Polychlorinated biphenyl (PCB) concentrations and congener composition in masu salmon from Japan: A study of all 209 PCB congeners by high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS)

We collected two subspecies of masu salmon: Oncorhynchus masou masou from four localities (southern Sea of Japan northward to Hokkaido) and O. masou ishikawae from upstream from Ise Bay close to a heavy industrial area. All 209 PCB congeners were analyzed using HRGC/HRMS. PCA ordination of congener concentrations divided data into three groups: (i) ssp. masou from Hokkaido, (ii) ssp. masou from the other regions and (iii) ssp. ishikawae. The highest ∑ PCB concentration (40.39 ng/wet wt) was in ssp. ishikawae followed by ssp. masou from southern waters; however the TEQ_{dioxin-like PCBs} was highest in ssp. masou from southern water (1.96 pg-TEQ_{dioxin-like PCBs}/g wet wt.) due to the high proportion of congener #126 in its complement (#126 has the highest toxic equivalency factor among congeners). There is likely a contamination source offshore in the southern Sea of Japan and/or along the migratory route of ssp. masou.     

Origin of the Velocity-Strengthening Nature of Granular Friction

A simple theory for a constitutive law for steady state dynamic friction in granular matter is presented. Starting from the energy balance equation together with the kinetics of grains, the energy dissipation rate is estimated, which directly leads to a constitutive law. The result indicates that a system of lower density is stronger than a system of higher density, albeit somewhat counterintuitive. This is a consequence of the fact that the grain rearrangement, which causes energy dissipation, is more frequent in a system of lower density. Thus, the velocity-strengthening nature of granular friction is naturally explained by the negative shear-rate dependence of the density. The present theory also qualitatively explains the experimental observation that a system of smaller layer thickness tends to be velocity-weakening.     

A possible Caledonide arm through the Barents Sea imaged by OBS data

The assembly of the crystalline basement of the western Barents Sea is related to the Caledonian orogeny during the Silurian. However, the development southeast of Svalbard is not well understood, as conventional seismic reflection data does not provide reliable mapping below the Permian sequence. A wide-angle seismic survey from 1998, conducted with ocean bottom seismometers in the northwestern Barents Sea, provides data that enables the identification and mapping of the depths to crystalline basement and Moho by ray tracing and inversion. The four profiles modeled show pre-Permian basins and highs with a configuration distinct from later Mesozoic structural elements. Several strong reflections from within the crystalline crust indicate an inhomogeneous basement terrain. Refractions from the top of the basement together with reflections from the Moho constrain the basement velocity to increase from 6.3 km s⁻¹ at the top to 6.6 km s⁻¹ at the base of the crust. On two profiles, the Moho deepens locally into root structures, which are associated with high top mantle velocities of 8.5 km s⁻¹. Combined P- and S-wave data indicate a mixed sand/clay/carbonate lithology for the sedimentary section, and a predominantly felsic to intermediate crystalline crust. In general, the top basement and Moho surfaces exhibit poor correlation with the observed gravity field, and the gravity models required high-density bodies in the basement and upper mantle to account for the positive gravity anomalies in the area. Comparisons with the Ural suture zone suggest that the Barents Sea data may be interpreted in terms of a proto-Caledonian subduction zone dipping to the southeast, with a crustal root representing remnant of the continental collision, and high mantle velocities and densities representing eclogitized oceanic crust. High-density bodies within the crystalline crust may be accreted island arc or oceanic terrain. The mapped trend of the suture resembles a previously published model of the Caledonian orogeny. This model postulates a separate branch extending into central parts of the Barents Sea coupled with the northerly trending Svalbard Caledonides, and a microcontinent consisting of Svalbard and northern parts of the Barents Sea independent of Laurentia and Baltica at the time. Later, compressional faulting within the suture zone apparently formed the Sentralbanken High.