Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.     

Environmental impact on groundwater of Maheshwaram Watershed,Ranga Reddy district,Andhra Pradesh

Maheshwaram watershed is situated in Ranga Reddy district of at a distance of about 30 km south of Hyderabad. The watershed has an area of 53 km² and has hard rock aquifers with semi-arid climate. The study area has been expanding at a fast pace and now has the distinction of being one of the fastest growing urban centers, facing the problem of groundwater depletion and quality deterioration due to the absence of perennial source of surface water and also due to over exploitation. Human activities involving industrial and agricultural development and the inadequate management of land and water resources have, directly or indirectly resulted in the degradation of environment viz. water and soil.     

Evaluating some factors that affect feasility of using ground penetrating radar for landmine detection

Ground penetrating radar （GPR） is one of the promising technologies that can be used to detect landmines. Many factors may affect the ability of GPR to detect landmines. Among those factors are： 1） the type of landmine material （metallic or plastic）, 2） conditions of the host soil （soil texture and soil moisture）, and 3） the radar frequency utilized. The impact of these factors on the ability of GPR to detect landmines is investigated by studying their effect on the dielectric permittivity contrast between the landmine and the host soil, as well as on the attenuation of the radar waves. The impact of each factor was theoretically reviewed and modeled using the Matlab and Mathcad software packages. Results of the computer modeling were correlated with GPR data acquired for metallic and plastic landmine types. It was found that the ability of GPR to detect landmines depends to a great extent on the landmine type, water content of the host soil, utilized radar frequency, and soil texture. The landmines are much easier to detect than plastic landmines for any soil conditions and any radar frequency. Increasing the soil＇s moisture content, regardless of soil texture, eases the detection of the plastic landmine and worsens the detection of the metallic mines. Increasing the percentage of clay in the soil causes the same effect as the moisture content. However, higher radar frequency delivers better results for landmine detection as long as the percentage of clay and the moisture content in the soil remains low. The results of this study are expected to help in selecting optimum radar antennae and data acquisition parameters depending on the landmine type and environmental conditions.     

Factors controlling mechanisms of groundwater salinization and hydrogeochemical processes in the Quaternary aquifer of the Eastern Nile Delta, Egypt

In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ¹⁸O–δ²H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ¹⁸O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between ¹⁴C activities and Cl^? concentration confirms this hypothesis.     

Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.     

Land use history of Jebel Marra,Sudan, as related to the present distribution of woody vegetation

This study attempts to relate vegetation distribution to land use history in Jebel Marra, the Democratic Republic of the Sudan. There are evidences that most,if not all, of the woody vegetation communities in Jebel Marra have been derived from some more complex types by continuous disturbance ssince antiquity. Here past and contemporary land use types are described and associated to woody plants distribution. Empirical stratified sampling methods of plant geographers and ecologists are applied to both natural and artificial systems. Frequencies, densities and diversities for all woody plant communities are estimated by standard ecological indices. It was found that throughout known history woody plant communities were subjected to different degrees of suppression. Thus, the present distribution of the woody plant communities reflects the different stages as well as modes of suppression. Drastic population movements and the resulting changes in land use types since antiquity, seem to be the chief explanation behind the variations in modes of suppression.     

Climate impacts of environmental degradation in Sudan

There exists an impressive amount of work for Sudan showing the anthropogenic degradation of natural vegetation cover. However, there are few examples of consequent climatic changes in literature. This work, thus, seeks to assess such effects of environmental forcing on various climatic patterns over the past few decades. Within the frame of the present analysis, the results are quite striking and are in concordance with scientific contentions that such land degradation could result in climatic modification. Higher temperature and less rainfall, sunshine duration and global radiation have been noticed. Evapotranspiration has responded more to the warming and drying conditions, thus showed signs of increasing rates, especially during the wet season. However, the extent of increase seems to have been suppressed by the decrease in sunshine duration and solar radiation as well as the inconsistent behaviour of wind speed. Changes in the variability of the within-year monthly observations have also occurred, thus suggesting an increase in the occurrence of extremes. The observed climatic modification in the country has exaggerated the insidious drought conditions. The present findings are hoped to contribute to our understanding of the effects of environmental problem and assist in considering policy responses. This revised version was published online in July 2006 with corrections to the Cover Date.     

Evaluation of Electro-Oxidation of Textile Effluent Using Response Surface Methods

In the present investigation, treatment of textile effluent using an electrochemical technique was designed and analyzed using the Box-Behnken method. The influence of individual parameters on electro-oxidation of textile effluent has been critically examined using the response surface method (RSM), and a quadratic model for chemical oxygen demand (COD) reduction has been developed. It has been observed from the present analysis that the predicted values are in good agreement with experimental data with a correlation coefficient of 0.945.     

Station-keeping for a translunar communication station

A translunar communication station is to be kept close to a nominal unstable periodic ‘Halo’ orbit, visible at all times from Earth. The analytically computed nominal orbit is not perfect, requiring an average control acceleration of about 10^?6 g's for tight control. An adjustable quadratic combination of position deviation and control acceleration is minimized to provide an (adjustable) control law with period feedback gains and a periodic bias. The average control acceleration can be reduced to less than 10^?8 g's with an error settling time of less than 21/2 months. The resulting limiting motion provides, in turn, an improved nominal, permitting the same low control cost with much tighter control, corresponding to settling times of the order of one day.     

Anticipated economic costs and benefits of ratification of the Kyoto Protocol by the State of Qatar

Abstract

Further ratification of the Kyoto Protocol by non-Annex 1 countries such as the State of Qatar will not affect the entrance into force of the Treaty; however, ratification remains an important decision due to other considerations, primarily the economic costs and benefits associated with ratification. As a member of the Organization of Petroleum Exporting Countries (OPEC), Qatar's economic position is closely allied with revenue generated from its oil and natural gas resources. Qatar expects adverse impacts from implementing the Kyoto Protocol, though the estimated magnitude varies enormously with different models. Also, the impacts depend significantly on how the implementation is done; for example, the kind of policies that other countries use. Qatar is able to counter adverse impacts by exploiting its greater share of natural gas and developing energy-intensive industries that produce nonenergy goods such as steel, petrochemicals, and chemicals. Furthermore, it is clear that clauses in the Protocol can be developed to protect OPEC interests, and if Qatar does not ratify the Protocol, it will be excluded from the subsequent rule-making processes. On balance, there are benefits to ratifying the Treaty, and there is also a strong need for extensive further research.