Spatial Variation in the Optical Properties of Dissolved Organic Matter (DOM) in Lakes on the Canadian Precambrian Shield and Links to Watershed Characteristics

In the present study, we explored the use of various optical parameters to detect differences in the composition of the dissolved organic matter (DOM) in a set of lakes that are all located on the Canadian Precambrian Shield, but within which Cu and Ni speciation predictions were previously shown to diverge from measured values in some lakes but not in others. Water samples were collected with in situ diffusion samplers in 2007 (N = 18 lakes) and 2008 (N = 8 lakes). Significant differences in DOM quality were identified between the sampling regions (Rouyn-Noranda, Québec and Sudbury, Ontario) and among lakes, based on dissolved organic carbon concentrations ([DOC]), specific UV absorbance (SUVA₂₅₄), fluorescence indices (FI), and excitation–emission matrix (EEM) fluorescence measurements. Parallel factor analysis (PARAFAC) of the EEM spectra revealed four components, two of which (C3, oxidized quinone fluorophore of allochthonous origin, and C4, tryptophan-like protein fluorescence of autochthonous origin) showed the greatest inter-regional variation. The inter-lake differences in DOM quality were consistent with the regional watershed characteristics as determined from satellite imagery (e.g., watershed-to-lake surface area ratios and relative percentages of surface water, rock outcrops vegetative cover and urban development). Source apportionment plots, built upon PARAFAC components ratios calculated for our lakes, were used to discriminate among DOM sources and to compare them to sources identified in the literature. These results have implications for other areas of research, such as quantifying lake-to-lake variations in the influence of organic matter on the speciation of trace elements in natural aquatic environments.     

A brief comparison of lava flows from the Deccan Volcanic Province and the Columbia-Oregon Plateau Flood Basalts: Implications for models of flood basalt emplacement

The nature and style of emplacement of Continental Flood Basalt (CFB) lava flows has been a matter of great interest as well as considerable controversy in the recent past. However, even a cursory review of published literature reveals that the Columbia River Basalt Group (CRBG) and Hawaiian volcanoes provide most of the data relevant to this topic. It is interesting to note, however, that the CRBG lava flows and their palaeotopographic control is atypical of other CFB provinces in the world. In this paper, we first present a short overview of important studies pertaining to the emplacement of flood basalt flows. We then briefly review the morphology of lava flows from the Deccan Volcanic Province (DVP) and the Columbia-Oregon Plateau flood basalts. The review underscores the existence of significant variations in lava flow morphology between different provinces, and even within the same province. It is quite likely that there were more than one way of emplacing the voluminous and extensive CFB lava flows. We argue that the establishment of general models of emplacement must be based on a comprehensive documentation of lava flow morphology from all CFB provinces.     

Ocean-atmosphere CO2 exchange: An accessible lab simulation for considering biological effects

Phytoplankton is considered a key component mediating the ocean-atmospheric exchange of carbon dioxide and oxygen. Lab simulations which model biological responses to atmospheric change are difficult to translate into natural settings owing in part to the vertical migration of phytoplankton. In the sea this vertical migration acts to regulate actual carbon dioxide consumption. To capture some critical properties of this vertical material transfer, we monitored the effects of atmospheric CO₂ on dense suspensions of bioconvecting microorganisms. Bioconvection refers to the spontaneous patterns of circulation which arise among such upwardly swimming cells as alga, protozoa, zoospore and large bacteria. Gravity, phototaxis and chemotaxis have all been implicated as affecting pattern-forming ability. The ability of a biologically active suspension to detect atmospheric changes offers a unique method to quantify organism adjustment and vertical migration. With increasing CO₂, bioconvection patterns in alga (P. parva) and protozoa (T. pyriformis) lose their robustness, and surface cell populations retreat from the highest CO₂ regions. Cell movement (both percent motile and mean velocity) generally diminishes. A general program of image analysis yields statistically significant variations in macroscopic migration patterns; both fractal dimension and various crystallographic parameters correlate strongly with carbon dioxide content.     

The Loyalty—New Hebrides Arc collision: Effects on the Loyalty Ridge and basin system,Southwest Pacific (first results of the ZoNéCo programme)

The ZoNéCo 1 and 2 cruises of Ifremer's Research Vessel L'Atalante, collected new swath bathymetry and geophysical data over the southern and northern segments of the basins and ridges forming the Loyalty system. Between the two surveyed areas, previous studies found evidence for the resistance of the Loyalty Ridge to subduction beneath the New Hebrides trench near 22°S–169°E. On the subducted plate, except for seismicity related to the downbending of the Australian plate, recorded shallow seismicity is sparse within the Loyalty system (Ridge and Basin) where reliable focal mechanism solutions are almost absent.Swath bathymetry, seismic reflection and magnetic data acquired during the ZoNéCo 1 and 2 cruises revealed a transverse asymmetric morphology in the Loyalty system, and an along-strike horst and graben structure on the discontinuous Loyalty Ridge. South of 23°50S and at 20°S, the two WSW-ENE-trending fault systems, respectively, sinistral and dextral, that crosscut the southern and northern segments of the Loyalty system, are interpreted as due to the early effects of collision with the New Hebrides Arc. A NNW-SSE trend, evident along the whole Loyalty system and on the island of New Caledonia, is interpreted as an inherited structural trend that may have been reactivated through flexure of the Australian lithospheric plate at the subduction zone.Overall then, the morphology, structure and evolution of the southern and northern segments of the Loyalty system probably result from the combined effects of the Australian plate lithospheric bulge, the active Loyalty-New Hebrides collision and the overthrust of the New Caledonian ophiolite.     

Potential of High-Resolution Satellite Data in the Context of Vulnerability of Buildings

High-resolution space-borne remote sensing data are investigated for their potential to extract relevant parameters for a vulnerability analysis of buildings in European countries. For an evaluation of large earthquake scenarios, the number of parameters in models for vulnerability is reduced to a minimum of relevant information such as the type of building (age, material, number of storeys) and the geological and spatial context. Building-related parameters can be derived from remote sensing data either directly (e.g. height) or indirectly based on the recognition of the urban structure type in which the buildings are located. With the potential of a fully- or semi-automatic inventory of the buildings and their parameters, high-resolution satellite data and techniques for their processing are a useful supporting tool for the assessment of vulnerability.     

Geometric consistency for regression model estimation and testing in climatology and meteorology

Abstract

The effects of outliers on linear regression are examined. The sensitivity of classical least‐squares (LS) procedures to outliers is shown to be associated with the geometric inconsistency between the data space and the analysis space. This is illustrated for both estimation and inference. A geometrically consistent procedure based on the Euclidean distance is proposed. This procedure involves the least absolute deviation (LAD) regression and a new permutation test for matched pairs (PTMP). Comparisons made with LS techniques demonstrate that the proposed procedure is more resistant to the existence of outliers in the data set and leads to more intuitive results. Applications and illustrations using meteorological and climatological data are also discussed.     

Mathematical model for one-dimensional desiccation and consolidation of sedimented soils

A mathematical model has been developed to represent the physical phenomena that occur during the desiccation and one-dimensional consolidation of successive layers of hydraulically transported sediments as they are periodically deposited in a containment area. The governing boundary value problem, defined in terms of pore water pressures, consists of two field equations (one for the saturated domain and one for the unsaturated domain), a drainage boundary condition, an evapotranspiration boundary condition and a series of continuity conditions at the interfaces between different layers. A number of simplifying assumptions were made to render the field equations tractable, and a step-by-step numerical procedure was used to solve the linearized boundary value problem; at the end of each step, the errors introduced by the simplifying assumptions were corrected. Based on a thorough study of the convergence and stability conditions associated with the numerical approximation employed, a system of automatic corrections was incorporated into the computer program to reduce the time increment if stability problems originate during the solution. Based on the results of a parameter study, it was found that, although drainage conditions at the bottom of the, layer do exert some influence on the consolidation rate during deposition of the dredgings, the evapotranspiration potential renders this effect almost negligible when desiccation takes place at the surface. In contrast, transpiration plays an important, role on the consolidation rate during the early stages of desiccation, but its effect is reduced considerably as the water table approaches an equilibrium position.     

Radar observations at 3.5 and 12.6 cm wavelength of asteroid 433 Eros

A study of the asteroid 433 Eros using 3.5 and 12.6 cm radar waves indicates that the surface is very much rougher than any planetary or lunar surface observed by this method. A surface completely covered with sharp edges, pits, subsurface holes, or embedded chunks with scale sizes on the order of our wavelengths seems to be indicated. A model based on a rough rotating triaxial ellipsoid having radii in the rotation equator of 18.6 and 7.9 km agrees well with our data, although a strong wobble in the apparent center frequency of the spectra as rotation progresses indicates that one side may be more reflective than the other, or more likely, that the projected axis of rotation does not equally divide the projected area.