Surficial deposits on salt diapirs (Zagros Mountains and Persian Gulf Platform, Iran): Characterization, evolution, erosion and the influence on landscape morphology

The surfaces of salt diapirs in the Zagros Mountains are mostly covered by surficial deposits, which significantly affect erosion rates, salt karst evolution, land use and the density of the vegetation cover. Eleven salt diapirs were selected for the study of surficial deposits in order to cover variability in the geology, morphology and climate in a majority of the diapirs in the Zagros Mountains and Persian Gulf Platform. The chemical and mineralogical compositions of 80 selected samples were studied mainly by X-ray powder diffraction and X-ray fluorescence. Changes in salinity along selected vertical profiles were studied together with the halite and gypsum distribution. The subaerial residuum formed from minerals and rock detritus released from the dissolved rock salt is by far the most abundant material on the diapirs. Fluvial sediments derived from this type of residuum are the second most common deposits found, while submarine residuum and marine sediments have only local importance. The mineralogical/chemical composition of surficial deposits varies amongst the three end members: evaporite minerals (gypsum/anhydrite and minor halite), carbonates (dolomite and calcite) and silicates-oxides (mainly quartz, phyllosilicates, and hematite). Based on infiltration tests on different types of surficial deposits, most of the rainwater will infiltrate, while overland flow predominates on rock salt exposures. Recharge concentration and thick accumulations of fine sediment support relatively rich vegetation cover in some places and even enable local agricultural activity. The source material, diapir relief, climatic conditions and vegetation cover were found to be the main factors affecting the development and erosion of surficial deposits. A difference was found in residuum type and landscape morphology between the relatively humid NW part of the studied area and the arid Persian Gulf coast: In the NW, the medium and thick residuum seems to be stable under current climatic conditions. Large sinkholes and blind valleys with sinking streams are common. On other diapirs, the original thick residuum is undergoing erosion and the new morphology is currently represented by salt exposures and badland-like landscapes or by fields of small sinkholes developed in the thin residuum. Models for evolution of the subaerial residuum and the diapir landscape/morphology are described in this paper. While the thick residuum with vegetation has very low erosion rates, the salt exposures and thin residuum are eroded rapidly. During wet periods (e.g. early Holocene), the diapirs rose and salt glaciers expanded as the influx of salt mass was much faster compared to erosion. After the onset of an arid climate, c. 6 ka BP, the rising of the some diapir surfaces decreased or even reversed due to acceleration of erosion thanks to vegetation degradation and changes in the residuum type and thickness.     

Environmental impact assessment on water quality deterioration caused by the decreased Ganges outflow and saline water intrusion in south-western Bangladesh

 This paper deals with an environmental impact assessment of low water flow in the river Ganges during a dry period at the Khulna and Mongla port areas in south-western Bangladesh. Large-scale surface water withdrawal in India after commissioning the Farakka Barrage causes a drastic fall in the Ganges low-flow condition within the Bangladesh territory during every dry period. The average lowest discharge in the Ganges is 552 m³/s, which is about 73% less than that in the pre-Farakka time. This has caused the deterioration of both surface and groundwater quality of the study area. Salinity is the principal cause of water quality degradation in the area. Present observation shows that the surface water of the area is sulphate-chloride dominated, which signifies high salinity whereas the groundwater is categorized as of medium to high salinity. To maintain the Rupsa River's maximum salinity below 1000 μS/cm the discharge in the Ganges should be ∼1500 m³/s, whereas that at Garai basin is ∼10 m³/s. If this present situation continues it will be a crippling blow to the environment of the area in the long term. An integrated multidisciplinary approach to hydrogeological research is urgently required to salvage the area from further deterioration. Received: 9 August 1999 · Accepted: 8 March 2000     

P–T evolution of meta-peridotite in the Penjwin ophiolite, northeastern Iraq

The Penjwin meta-peridotite rock represents one of the five main metamorphosed ultramafic bodies in Kurdistan region, Northwest Zagros Thrust Zone. It underwent at least two successively low-retrograde metamorphic events with one progressive one which all modified the original mineralogy and texture of primary dunite and harzburgite. The primary upper mantle mineral assemblage olivine?+?orthopyroxene?+?chromian spinel is replaced by olivine?+?tremolite–actiolite?+?anthopylite?+?talc?+?ferichromite?+?Cr-chlorite assemblage of amphibolite facies. The further retrograde metamorphic amphibolite facies assemblage is replaced by lizardite–chrysotile?+?Cr-chlorite?+?syn-serpentinization Cr-magnetite of lower greenschist facies. Later at the main Zagros thrust fault, low greenschist facies underwent progressive metamorphism due to the local effect of shear stress as a result of the exhumation and obduction of Penjwin ophiolite suite over Merga Red bed series during Tertiary. Lizardite–chrysotile transformed to antigorite and producing antigorite?+?carbonate?+?syn-serpentinization Cr-magnetite?+?Cr-chlorite assemblage of upper greenschist facies. Chromian spinel is concentrically zoned as a result of multi-stages retrogressive metamorphic events, in which the Cr # (Cr/(Cr?+?Al)) increases from core to rim (0.5 to 1). Three zones can be identified from core to rim: The core is primary Al-rich and mantled by ferrichromite of amphibolite facies. The most outer zone of chromian spinel grains is represented by syn-serpentinization Cr-magnetite of greenschist facies.     

Predicting groundwater level of wells in the Diyala River Basin in eastern Iraq using artificial neural network

Al-Mansourieh zone is a part of Al-Khalis City within the province of Diyala and located in the Diyala River Basin in eastern Iraq with a total area about 830 km2.Groundwater is the main water source for agriculture in this zone.Random well drilling without geological and hydraulic information has led the most of these wells to dry up quickly.Therefore,it is necessary to estimate the levels of groundwater in wells through observed data.In this study,Alyuda NeroIntelligance 2.1 software was applied to predict the groundwater levels in 244 wells using sets of measured data.These data included the coordinates of wells(x,y),elevations,well depth,discharge and groundwater levels.Three ANN structures(5-3-3-1,5-10-10-1 and 5-11-11-1)were used to predict the groundwater levels and to acquire the best matching between the measured and ANN predicted values.The coefficient of correlation,coefficient determination(R2)and sum-square error(SSE)were used to evaluate the performance of the ANN models.According to the ANN results,the model with the three structures has a good predictability and proves more effective for determining groundwater level in wells.The best predictor was achieved in the structure 5-3-3-1,with R2 about 0.92,0.89,0.84 and 0.91 in training,validation,testing and all processes respectively.The minimum average error in the best predictor is achieved in validation and testing processes at about 0.130 and 0.171 respectively.On the other hand,the results indicated that the model has the potential to determine the appropriate places for drilling the wells to obtain the highest level of groundwater.     

Shigar valley gemstones,their chemical composition and origin,Skardu, Gilgit-Baltistan,Pakistan

A variety of gemstones is being mined in the Shigar valley, Skardu, Pakistan. These include beryl (goshenite and aquamarine), tourmaline (schorl), garnet (almandine–spessartine), apatite, topaz, fluorite, zoisite, clinozoisite, and axinite, mostly occurring in complex or zoned pegmatites and metamorphic rocks. These have been analyzed using electron probe micro-analyzer and X-ray diffractometer. The mineral chemistry of each gemstone is similar to its respective typical gemstone variety with homogenous chemical composition. Field and chemical characteristics suggest that beryl, tourmaline, garnet, apatite, topaz, and fluorite are occurring in zoned pegmatites which are largely formed by magmatic hydrothermal fluids in the cavities and vugs within the intermediate zone. However, zoisite, clinozoisite, and axinite may have a metamorphic and/or metasomatic origin.     

Removal of chromium (VI) from aqueous solutions using Lewatit FO36 nano ion exchange resin

The removal of the chromium (VI) ion from aqueous solutions with the Lewatit FO36 ion-exchange resin is described at different conditions. The effects of adsorbent dose, initial metal concentration, contact time and pH on the removal of chromium (VI) were investigated. The batch ion exchange process was relatively fast and it reached equilibrium after about 90 min of contact. The ion exchange process, which is pH dependent showed maximum removal of chromium (VI) in the pH range 5.0–8.0 for an initial chromium (VI) concentration of 0.5 mg/dm³. The equilibrium related to Lewatit FO36 ion- exchange capacity and the amounts of the ion exchange were obtained using the plots of the Langmuir adsorption isotherm. It was observed that the maximum ion exchange capacity of 0.29 mmol of chromium (VLVg for Lewatit FO36 was achieved at optimum pH value of 6.0. The ion exchange of chromium (VI) on this cation-exchange resin followed first-order reversible kinetics.     

Petrogenesis of Volcanic Rocks in the Khabr-Marvast Tectonized Ophiolite:Evidence for Subduction Processes in the South-Western Margin of Central Iranian Microcontinent

Abstract: The Late Cretaceous Khabr–Marvast tectonized ophiolite is located in the middle part of the Nain–Baft ophiolite belt, at the south-western edge of the central Iranian microcontinent. Although all the volcanic rocks in the study area indicate subduction-related magmatism (e.g. high LILE (large ion lithophile elements) / HFSE (high field strenght elements) ratios and negative anomalies in Nb and Ta), geological and geochemical data clearly distinguish two distinct groups of volcanic rocks in the tectonized association: (1) group 1 is comprised of hyaloclastic breccias, basaltic pillow lavas, and andesite sheet flows. These rocks represent the Nain–Baft oceanic crust; and (2) group 2 is alkaline lavas from the top section of the ophiolite suite. These lavas show shoshonite affinity, but do not support the propensity of ophiolite.     

Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

PM10 Source Apportionment in Ahvaz,Iran, Using Positive Matrix Factorization

Source apportionment of particulate matter <10 µm in diameter (PM₁₀), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM₁₀ in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM₁₀ samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl^?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM₁₀ particles in the area, followed closely by the anthropogenic sources.     

Modelling and predicting the spatial dispersion of skin cancer considering environmental and socio-economic factors using a digital earth approach

ABSTRACT

Almost all causative factors of diseases depend on location. The Digital Earth approach is suitable for studying diseases globally. Geospatial information systems integrated with statistical models can be used to model the relationship between a disease and its causative factors. Through modelling, the most important causative factors can be extracted and the epidemiology of the disease can be observed. In this paper, skin cancer (the most common type of cancer) has been modelled based on its causative factors, including climate factors, people's occupations, nutrition habits, socio-economic factors, and usage of chemical fertiliser. To fit the model, a data framework was first designed, and then data were gathered and processed. Finally, the disease was modelled using Generalised Linear Models (GLM), a statistical model based on the location of the factors. The results of this study identify the most important causative factors together with their relative priority. Furthermore, a model was used to predict the change in skin cancer occurrences caused by a change in one of its causative factors. This work illustrates the ability of the model to predict disease occurrence. Thus, by using this Digital Earth approach, skincancer can be studied in all the key countries around the world.