Biodegradation of phenol from a synthetic aqueous system using acclimatized activated sludge

Phenol is one of the aromatic hydrocarbons. Phenol and its derivatives are highly toxic. These pollutants can be observed in the effluents of many industries. This research investigates the removal of phenol by the use of activated sludge in a batch system. The effects of influencing factors on biodegradation efficiency have been evaluated. The main factors considered in this study were the volume of acclimatized activated sludge inoculation, pH, temperature, and initial concentration of phenol. The inoculation volumes of 1, 3, and 5 mL of acclimatized activated sludge were taken into account. Different pH values of 3, 5, 7, 9, and 11 were examined. The experiments were conducted for temperatures of 25, 30, 35, and 40 °C and initial phenol concentrations of 400, 800, 1,000, and 1,500 ppm. The results show that the acclimatized activated sludge has a high capacity for the removal of phenol. From a 100-mL aqueous solution was removed 1,500 ppm of phenol after 80 h. Furthermore, maximum phenol removal was observed for an inoculation volume of 5 mL for three different phenol concentrations of 100, 400, and 800 ppm. The best pH was 7 for the biodegradation process, and the optimum temperature was 30 °C. It was further found that an increase in the phenol concentration increased its removal time. Moreover, the activated sludge could effectively remove about 99.9 % of phenol from a synthetic aqueous solution in a batch system.     

Correlation of lineaments and groundwater quality in Dasht-e-Arjan Fars,SW of Iran

The NE-oriented Dasht-e-Arjan graben is located 65 km west of Shiraz and has resulted from the active Kare-e-Bas fault segmentations. This extensional graben bounded by two fault system east-Arjan and west-Arjan to the Shahneshin and Salamati anticline. In these study using Landsat 7 ETM images with resolution 2.5 m and directional filtering in the four azimuths and semi-automatic technique for linear structure in the study area. Using the obtained data from extracted lineaments, the rose diagrams of the main strike lineaments are well confirm with field measurements of faults with N56° ± 4°E direction. The structural lineaments of the study area show that the Dasht-e-Arjan area is underlain by the limestone, sandstone, and marl. LANDSAT imagery of the area has been analyzed and interpreted in order to determine the lineament and groundwater quality across the area. The fracture is structurally controlled and mostly influences both the groundwater and surface water pollution and flow directions in the Dasht-e-Arjan. Using visual interpretation, determining the lineaments on the satellite image is very difficult and subjective, and it requires an experienced interpreter. In this study, the lineament analysis is undertaken to examine the orientation of the lineament, the relationship between lineaments and tectonic features and groundwater quality. Lineament density maps show that the lineament density is high around areas. Areas having high lineament density represent areas with relatively high groundwater pollution. Field observations agreed with the results from the analysis of the imagery.     

A simple two-step method for spatio-temporal design-based balanced sampling

We introduce a two-step method to perform spatio-temporal balanced sampling in a design-based approach. For populations with spatio-temporal trends and with anisotropic effects in the variable of interest, the prediction can be further improved by selecting samples that are well spread over the entire population in space and time. We control the spread of the sample over the population by using the volume of the corresponding three-dimensional Voronoi tessellation. Indeed, spatio-temporal design-based balanced sampling is even more efficient under the presence of a trend and anisotropic effects. We present an intensive simulation study comparing our method to other available methods for spatio-temporal sampling. Finally, we analyze real data by sampling from a population of temperature stations over six European countries.     

Aquifer vulnerability assessment using GIS and fuzzy system: a case study in Tehran–Karaj aquifer,Iran

Aquifer vulnerability assessment techniques have been developed to predict which areas are more likely than others to become contaminated as a result of activities at or near the land surface. This research focuses on the evaluation of groundwater vulnerability to pollution in an urban area. Among several assessment methods, DRASTIC has been selected for this study. ArcGIS has been used to overlay and calculate different layers and obtain the vulnerability map. In order to show the importance of fuzzy algorithms in classification, both Boolean and fuzzy algorithms were used and compared. The fuzzy algorithm could recognize the areas with low and negligible vulnerability potentials whereas the Boolean model classified them as moderate. Two sensitivity tests, the map removal sensitivity analyses and single-parameter sensitivity analysis, were performed to show the importance of each parameter in the index calculation.     

Development of a new connection for precast concrete walls subjected to cyclic loading

The Industrialized Building System (IBS) was recently introduced to minimize the time and cost of project construction. Accordingly, ensuring the integration of the connection of precast components in IBS structures is an important factor that ensures stability of buildings subjected to dynamic loads from earthquakes, vehicles, and machineries. However, structural engineers still lack knowledge on the proper connection and detailed joints of IBS structure construction. Therefore, this study proposes a special precast concrete wall-to-wall connection system for dynamic loads that resists multidirectional imposed loads and reduces vibration effects (PI2014701723). This system is designed to connect two adjacent precast wall panels by using two steel U-shaped channels (i.e., male and female joints). During casting, each joint is adapted for incorporation into a respective wall panel after considering the following conditions: one side of the steel channel opens into the thickness face of the panel; a U-shaped rubber is implemented between the two channels to dissipate the vibration effect; and bolts and nuts are used to create an extension between the two U-shaped male and female steel channels. The developed finite element model of the precast wall is subjected to cyclic loads to evaluate the performance of the proposed connection during an imposed dynamic load. Connection performance is then compared with conventional connections based on the energy dissipation, stress, deformation, and concrete damage in the plastic range. The proposed precast connection is capable of exceeding the energy absorption of precast walls subjected to dynamic load, thereby improving its resistance behavior in all principal directions.     

Assessment of changes in urban green spaces of Mashad city using satellite data

Green spaces play important functions in urban environments. Reducing air pollution, providing shade and habitat for arboreal birds, producing oxygen, providing shelter against winds, recreational and aesthetic qualities and architectural applications are the main functions of urban green spaces. With the rapid change of urban area in Mashad city during the past decades, green spaces have been fragmented and dispersed causing impairment and dysfunction of these important urban elements. The objective of this study was to detect changes in extent and pattern of green areas of Mashad city and to analyze the results in terms of landscape ecology principles and functioning of the green spaces. In this research, we classified a Landsat TM and an IRS LISS-III image belonging to the years 1987 and 2006, respectively. We then used a post-classification comparison to determine the changes in green space areas of Mashad city during the 19 years covered by the images. Then, we applied landscape ecology calculations to derive metrics that quantified pattern of the changes in the green areas. The results showed that during 19 years from 1987, a significant decrease had occurred in the extent of urban green spaces with a concomitant fragmentation resulting in downgrading and destruction of the functions and services these areas provide. We conclude that the general quality of life in the central parts of the city has been diminished. We also state that a combination of remote sensing image classification, landscape metrics assessment and vegetation indices can provide a tool for assessing life quality and its trend for urban areas.     

Treatment of Synthetic Olefin Plant Wastewater at Various Salt Concentrations in a Membrane Bioreactor

The objective of this study was to investigate the effect of salt concentration on performance of a membrane bioreactor (MBR) for treating an olefin plant wastewater. For this purpose, a lab‐scale submerged MBR with a flat‐sheet ultrafiltration membrane was used for treatment of synthetic wastewater according to oxidation and neutralization unit of olefin plant. The synthetic wastewater was adjusted to have 500 mg/L chemical oxygen demand (COD). Trials on different concentrations of sodium sulfate (Na₂SO₄) (0–20 000 ppm) in the feed were conducted under aerobic conditions in the MBR. The results showed that increasing the salt concentrations causes an increase in the effluent COD, phenol, and oil concentrations. These results are due to reduction of the membrane filtration efficiency and also decline in the microbial activity that it is indicated by decreasing the sOUR in MBR. But in all the trials, the effluent COD and oil concentration was well within the local discharge limit of 100 and 10 mg/L, respectively. These results indicate that the MBR system is highly efficient for treating the olefin plant wastewater, and although high salt concentrations decreased organic contaminant removal rates in the MBR, the effluent still met the discharge limits for treating the olefin plant wastewater.     

Capability of vis-NIR spectroscopy and Landsat 8 spectral data to predict soil heavy metals in polluted agricultural land (Iran)

Heavy metals are toxic elements that have hazardous effect on the environment. They cause soil pollution as a result of their toxicity, potential reactivity, and mobility in soils. There are so many methods for the measurement of heavy metal concentrations in soils and aquatic systems. The traditional methods used for detecting heavy metal distribution in soil involve laboratory analysis and raster sampling. Both of them are expensive and time-consuming for large areas. Remote sensing techniques are used for obtaining the earth’s surface information, and these techniques have been used in the investigations of heavy metal distributions in preliminary analysis of soils as a rapid method. Today, near-infrared reflectance spectroscopy (NIRS) of soil characteristics has been of interest as a significant object. The present investigation is focused on the detection of heavy metals in contaminated soils by the application of reflectance spectroscopy in the spectral range of 350 to 2500 nm. This study also discusses the circumstances of the applied current methods for the detection and estimation of arsenic (As), cadmium (Cd), nickel (Ni), and lead (Pb) in contaminated agricultural soils. In the first part of laboratory spectroscopy, estimations were done using heavy metal reflectance spectroscopy and partial least square regression (PLSR) approaches, while in the second part, the heavy metal estimations were done using soil organic carbon reflectance spectroscopy through the PLSR approaches. Similar to the tasks above, estimations of As, Cd, Ni, and Pb by using Landsat 8 images were done in the forms of direct and indirect methods and the distribution of heavy metals in the study area was determined. Finally, the results obtained using direct and indirect methods were compared with the wet chemical measurements of heavy metals and organic carbon. It was found that although the direct detection of heavy metals using the images of Landsat 8 produced more accurate results than the indirect detections, the results obtained from laboratory spectroscopy corresponded more with the results from atomic adsorption spectroscopy. On the other hand, based on the fact that the soil has a complex content, the use of nonlinear methods, such as artificial neural networks in predicting soil heavy metal contents, could be regarded as a trusted method.