Mercury in sediments of Ulhas estuary

Hg levels in water, suspended particulate matter and sediment of the Ulhas estuary are under considerable environmental stress due to the indiscriminate release of effluents from a variety of industries including chlor-alkali plants. Concentration ranges of dissolved (0.04-0.61 micro gl(-1)) and particulate (1.13-6.43 micro gg(-1)) Hg reveal a definite enhancement of levels in the estuary. The Hg burden in sediment upstream of the weir that limits the tidal influence is low (0.08-0.19 micro gg(-1)) with low C(org) content (1.8-2.9%). The high Hg content of the sediment just below the weir varies seasonally (highest concentration recorded being 38.45 micro gg(-1)) due to incremental accretion of sediment as the fresh water flow over the weir progressively decreases. The 30 km segment of the estuary sustains markedly high levels of Hg in the sediment with an exponential decrease in the seaward direction from the weir. Higher concentrations than the expected background prevail in all the estuarine cores up to the bottom, though the overall concentration decreases from about 20 micro gg(-1) in core 7 (inner estuary) to 1 micro gg(-1) in core 31 (outer estuary). The Hg in sediment is associated with C(org), while its correlation with Al, Fe and Mn is poor. The Hg profiles in cores from the Arabian Sea (stations 34, 35 and 37) have a distinct horizon of enhanced concentration in the 5-60 cm segment. Based on 210Pb dating of core 37, the sediment at the bottom of this core is inferred to have been deposited in the year 1949, roughly two year prior to the establishment of the first chlor-alkali plant and represents the background (0.06-0.10 micro gg(-1)). The Hg profiles in the offshore cores indicate a marked increase in transfer of Hg to sediment subsequent to 1980, with a peak around 1990-1992. Based on the index of geoaccumulation it is considered that the estuarine segment between stations 4 and 23 is extremely polluted, while the sediment from the open coast is moderately polluted in the top 25-30 cm with respect to Hg. The enrichment factor of Hg in the sediment is 350-700 for core 4 and decreases to 0-7 for the open-shore cores.     

Aerosol optical depth, physical properties and radiative forcing over the Arabian Sea

Summary The Arabian Sea region (4° N–20° N to 50° E–78° E) has a unique weather pattern on account of the Indian monsoon and the associated winds that reverse direction seasonally. The aerosol data, collected using ship-borne and island platforms (for 8 years from 1995 to 2002) along with MODIS (onboard TERRA satellite) data (from 2000 to 2003) have been used to evolve a comprehensive characterisation of the spatial and temporal variation in the physical, chemical, and radiative properties of aerosols over the Arabian Sea. The aerosol optical depth (AOD) was found to increase with latitude between the equator and 12° N. Over the northern Arabian Sea (regions lying north of 12° N), AODs do not show significant latitudinal variations; the average aerosol optical depth for this region was 0.29±0.12 during winter monsoon season (WMS; November to March) and 0.47±0.14 during summer monsoon season (SMS; April/May to September). The corresponding Angstrom exponents were 0.7±0.12 and 0.3±0.08, respectively. The low values of the exponent during SMS indicate the dominance of large aerosols (mainly dust particles >1 μm). The latitudinal gradient in AOD in the southern Arabian Sea is larger during SMS compared to WMS. The size distribution of aerosols shows two well-defined modes, one in the accumulation size regime and the other in the coarse size regime. During WMS, a third mode (nucleation) also appears in the sub micron range below ∼0.1 μm. The single scattering albedo does not show significant seasonal variations (remains within ∼0.93 to 0.98 through out the year). During WMS (SMS), top of the atmosphere diurnally averaged aerosol forcing remains around −6.1 (−14.3)W m⁻² over the northern Arabian Sea up to around 12° N and decreases southwards till it attains a value of −3.8 (−3.4)W m⁻² at the equator. The surface forcing remains around −16.2(−15.2)W m⁻² over the northern Arabian Sea up to 12° N and decreases southwards to a value of −5.5 (−3.5)W m⁻² at the equator. Over the north Arabian Sea, instantaneous forcing (flux change) at the surface can be as high as −50 W m⁻². The instantaneous forcing decreases with latitude in the southern Arabian Sea at a rate of ∼3 W m⁻²deg⁻¹.     

Hydrogen photoproduction ofA. Variabilis incorporated in a photobioreactor

H₂ photoproduction and nitrogenase activities in two strains ofAnabaena variabilis marked wild type ATCC 29413 and mutant PK84 exposed to thermal stress (temperature higher than the normal incubation temperature of 30°C) were studied. Cultures of both strains collected from any interval of logarithmic growth phase exhibited high H₂ photoproduction and nitrogenase activities when exposed to limited time heat shock during the assay process. In contrast, the algal H₂ photoproduction rate of both strains fluctuated with long term thermal stress caused by increasing the growth temperature from 30°C to 36°C.

The changes of nitrogenase (the key H₂ photobiosynthetic enzyme) activities in the mutant PK84 showed variation tendency similar to that of H₂ photoproduction during exposure to thermal stress, indicating that fluctuation of H₂ photoproduction in the mutant was mainly due to the variation of nitrogenase activities. A temporary maximal H₂ photoproduction in the mutant PK84 (wild type ATCC29413) was observed when cells grew at 36°C for 14 (6) days. However, the responses of nitrogenase activities in the wild type to thermal stress were not completely similar to those in the mutant in spite of similar variations of H₂ photoproduction in both strains. The data obtained in these studies suggested that the activities of other enzymes (in the wild strain) involved in H₂ photoproduction were affected by thermal stress since H₂ photoproduction maximized or dropped to 0 without variation tendency similar to that of nitrogenase activities.

Furthermore, an enhancement of H₂ photoproduction speed of the mutant strain cultured in a 4.4 L laboratory photobioreactor was also observed when it was subjected to short time continuous charge of argon, and temperature rise.

All these results indicated that high temperature plays an important role in the photo-autotrophic H₂ photoproduction, and that long term thermal stress is unfavourable for net H₂ photoproduction in both strains ofA. variabilis though short-time heat shock is conducive to H₂ photoproduction.

     

The structure of the natural stratosphere and the impact of chlorofluoromethanes on the ozone layer investigated in a 2-D time dependent model

two-dimensional time dependent model of the stratosphere incorporating the major interactions between radiative-photochemical and dynamical processes is described. The main prognostic equations considered are the thermodynamic equation and the general conservation equation for the minor chemical constituents representing the odd oxygen (O _x =O+('D)+O₃), odd hydrogen (HO _x =HO+HO₂), N₂O, odd nitrogen (NO _x =NO+NO₂+HNO₃), CF₂Cl₂, CFCl₃ and odd chlorine (Cl _x =Cl+ClO+HCl). The zonal wind and mean meridional circulations are determined diagnostically by the integration of the thermal wind equation and the stream function equation in the meridional plane espectively. The large scale eddy processes are parameterized in terms of zonal mean quantities using the generalized diffusion formulation on a sloping surface. The radiative heating and cooling and the hotochemical sources and sinks are incorporated in a form which allows for the major interactions among the minor trace constituents, temperature and mean circulation.Two integrations consisting of natural stratosphere and a stratosphere contaminated by the chlorofluoromethanes through lower boundary fluxes are carried out for 23 model years by changing the declination of the sun every day and using 6-hour time step. The model simulations of temperature, mean circulation, ozone, HO _x , N₂O and NO _x in the meridional plane for the normal stratosphere, show satisfactory agreement with the available observations. Based on the results of second integration it is found that the injection of chlorofluoromethanes in the atmosphere at the estimated current production rates can lead to significant changes in the meridional distribution of ozone, temperature and NO _x in the middle and upper stratosphere. The results also indicate that the percentage total ozone depletion increases from tropics to high latitudes and from summer to winter high latitudes. Also discussed are the results of additional experiments incorporating the reaction of HO₂ with NO and the reactions involving ClNO₃.     

Deformational and crystallization history of the Precambrian rocks in north-central Aravalli Mountain,Rajasthan, India

Large-scale structures, textures and mineral assemblages in the Precambrian rocks of the Banded Gneissic Complex and the overlying Delhi Group in north-central Aravalli Mountain reveal a complex deformational-crystallization history. In the basement Gneissic Complex at least three deformational events, D₀, D₁ and D₂, and two separate episodes of metamorphism, M₁ and M₂, are recognized. The supracrustal Delhi Rocks display only two phases of deformation, D₁ and D₂, associated with a single protracted period of metamorphism, M₂.The first phase of deformation (D₁) of the Delhi orogeny (1650-900 m.y.) produced large isoclinal folds that are overturned towards the southeast and have gentle plunges in NE and SW directions. The second phase of deformation (D₂) gave rise to tight open folds on the limbs and axial-plane surfaces of the D₁ folds. These folds generally plunge towards the N and NNW at 30°–80°. In the Basement Complex one more deformation (D₀) of the Pre-Delhi orogeny (> 2000 m.y.) is recorded by the presence of reclined and recumbent folds with W to WNW trending fold axes. The D₀ folds were superimposed by D₁ and D₂ folds during the Delhi orogeny.The three deformational events have been correlated with the crystallization periods of minerals in the rocks and a setting in time is established for this part of the Aravalli range.     

Concurrent Use of OSCAT and AltiKa to Characterize Antarctic Ice Surface Features

Radar altimetry provides an important geophysical parameter, backscatter coefficient (σ₀), which is useful in studying target surface characteristics. Ku-band (Oceansat-2 scatterometer- OSCAT) and Ka-band (SARAL-AltiKa altimeter) data are concurrently used to characterize polar surface features over the Antarctic region. Maximum-likelihood classification has been employed to classify combined data set (AltiKa and OSCAT) for discrimination among sea ice, open water, and ice sheet (interior and exterior). The sea ice region obtained using the current approach has been compared with sea ice boundary derived from passive microwave data.     

Probing Statistical Isotropy of Cosmological Radio Sources using Square Kilometre Array

There currently exist many observations which are not consistent with the cosmological principle. We review these observations with a particular emphasis on those relevant for the Square Kilometre Array (SKA). In particular, several different data sets indicate a preferred direction pointing approximately towards the Virgo cluster. We also observe a hemispherical anisotropy in the Cosmic Microwave Background radiation (CMB) temperature fluctuations. Although these inconsistencies may be attributed to systematic effects, there remains the possibility that they indicate new physics and various theories have been proposed to explain them. One possibility, which we discuss in this review, is the generation of perturbation modes during the early pre-inflationary epoch, when the Universe may not obey the cosmological principle. Better measurements will provide better constraints on these theories. In particular, we propose measurement of the dipole in number counts, sky brightness, polarized flux and polarization orientations of radio sources. We also suggest test of alignment of linear polarizations of sources as a function of their relative separation. Finally we propose measurement of hemispherical anisotropy or equivalently dipole modulation in radio sources.