Impact of land cover changes and topography on soil quality in the Kasso catchment,Bale Mountains of southeastern Ethiopia

This study assessed land cover change and topographic elevation on selected soil quality parameters in the Kasso catchment, southeastern Ethiopia. Twenty‐seven soil samples collected from 0–30cm depth under four land cover types across three elevation gradients were analysed for selected soil quality parameters. Results indicated that soil particle size distribution is different (p<0.001) in the catchment because of the effect of land cover change and elevation. Most cultivated lands occupy lower elevations where clay accumulates as a result of its movement from higher to lower elevations. Ploughing accentuates weathering, making cultivated lands richer in finer materials. Cation exchange capacity and exchangeable magnesium and potassium negatively correlated with elevation, total nitrogen and available phosphorous. Conversion of natural vegetation to cropland contributed to changes in pH (p<0.05), exchangeable calcium (p<0.01), potassium (p<0.001), available phosphorous (p<0.01) and nitrogen (p<0.01) contents. Parameter soil degradation index results showed that soil organic carbon, nitrogen, available phosphorous and exchangeable potassium contents declined and bulk density increased because of the land cover change. This negative effect on agricultural development and environmental health of the catchment makes an integrated land resource management approach indispensable for sustaining agricultural productivity and the environmental health of the Kasso catchment.     

Mechanisms Controlling the Undrained Strength Behavior of Remolded Ariake Marine Clays

The soft clay of Ariake Bay, in western Kyushu, Japan covers several hundred square kilometers. Ariake clay consists of the principal clay minerals namely smectite, illite, kaolinite and vermiculite, and other minerals in lesser quantity. The percentage of the principal clay mineral can vary significantly. The percent clay size fraction and the salt concentration can also vary significantly. In view of the importance of undrained shear strength in geotechnical engineering practice, its behavior has been studied with respect to variation in salt concentration. Basically two mechanisms control the undrained strength in clays, namely (a) cohesion or undrained strength is due to the net interparticle attractive forces, or (b) cohesion is due to the viscous nature of the double layer water. Concept (a) operates primarily for kaolinitic soil, and concept (b) dominates primarily for montmorillonitic soils. In Ariake clay, different clay minerals with different exchangeable cations and varying ion concentration in the pore water and varying nonclay size fraction are present. In view of this while both concepts (a) and (b) can coexist and operate simultaneously, one of the mechanisms dominates. For Isahaya clay, concept (a), factors responsible for an increase in level of flocculation and attractive forces result in higher undrained strength. Increase in salt concentration increases the remolded undrained strength at any moisture content. For Kubota and Kawazoe clays, concept (b) factors responsible for an expansion of diffuse double layer thickness, resulting in higher viscous resistance, increase the undrained shear strength, that is, as concentration decreases, the undrained strength increases at any moisture content. The liquid limit of Isahaya clay increases with increase in ion concentration and a marginal decrease is seen for both Kubota and Kawazoe clays, and their behavior has been explained satisfactorily.     

Performance evaluation of artificial neural networks for planimetric coordinate transformation—a case study,Ghana

Two national horizontal geodetic datums, namely, the Accra and Leigon datum, have been the only available datum used in Ghana. These two datums are non-geocentric and were established based on astro-geodetic observations. Relating these different geodetic datums mostly involves the use of conformal transformation techniques which could produce results that are not very often satisfactory for certain geodetic, surveying and mapping purposes. This has been ascribed to the incapability of the conformal models to absorb more of the heterogeneous and local character of deformations existing within the local geodetic networks. Presently, application of new approaches such as artificial neural network (ANN) is highly recommended. Whereas the ANN has been gaining much popularity to solving coordinate transformation-related problems in recent times, the existing researches carried out in Ghana have shown that only three-dimensional conformal transformation methods have been utilized. To the best of our knowledge, plane coordinate transformation between the two local geodetic datums in Ghana has not been investigated. In this paper, an attempt has been made to explore the plane coordinate transformation performance of two different ANN approaches (backpropagation neural network (BPNN) and radial basis function neural network (RBFNN)) compared with two different traditional techniques (six- and four-parameter models) in the Ghana national geodetic reference network. The results revealed that transforming plane coordinates from Leigon to Accra datum, the RBFNN was better than the BPNN and traditional techniques. Transforming from Accra to Leigon datum, both the BPNN and RBFNN produced closely related results and were better than the traditional methods. Therefore, this study will create the opportunity for Ghana to recognize the significance and strength of the ANN technology in solving coordinate transformation problems.     

Spatial-temporal evaluation of different reference evapotranspiration methods based on the climate forecast system reanalysis data

Evapotranspiration is a major component of the interaction between land-surface processes and the atmosphere. Climate Forecast System Reanalysis (CFSR) data offer a promising database for overcoming the limitations in availability and reliability of climatological data and, hence, for understanding the evapotranspiration process. Using these data on grid-by-grid daily, seasonal and yearly scales, the present study attempts to advance the spatio-temporal evaluation of two radiation-based and three temperature-based methods for estimating potential evapotranspiration (PET) against estimates of grass reference evapotranspiration (ETo) by FAO Penman–Monteith method (FAO-PM). The analysis was performed for the period 1979–2013, considering the second largest (79 000 km²) river system in Ethiopia, that is, Omo-Gibe basin, which accommodates national parks and vast hydropower, cultivation and afforestation developments and discharges its flow to Lake Turkana in Kenya. Despite the large regional variations in climate and elevation, the results in overall emphasize the outperformance of the simple temperature method, viz. Hargreaves–Samani method, in capturing both the annual and seasonal FAO-PM estimates. Calibration of the Hargreaves–Samani equation is, however, a requisite for spectacular improvement of its performance. Accordingly, new coefficients of the equation are proposed. The annual trends in the basin's ETo increased with rising temperature and decreasing relative humidity, wind speed, and solar radiation, but with decreasing (increasing) rainfall in the upper region (the middle and lower regions). It is deduced that trends in simple methods do not necessarily reflect the true trends in ETo. Annual ETo decreases with increasing elevation and annual rainfall. The present findings are discussed in the context of a worldwide literature, thereby improving the understanding of the best performing PET methods in similar data-scarce national or transboundary rivers basin in Ethiopia, the region or worldwide. The wider implications regarding water loss from reservoirs and the rain-fed food and sugar production in the basin under study are also highlighted.     

Natural and human-induced sinkhole hazards in Saudi Arabia: distribution,investigation, causes and impacts

Approximately 60 % of the 2,150,000 km² area of Saudi Arabia is underlain by soluble sediments (carbonate and evaporite rock formations, salt diapirs, sabkha deposits). Despite its hyper-arid climate, a wide variety of recent sinkholes have been reported in numerous areas, involving significant property losses. Human activities, most notably groundwater extraction, have induced unstable conditions on pre-existing cavities. This work provides an overview of the sinkhole hazard in Saudi Arabia, a scarcely explored topic. It identifies the main karst formations and the distribution of the most problematic sinkhole areas, illustrated through several case studies covering the wide spectrum of subsidence mechanisms. Some of the main investigation methods are presented through selected examples, including remote sensing, trenching and geophysics. Based on the available data, the main causal factors are identified and further actions that should be undertaken to better assess and manage the risk are discussed.     

Generation and expulsion of oils from Permian coals of the Sydney Basin,Australia

Organic geochemical and petrological assessment of coals/coaly shales and fine grained sediments, coupled with organic geochemical analyses of oil samples, all from Permo–Triassic sections of the Southern Sydney Basin (Australia), have enabled identification of the source for the widely distributed oil shows and oil seeps in this region. The Permian coals have higher hydrogen indices, higher liptinite contents, and much higher total organic matter extract yields than the fine grained sediments. A variety of source specific parameters obtained from n-alkanes, regular isoprenoids, terpanes, steranes and diasteranes indicate that the oil shows and seeps were generated and expelled predominantly from higher plant derived organic matter deposited in oxic environments. The source and maturity related biomarkers and aromatic hydrocarbon distributions of the oils are similar to those of the coals. The oil-coal relationship also is demonstrated by similarities in the carbon isotopic composition of the total oils, coal extracts, and their individual n-alkanes. Extracts from the Permo–Triassic fine grained sediments, on the other hand, have organic geochemical signatures indicative of mixed terrestrial and prokaryotic organic matter deposited in suboxic environments, which are significantly different from both the oils and coal extracts. The molecular signatures indicating the presence of prokaryotic organic matter in some of the coal extracts and oils may be due to thin sections of possibly calcareous lithologies interbedded within the coal measures. The genetic relationship between the oils and coals provides new evidence for the generation and expulsion of oils from the Permian coals and raises the possibility for commercial oil accumulations in the Permian and Early Triassic sandstones, potentially in the deeper offshore part of the Sydney Basin.     

Origin of spheroidal chert nodules, Drunka Formation (Lower Eocene), Egypt

Chert nodules of the Drunka Formation (Lower Eocene) are mostly spherical, have diameters from 40 to 120 cm, are quasi-uniformly spaced 2–3 m apart in the plane of bedding, have concentric internal structure and, except for rare small (<6 cm) solid chert nodules, are less than 85% chertified. Nodules formed after moderate alteration of limestone by meteoric water (δ¹⁸O_calcite = –4 to –8‰) at shallow (<100 m) burial depths; more extensive alteration of limestone (δ¹⁸O = –10 to –16‰) by meteoric water followed nodule growth. Chertification was by low-temperature meteoric water (δ¹⁸O_quartz = +18‰ in margins to +22‰ in nuclei) at shallow burial depths. Meteoric water may have invaded the Drunka Formation in association with shelf progradation during the Early Eocene, or during the development of a Middle Eocene unconformity. Replacement of carbonate mud by microcrystalline quartz was the dominant chertification process, but fossils were replaced in part by fine-grained equant megaquartz, quartzine and chalcedony; the last of these occurs in places as beekite. Opal A-secreting marine organisms are the inferred source of silica, but none are preserved. There is no compelling evidence of an opal-CT precursor, so quartz may have formed by direct precipitation. Self-organization processes of enigmatic character established the spacing pattern of the nodules and also the Liesegang-banded internal structure of the chert nodules. Nodules grew chiefly by diffusive supply of silica, although one locality has elongate nodules that grew when there was some porewater advection. Chertification patterns and δ¹⁸O values of both calcite and quartz indicate that nodule growth was complex and variable. Some nodules probably grew from the centre outwards. Many nodules, however, initially grew simultaneously across the entire nodule, but late-stage growth was predominantly at the outer margins or at selective internal sites.     

A menagerie of graphite morphologies in the Acapulco meteorite with diverse carbon and nitrogen isotopic signatures: Implications for the evolution history of acapulcoite meteorites

Morphologies, petrographic settings and carbon and nitrogen isotopic compositions of graphites in the Acapulco meteorite, the latter determined by secondary ionization mass spectrometry, are reported. Seven different graphite morphologies were recognized, the majority of which occur enclosed exclusively in kamacite. Individual graphite grains also rarely occur in the silicate matrix. Kamacite rims surrounding taenite cores of metal grains are separated from the Ni-rich metal cores by graphite veneers. These graphite veneers impeded or prevented Ni-Fe interdiffusion during cooling. In addition, matrix FeNi metal contains considerable amounts of phosphorous (≈ 700 ppm) and silicon (≈ 300 ppm) (Pack et al., 2005 in preparation) thus indicating that results of laboratory cooling experiments in the Fe-Ni binary system are inapplicable to Acapulco metals. Graphites of different morphologies display a range of carbon and nitrogen isotopic compositions, indicating a diversity of source regions before accretion in the Acapulco parent body. The isotopic compositions point to at least three isotopic reservoirs from which the graphites originated: (1) A reservoir with heavy carbon, represented by graphite in silicates (δ¹³C = 14.3 ± 2.4 ‰ and δ¹⁵N = −103.4 ± 10.9 ‰), (2) A reservoir with isotopically light carbon and nitrogen, characteristic for the metals. Its C- and N-isotopic compositions are probably preserved in the graphite exsolutions that are isotopically light in carbon and lightest in nitrogen (δ¹³C = −17 to −23 ‰ δ¹⁵N = −141 to −159 ‰). (3) A reservoir with an assumed isotopic composition (δ¹³C ∼ −5 ‰; δ¹⁵N ∼ −50 ‰). A detailed three-dimensional tomography in reflected light microscopy of the decorations of metal-troilite spherules in the cores of orthopyroxenes and olivines and metal-troilite veins was conducted to clarify their origin. Metal and troilite veins are present only near the fusion crust. Hence, these veins are not pristine to Acapulco parent body but resulted during passage of Acapulco in Earth’s atmosphere. A thorough search for symplectite-type silicate-troilite liquid quench textures was conducted to determine the extent of closed-system partial silicate melting in Acapulco.Metal-troilite spherules in orthopyroxenes and olivines are not randomly distributed but decorate ferromagnesian silicate restite cores, indicating that the metal-spherule decoration around restite silicates took place in a silicate partial melt. Graphite inclusions in these spherules have C- and N- isotopic compositions (δ¹³C = −2.9 ± 2.5 ‰ and δ¹⁵N = −101.2 ± 32 ‰) close to the average values of graphite in metals and in the silicate matrix, thus strongly suggesting that they originated from a mixture of graphite inclusions in metals and silicate matrix graphite during a closed system crystallization process subsequent to silicate-metal-sulfide partial melting. Troilite-orthopyroxene quench symplectite textures in orthopyroxene rims are clear evidence that silicate-sulfide partial melting took place in Acapulco. Due to petrographic heterogeneity on a centimeter scale, bulk REE abundances of individual samples or of individual minerals provide only limited information and the REE abundances alone are not entirely adequate to unravel the formational processes that prevailed in the acapulcoite-lodranite parent body. The present investigations demonstrate the complexity of the evolutionary stages of acapulcoites from accretion to parent body processes.