Prediction of central California earthquakes from soil-gas helium fluctuations

The observations of short-term decreases in helium soil-gas concentrations along the San Andreas Fault in central California have been correlated with subsequent earthquake activity. The area of study is elliptical in shape with radii approximately 160×80 km, centered near San Benito, and with the major axis parallel to the Fault. For 83 percent of theM>4 earthquakes in this area a helium decrease preceded seismic activity by 1.5 to 6.5 weeks. There were several earthquakes without a decrease and several decreases without a corresponding earthquake. Owing to complex and unresolved interaction of many geophysical and geochemical parameters, no suitable model is yet developed to explain the observations.     

Pseudo-oolites in rocks of the Ulundi Formation, lower part of the Archaean Fig Tree Group (South Africa)

The Ulundi Formation of the lowermost Fig Tree Group in the type area in the Barberton Mountain Land consists of a sequence of quartz—sericite schists, banded cherts and tuffaceous rocks up to 40 m thick. It overlies talc—carbonate schists assigned to the upper part of the Onverwacht Group. In the cherts, which in parts represent the sulfide facies of a banded-iron formation, silicified spheroids have been observed which appear to be diagenetically altered, locally zeolitized accretionary lapilli. Portions of the cherts formed through silicification of fine-grained felsic tuffs and contain abundant stylolite seams along which 4% of the rock thickness has been removed by intrastratal solution during deformation.A supposedly organogenic spheroidal structure, Ramsaysphera, has been previously described from the upper part of the Ulundi Formation. The spheroids, with diameters of up to 8 mm, occur in a distinct bed of up to at least 1.6 m thickness and can be traced in outcrop over an area which originally covered 17 × 30 km. The bed was deposited in fairly still water of several 100 m depth. The spheroids accumulated with only little finer-grained detrital material, the interstices between them being filled by cherty silica and minor amounts of dolomite. Up to 65% of the spheroids consist of tectonically elongated, originally round fragments of a micro-felsitic groundmass with remnants of phenocrysts. The majority of the remaining spheroids consists of concentrically banded bodies of siliceous material with minor amounts of chlorite and sericite, as well as small dolomite crystals. These spheroids represent highly altered granules of volcanic glass deposited from volcanic ash clouds through a body of water. The prototype of Ramsay-sphera also belongs to this group of spheroids, and there is little microscopic or macroscopic evidence for its explanation as an organic structure.     

Oil persistence on beaches in Prince William Sound - a review of SCAT surveys conducted from 1989 to 2002

In 2002, 13 years after the Exxon Valdez oil spill (EVOS), 39 selected sites in Prince William Sound (PWS) were re-surveyed following established shoreline cleanup assessment team (SCAT) field observation procedures to document surface and sub-surface oiling conditions in shoreline sediments and to compare results with those from previous Shoreline Cleanup Assessment Team (SCAT) surveys and other surveys in PWS. The selected sites are locations where EVOS oil persisted in 1992, at the time the Federal and State On-Scene Coordinators determined that the cleanup was complete and that further cleanup activities would provide no net environmental benefit. These sites had been included in a 2001 NOAA survey of shoreline oiling conditions and account for 88% of the sub-surface oil residues (SSO) oil documented by that study. The 2002 field survey found isolated occurrences of residual EVOS surface oil residues (SO) in the form of weathered asphalt pavement at 15 of the 39 sites. This residual SO typically consisted of asphalt in mixed sand/gravel substrate, located within a wave shadow effect created by boulders or bedrock in the upper intertidal to supratidal zone. Residual SO, expressed as a continuous oil cover, was less than 200 m(2) within the approximately 111,120 m(2) surveyed. A total of 1182 pits were dug at locations where SSO residues were present in 1992. Six of the 39 sites and 815 (68%) of the pits contained no residual SSO. Eighty-three percent of pits with SSO residues were found primarily in middle to upper intertidal locations. SSO residues commonly occurred in a discontinuous approximately 3 cm thick band 5-10 cm below the boulder/cobble or pebble/gravel veneer. The SO and SSO occurrences in the 2002 survey closely match the locations where they were found in 1992 and earlier surveys; however, in 2002 residual SSO patches are more discontinuous and thinner than they were in the earlier surveys. These sites are biased toward SSO persistence; those that have SSO residues represent less than 0.5% of the originally oiled shorelines in PWS. Despite evidence of continued oil weathering, both at the surface and in the sub-surface, it is clear that the natural cleaning processes at these particular locations are slow. The slow weathering rates are a consequence of the oil residue being incorporated in finer sediments (fine sand, silt, mix) and isolated from active weathering processes as boulders and outcrops, shallow bedrock asperities, or boulder-armoring create wave shadows and limit effective physical action on shorelines.     

The oxygen isotope compositions of olivine in main group (MG) pallasites: New measurements by adopting an improved laser fluorination approach

Oxygen isotope measurements of olivine in main group (MG) pallasites by traditional laser fluorination method are associated with some uncertainties including terrestrial weathering, incomplete olivine reaction, and sample state. We improved our laser fluorination approach by pretreating olivine grains with acid to remove terrestrial weathering products and by modifying the sample holder for an efficient and complete laser reaction. Our experiments on Brahin olivine demonstrate that acid-washing successfully removes the terrestrial weathering with <0.1‰ variation in δ¹⁸O value and, at the same time, improving the ∆¹⁷O value significantly. We also achieved a complete olivine fluorination by employing a custom-designed sample holder with “V”-shaped profile having rounded bottom because incomplete/partial reaction of olivine gives comparatively lighter δ¹⁸O values. Using these new techniques, we present precise triple oxygen isotope data (N = 72) of 25 olivine samples separated from main group pallasites. The data are, on average, ~0.5‰ heavier in δ¹⁸O relative to the values published in the literature for the same samples. Critically, the ∆¹⁷O values of MG pallasites and to some extent their Fo-contents suggest that there are at least two populations of olivine. Based on our improved data set, we propose that MG pallasites potentially have high-∆¹⁷O- and low-∆¹⁷O-bearing subgroups that are statistically distinct. The subgroups present average ∆¹⁷O values of −0.166 ± 0.003 (2SE; N = 16) and −0.220 ± 0.003 (2SE; N = 9), respectively. Furthermore, the high-∆¹⁷O-bearing subgroup samples trend toward lower Fo-contents compared to the other subgroup. Taken together, our data provide evidence that argues against a single parent body origin for MG pallasites.     

Development of a conceptual hydrogeological model for the evaluation of residence times of water in soil and groundwater: the state of Hesse case study, Germany

A regional conceptual hydrogeological model has been developed for evaluating residence times of both, percolate water in the unsaturated zone and groundwater in upper aquifers. The model is based on digitally geo-data bases available at the regional level and has been applied for the entire Federal State of Hesse (Germany) with a spatial resolution of 60?×?60?m. Residence times determined for unconsolidated rock areas typically ranged between 10 and 25?years, whereas residence times of <5?years were assessed for consolidated rock areas. With regard to the implementation of the EU Water Framework Directive, the determined residence times may help to assess the time periods between the introduction of well-targeted groundwater protection measures and their impact on groundwater and surface water quality, respectively.     

The nature and origin of pigments in black opal from Lightning Ridge,New South Wales,Australia

Abstract

Black opal (opal-AG) owes its dark coloration to a fine-grained pigment commonly inferred to be mainly carbon, yet chemical compositions for black opals suggest there may be additional components. Here we search for such components in pigment concentrates prepared by dissolving black opal nodules (nobbies) from Lightning Ridge (NSW) in hydrofluoric acid, using electron microscopy (scanning electron microscopy, transmission electron microscopy), X-ray diffraction and laser-ablation ICP-MS. The results demonstrate the presence of sulfides—predominantly pyrite and chalcopyrite, with minor galena and Ti-oxide phases, as additional components of the pigment. ATR-FTIR analysis indicates the presence of C=O and C–H groups, consistent with an organic origin. Transmission electron microscopy images of pigment show variously deformed, originally spherical ～100?nm particles rich in sulfide and carbon, which are interpreted as thin coatings of pigment on now dissolved opaline silica spheres. Laser-ablation ICP-MS analysis identifies remnant silica in pigment concentrates, which may be interpreted as opaline silica surviving HF treatment protected as inclusions in sulfides. When examined within the context of petrographic observations from more than 1000 opal nodules (nobbies) at Lightning Ridge, these new results suggest that pigment carbon and sulfides in the nodules formed microbially under initially anoxic groundwater conditions, within pre-existing cavities concurrently being filled with silica sol ultimately derived from chemical weathering of feldspar-rich volcaniclastic sediment. Intensely black pigment layers observed at the floor of many nodules indicate settling of dark, high-density (sulfide–Ti-oxide-rich) pigment within cavities, with the implication that sulfate-reducing bacterial (SRB) activity commences early during the silica sol-gel ripening process. Microbial activity may persist until after the cavity has completely filled with the silica sol, as illustrated by abundant black opals with uniformly distributed pigment. Pigment formed at this stage may no longer be able to settle out within the ripening and increasingly viscous silica gel, thus forming pigmentation throughout the opal cavity. The existence of ‘amber’, pigment-poor opal with intensely black basal pigment layers is interpreted as signalling a lack of sulfate to sustain further SRB activity, or a change to more oxidising conditions, possibly related to interaction with surface waters within a downward-penetrating weathering front. A change in redox conditions would shut off activity of SRB and thus sulfide pigment production and allow development of aerobic microbial activity as described by others.     

Arsenic bioaccessibility and speciation in clams and seaweed from a contaminated marine environment

The bioaccessible concentration and speciation of arsenic (soluble in a gastrointestinal medium and available for absorption into the bloodstream) were determined in softshell clams (Mya arenaria), harvested by local residents until 2005, and in seaweed (Fucus sp.) from an arsenic-contaminated marine site in Seal Harbour, Nova Scotia, Canada. Bioaccessibility extractions to simulate the human gastrointestinal environment (pH 1.5 and glycine for 1h followed by pancreatin, bile extract and pH adjustment to 7 for an additional 4h) and speciation of arsenic in extracts (HPLC-HG-AAS to target inorganic arsenic species) and whole samples (XANES) were carried out. Total arsenic for the clams from the contaminated area ranged from 218 to 228 ppm wet weight, with a bioaccessible fraction of 34-46%, and the major bioaccessible species of arsenic were inorganic. The seaweed from the contaminated area contained 27-43 ppm wet weight total arsenic, with the bioaccessible fraction ranging from 63% to 81%, and inorganic arsenic was also predominant. The predominantly inorganic nature of arsenic in the whole samples was confirmed by XANES. In concurrence with the closure of the area for clam harvesting, the clams and seaweed from Seal Harbour should probably not be used for human consumption.