on the elastic properties of fluorapatite under hydrostatic compression

Static elasticity measurements at high pressures were carried out on oriented fluorapatite single crystals, some of which contained oriented amorphous ion tracks (ITs) implanted with relativistic Au ions (2.2 GeV) from the UNILAC linear accelerator at GSI, Darmstadt. High-pressure experiments on irradiated and non-irradiated crystal sections were carried out in diamond-anvil high-pressure cells under hydrostatic conditions. In situ single-crystal diffraction was performed to determine the high-precision lattice parameters, simultaneously monitoring the widths of X-ray diffraction Bragg peaks. High-pressure Raman spectra were analyzed with respect to the frequency shift and widths of bands, which correspond to the Raman-active vibrational modes of the phosphate tetrahedra. Swift heavy ion irradiation was found to induce anisotropic lattice expansion and tensile strain within the host lattice dependent on the ion-track orientation. The relatively low Grüneisen parameter for the ν _1b(A _g) mode, which has been assigned to originate from the volume fraction of the amorphous tracks, and the γ(ν _1a)/γ(ν _1b) ratio reveals compressive strain on the amorphous ITs. The comparative compressibilities for the host lattice reveal approximately equivalent bulk moduli, but significantly different pressure derivatives (K _T = 88.4 ± 0.7 GPa, ∂K/∂P = 6.3 ± 0.3 for non-irradiated, K _T = 90.0 ± 1.7 GPa, ∂K/∂P = 3.8 ± 0.5 for irradiated samples). The axial compressibility moduli β ⁻¹ reveal significant differences, which correlate with the ion-track orientation [b_a ^{- 1} \beta_{a}^{ - 1}  = 240 ± 5 GPa, b_c ^{- 1} \beta_{c}^{ - 1}  = 361 ± 14 GPa, ∂( b_a ^{- 1} ) \left( {\beta_{a}^{ - 1} } \right) /∂P = 11.3 ± 1.2, ∂( b_c ^{- 1} ) \left( {\beta_{c}^{ - 1} } \right) /∂P = 11.6 ± 3.4 for irradiation ⊥(100); 246 ± 9 GPa, 364 ± 57 GPa, 9.5 ± 2.9, 14.7 ± 14.1 for irradiation ⊥(001), 230.7 ± 3.6 GPa, 373.5 ± 5.1 GPa, 19.2 ± 1.4, 20.1 ± 1.8 for no irradiation]. Line widths of XRD Bragg peaks in irradiated apatites confirm the strain of the host lattice, which appears to decrease with increasing pressure. By contrast, the bandwidths of Raman modes increase with pressure, and this is attributed to increasing strain gradients on the length scale of the short-range order. The investigations reveal considerable deviatoric stress on the [100]-oriented tracks due to the anisotropic elasticity, while the compression is uniform for the directions perpendicular to the tracks, which are aligned parallel to the c-axis. This difference might be considered to control the diffusion properties related to the annealing kinetics and its observed anisotropy, and hence to cause potential pressure effects on track-fading rates.     

125 years of high-mountain research at Sonnblick Observatory (Austrian Alps)—from “the house above the clouds” to a unique research platform

Mountain observatories around the world are unique sites for monitoring and investigating variations, trends, forcings and feedbacks in the climate system, which are of utmost interest for understanding global climate change. From the small number of these research platforms, Sonnblick Observatory (Austrian Alps) stands out because of its long time series dating back to 1886 at an elevation of 3,100?m a.s.l. The paper describes the contribution of mountain observatories to climatology by the example of Sonnblick Observatory. The observatory's scientific evolution is summarised, starting from the original idea of upper air atmospheric measurements to its recent role as an atmospheric background station and interdisciplinary research site.     

Comparison of Multimission Altimetric Sea-Surface Heights with Tide Gauge Observations in the Southern Baltic Sea

One possible technique to validate the observations of altimeter missions is the comparison with sea-surface heights measured by tide gauges. In our investigation, we compared observations of the two tide gauge stations, Sassnitz and Warnemünde, which are located at the southern coast of the Baltic Sea, with sea-surface heights obtained from the altimeter missions Geosat, ERS-1, ERS-2, and TOPEX/Poseidon. For this purpose, the compared sea-surface heights were related to a common reference system and extrapolated to a common location. GPS observations, leveling data, regional geoid information, sea-surface topography, and postglacial rebound were included in the analysis. Considering the uncertainties of all model components, a more reliable estimation of the error budget (source, type, and magnitude of the errors) was performed. The obtained absolute altimeter biases are (-243 - 32) mm for Geosat, (467 - 19) mm for ERS-1, (76 - 19) mm for ERS-2, and (13 - 18) mm for TOPEX.     

Monthly, seasonal and annual temperature reconstructions for Central Europe derived from documentary evidence and instrumental records since AD 1500

Monthly temperature series for Central Europe back to AD 1500 are developed from documentary index series from Germany, Switzerland and the Czech Republic (1500–1854) and 11 instrumental temperature records (1760–2007). Documentary evidence from the Low Countries, the Carpathian Basin and Poland are used for cross-checking for earlier centuries. The instrumental station records are corrected for inhomogeneities, including insufficient radiation protection of early thermometers and the urban heat island effect. For overlapping period (1760–1854), the documentary data series correlate with instrumental temperatures, most strongly in winter (86% explained variance in January) and least in autumn (56% in September). For annual average temperatures, 81% of the variance is explained. Verification statistics indicate high reconstruction skill for most months and seasons. The last 20 years (since 1988) stand out as very likely the warmest 20-year period, accounting for the calibration uncertainty and decreases in proxy data quality before the calibration period. The new reconstruction displays a previously unobserved long-term decrease in DJF, MAM and JJA temperature variability over last five centuries. Compiled monthly, seasonal and annual series can be used to improve the robustness of gridded large-scale European temperature reconstructions and possible impact studies. Further improvement of the reconstruction would be achieved if documentary data from other European countries are further developed.     

The early instrumental warm-bias: a solution for long central European temperature series 1760–2007

Instrumental temperature recording in the Greater Alpine Region (GAR) began in the year 1760. Prior to the 1850–1870 period, after which screens of different types protected the instruments, thermometers were insufficiently sheltered from direct sunlight so were normally placed on north-facing walls or windows. It is likely that temperatures recorded in the summer half of the year were biased warm and those in the winter half biased cold, with the summer effect dominating. Because the changeover to screens often occurred at similar times, often coincident with the formation of National Meteorological Services (NMSs) in the GAR, it has been difficult to determine the scale of the problem, as all neighbour sites were likely to be similarly affected. This paper uses simultaneous measurements taken for eight recent years at the old and modern site at Kremsmünster, Austria to assess the issue. The temperature differences between the two locations (screened and unscreened) have caused a change in the diurnal cycle, which depends on the time of year. Starting from this specific empirical evidence from the only still existing and active early instrumental measuring site in the region, we developed three correction models for orientations NW through N to NE. Using the orientation angle of the buildings derived from metadata in the station histories of the other early instrumental sites in the region (sites across the GAR in the range from NE to NW) different adjustments to the diurnal cycle are developed for each location. The effect on the 32 sites across the GAR varies due to different formulae being used by NMSs to calculate monthly means from the two or more observations made at each site each day. These formulae also vary with time, so considerable amounts of additional metadata have had to be collected to apply the adjustments across the whole network. Overall, the results indicate that summer (April to September) average temperatures are cooled by about 0.4°C before 1850, with winters (October to March) staying much the same. The effects on monthly temperature averages are largest in June (a cooling from 0.21° to 0.93°C, depending on location) to a slight warming (up to 0.3°C) at some sites in February. In addition to revising the temperature evolution during the past centuries, the results have important implications for the calibration of proxy climatic data in the region (such as tree ring indices and documentary data such as grape harvest dates). A difference series across the 32 sites in the GAR indicates that summers since 1760 have warmed by about 1°C less than winters.     

Adapting to climate change in The Netherlands: an inventory of climate adaptation options and ranking of alternatives

In many countries around the world impacts of climate change are assessed and adaptation options identified. We describe an approach for a qualitative and quantitative assessment of adaptation options to respond to climate change in the Netherlands. The study introduces an inventory and ranking of adaptation options based on stakeholder analysis and expert judgement, and presents some estimates of incremental costs and benefits. The qualitative assessment focuses on ranking and prioritisation of adaptation options. Options are selected and identified and discussed by stakeholders on the basis of a sectoral approach, and assessed with respect to their importance, urgency and other characteristics by experts. The preliminary quantitative assessment identifies incremental costs and benefits of adaptation options. Priority ranking based on a weighted sum of criteria reveals that in the Netherlands integrated nature and water management and risk based policies rank high, followed by policies aiming at ‘climate proof’ housing and infrastructure.     

Subduction of continental margins and the uplift of high-pressure metamorphic rocks

The mechanism by which high-pressure metamorphosed continental material is emplaced at high structural levels is a major unsolved problem of collisional orogenesis. We suggest that the emplacement results from partial subduction of the continental margin which, because of its high flexural rigidity, produces a rapid change in the trajectory of the descending slab. We assume a two-fold increase in effective elastic thickness of the lithosphere as the continental margin approaches the subduction zone, and calculate the flexural profile of a thin plate for progressive downward migration of the zone of increased rigidity. We assess the effect of changes in the flexural profile on the overlying accretionary prism and mantle wedge as the continent approaches by estimating the extra stresses that are imposed on the wedge due to the bending moment exerted by the continental part of the plate. The wedges overlying the subduction zones, and the subducting slab itself, experience substantial extra compressional stress at depths of around 100 km, and extensional stress at shallower depths, as the continental margin passes through the zone of maximum curvature. The magnitudes of such extra stresses are probably adequate to effect significant deformation of the wedge and/or the descending plate, and are experienced in a time interval of less than 5 m.y. for typical subduction rates. The spatial variation of yield stresses in the region of the wedge and descending slab indicates that much of this deformation may be taken up in the crustal part of the descending slab, which is the weakest region in the deeper parts of the subduction zone. This may result in rapid upward migration of the crust of the partially subducted continental margin, against the flow of subduction. High-pressure metamorphosed terranes emplaced by the mechanism envisaged in this paper would be bounded by thrust faults below and normal faults above. Movement on the faults would have been coeval, and would have resulted in rapid unroofing of the high-pressure terranes, synchronous with arrival of the continental margin at the subduction zone and, therefore, relatively early in the history of a collisional orogen.     

Dispersal of Benthic Meiofauna by Wave and Current Action in Bogue Sound, North Carolina, USA

Abstract. Results from sediment trap experiments in Bogue Sound, North Carolina, indicate that meiofauna from a wide variety of taxa and benthic habitats are regularly suspended in the subtidal water column. Interstitial species are estimated to account for 10–30 % of the suspended meiofauna. Measurements of suspended nematode concentrations, when compared with wind and current velocity records, suggest that in Bogue Sound, shoaling and breaking waves are more important than tidal currents in controlling meiofauna erosion and deposition. Linear regression analysis indicates that 80% (r = 0.907) of the variation in suspended nematode density is correlated with changes in the mean onshore-offshore component of local wind velocity. Nematode turnover associated with spring and summer coastal wind patterns is estimated to be several hundred animals per m²per day. Once suspended, meiofauna may be carried up to 10 km per day by residual currents in the Sound. Although erosion, transport and deposition of benthic nematodes by wave and current action appears to provide an effective means of dispersal along continental coastlines, the high settling velocity of nematodes suspended in Bogue Sound (on the order of 10^-4m s^-1) suggests that net downward flux in shelf and slope waters probably prevents their dispersal across ocean basins by surface currents.