Metal-enriched nanoparticles and black carbon: A perspective from the Brazil railway system air pollution

Having a better understanding of air pollutants in railway systems is crucial to ensure a clean public transport. This study measured, for the first time in Brazil, nanoparticles (NPs) and black carbon (BC) on two ground-level platforms and inside trains of the Metropolitan Area of Porto Alegre (MAPA). An intense sampling campaign during thirteen consecutive months was carried out and the chemical composition of NPs was examined by advanced microscopy techniques. The results showed that highest concentrations of the pollutants occur in colder seasons and influenced by variables such as frequency of the trains and passenger densities. Also, internal and external sources of pollution at the stations were identified. The predominance of NPs enriched with metals that increase oxidative stress like Cd, Fe, Pb, Cr, Zn, Ni, V, Hg, Sn, and Ba both on the platforms and inside trains, including Fe-minerals as hematite and magnetite, represents a critical risk to the health of passengers and employees of the system. This interdisciplinary and multi-analytical study aims to provide an improved understanding of reported adverse health effects induced by railway system aerosols.     

Anoxia over the western continental shelf of India: bacterial indications of intrinsic nitrification feeding denitrification

Studies on the Arabian Sea coastal anoxia have been of immense interest, but despite its ecological significance there is sparse understanding of the microbes involved. Hence, observations were carried out off Goa (15 degrees 30'N, 72 degrees 40'E to 15 degrees 30'N, 72 degrees 59'E) to understand the processes that mediate the changes in various inorganic nitrogen species in the water column during anoxia. Water column chemistry showed a clear distinct oxic environment in the month of April and anoxic condition in October. Our study based on microbial signatures indicated that oxygen deficit appeared as a well-defined nucleus almost 40 km away from the coast during the oxic period (April) and spreads there after to the entire water column synchronizing with the water chemistry. Striking results of net changes in inorganic nitrogen species in nitrification blocked and unblocked experimental systems show that denitrification is the predominant process in the water column consuming available nitrate ( approximately 0.5 microM) to near zero levels within approximately 72 h of incubation. These observations have been supported by concomitant increase in nitrite concentration ( approximately 4 microM). Similar studies on denitrification-blocked incubations, demonstrate the potential of nitrification to feed denitrification. Nitrification could contribute almost 4.5 microM to the total nitrate pool. It was found that the relation between ammonium and total dissolved inorganic nitrogen (DIN) pool (r=0.98, p<0.001, n=122) was significant compared to the latter with nitrite and nitrate. The occurrence of high ammonium under low phosphate conditions corroborates our observations that ammonium does not appear to be locked under low oxygen regimes. It is suggested that ammonium actively produced by detrital breakdown (ammonification) is efficiently consumed through nitrification process. The three processes in concert viz. ammonification, nitrification and denitrification appear to operate in more temporal and spatial proximity than hitherto appreciated in these systems and this gives additional cues on the absence of measurable nitrate at surface waters, which was earlier attributed only to efficient algal uptake. Hence we hypothesize that the alarming nitrous oxide input into the atmosphere could be due to high productivity driven tighter nitrification-denitrification coupling, rather than denitrification driven by extraneous nitrate.     

Modeling regional landslide susceptibility using dynamic soil moisture profiles

A landslide susceptibility mapping study was performed using dynamic hillslope hydrology. The modified infinite slope stability model that directly includes vadose zone soil moisture (SM) was applied at Cleveland Corral, California, US and Krishnabhir, Dhading, Nepal. The variable infiltration capacity (VIC-3L) model simulated vadose zone soil moisture and the wetness index hydrologic model simulated groundwater (GW). The GW model predictions had a 75% NASH-Sutcliffe efficiency when compared to California’s in-situ GW measurements. The model performed best during the wet season. Using predicted GW and VIC-3L vadose zone SM, the developed landslide susceptibility maps showed very good agreement with mapped landslides at each study region. Previous quasi-dynamic model predictions of Nepal’s hazardous areas during extreme rainfall events were enhanced to improve the spatial characterization and provide the timing of hazardous conditions.     

Effects of soil conservation practices on soil erosion and the size selectivity of eroded sediment on cultivated slopes

Soil conservation practices can greatly affect the soil erosion process, but limited information is available about its influence on the particle size distribution(PSD) of eroded sediment, especially under natural rainfall. In this study, the runoff, sediment yields, and effective/ultimate PSD were measured under two conventional tillage practices, downhill ridge tillage(DT) and plat tillage(PT) and three soil conservation practices, contour ridge tillage(CT), mulching with downhill ridge tillage(MDT), and mulching with contour ridge tillage(MCT) during 21 natural rainfall events in the lower Jinsha River. The results showed that(1) soil conservation practices had a significant effect on soil erosion. The conventional tillage of DT caused highest runoff depth(0.58 to 29.13 mm) and sediment yield(0.01 to 3.19 t hm-2). Compared with DT, the annual runoff depths and sediment yields of CT, MDT and MCT decreased by 12.24%-49.75% and 40.79%-88.30%, respectively.(2) Soil conservation practices can reduce the decomposition of aggregates in sediments. The ratios of effective and ultimate particle size(E/U) of siltand sand-sized particles of DT and PT plots were close to 1, indicating that they were transported as primary particles, however, values lower/greater than 1 subject to CT, MDT and MCT plots indicated they were transported as aggregates. The ratios of E/U of claysized particles were all less than 1 independently of tillage practices.(3) The sediments of soil conservation practices were more selective than those of conventional tillage practices. For CT, MDT and MCT plots, the average enrichment ratios(ERs) of clay, silt and sand were 1.99, 1.93 and 0.42, respectively, with enrichment of clay and silt and depletion of sand in sediments. However, the compositions of the eroded sediments of DT and PT plots were similar to that of the original soil. These findings support the use of both effective and ultimate particle size distributions for studying the size selectivity of eroded sediment, and provide a scientific basis for revealing the erosion mechanism in the purple soil area of China.     

Density variation effect on multi-ions with kinetic Alfven wave around cusp region—a kinetic approach

The kinetic Alfven waves in the presence of homogeneous magnetic field plasma with multi-ions effect are investigated. The dispersion relation and normalised damping rate are derived for low-\(\beta\) plasma using kinetic theory. The effect of density variation of \(\text{H}^{+}\), \(\text{He}^{+}\) and \(\text{O}^{+}\) ions is observed on frequency and damping rate of the wave. The variation of frequency (\(\omega\)) and normalised damping rate (\(\gamma / \varOmega_{H^{ +}} \)) of the wave are studied with respect to \(k_{ \bot} \rho_{j}\), where \(k_{ \bot} \) is the perpendicular wave number, \(\rho_{j}\) is the ion gyroradius and \(j \) denotes \(\text{H}^{+}\), \(\text{He}^{+}\) and \(\text{O}^{+}\) ions. The variation with \(k_{ \bot} \rho_{j}\) is considered over wide range. The parameters appropriate to cusp region are used for the explanation of results. It is found that with hydrogen and helium ions gyration, the frequency of wave is influenced by the density variation of \(\text{H}^{+}\) and \(\text{He}^{+}\) ions but remains insensitive to the change in density of \(\text{O}^{+}\) ions. For oxygen ion gyration, the frequency of wave varies over a short range only for \(\text{O}^{+}\) ion density variation. The wave shows damping at lower altitude due to variation in density of lighter \(\text{H}^{+}\) and \(\text{He}^{+}\) ions whereas at higher altitude only heavy \(\text{O}^{+}\) ions contribute in wave damping. The damping of wave may be due to landau damping or energy transfer from wave to particles. The present study signifies that the both lighter and heavier ions dominate differently to change the characteristics of kinetic Alfven wave and density variation is also an important parameter to understand wave phenomena in cusp region.     

Mid-term periodicities and heliospheric modulation of coronal index and solar flare index during solar cycles 22–23

We applied fast Fourier transform techniques and Morlet wavelet transform on the time series data of coronal index, solar flare index, and galactic cosmic ray, for the period 1986–2008, in order to investigate the long- and mid-term periodicities including the Rieger (\({\sim }130\) to \({\sim }190\) days), quasi-period (\({\sim }200\) to \({\sim }374\) days), and quasi-biennial periodicities (\({\sim }1.20\) to \({\sim }3.27\) years) during the combined solar cycles 22–23. We emphasize the fact that a lesser number of periodicities are found in the range of low frequencies, while the higher frequencies show a greater number of periodicities. The rotation rates at the base of convection zone have periods for coronal index of \({\sim }1.43\) years and for solar flare index of \({\sim }1.41\) year, and galactic cosmic ray, \({\sim }1.35\) year, during combined solar cycles 22–23. In relation to these two solar parameters (coronal index and solar flare index), for the solar cycles 22–23, we found that galactic cosmic ray modulation at mid cut-off rigidity (\(\hbox {Rc} = 2.43\hbox {GV}\)) is anti-correlated with time-lag of few months.     

Anisotropic model with decaying cosmological term

A spatially homogeneous and anisotropic locally rotationally symmetric Bianchi type-I spacetime with cosmological term \(\varLambda \) in \(f(R,T) \) theory has been studied. The exact solution of the field equations is obtained under a variation law of the Hubble parameter \((H) \) which yields a time dependent deceleration parameter (Banerjee and Das in Gen. Relativ. Gravit. 37:10, 2005). The model presents a cosmological scenario which describes early deceleration and late time acceleration. The physical parameters of the model have been analysed.     

Mangrove ecology,aquatic primary productivity,and fish community dynamics in the Teacapán-Agua Brava Lagoon-Estuarine system (Mexican Pacific)

Aquatic primary productivity, mangrove ecology, and fish community dynamics were investigated in the Teacapán-Agua Brava lagoon-estuarine system, the most extensive mangrove ecosystem on the Pacific coast of Mexico with three species of mangroves distributed heterogeneously (Laguncularia racemosa, Rhizophora mangle, andAvicennia germinans). Tree density was 3,203 trees ha^?1 and basal area was 14.0 m² ha^?1. Litterfall was 1,417 g m^?2 yr^?1, characteristic of a productive riverine forest. The degradation constant forLaguncularia racemosa leaves varied from 1.71 to 4.7 yr^?1 and mean annual net aquatic productivity was 0.41 g C m^?3 d^?1. There were high concentrations of humic substances (up to 150 mg l^?1) early in the wet season. Seasonal variations of the above parameters seemed closely related to the ecology of fish populations. There were 75 fish species distributed in two principal assemblages associated with wet and dry seasons. Diversity and biomass analysis indicated 18 dominant species. Total biomass of the community in this coastal system was estimated at 10 g wet wt m^?2. The highest biomass occurred in the wet season. The most common fish species wereMugil curema, Achirus mazatlanus, Galeichthys caerulescens, Arius liropus, Diapterus peruvianus, Lile stolifera, Centropomus robalito, andEucinostomus sp., all of which have fishery importance. Primary productivity and fish community ecology are controlled by habitat characteristics, river discharge, and climatic seasonality.     

Conflicts between wetland conservation and groundwater exploitation: Two case histories in Spain

The problems in two Spanish national parks located on wetlands are analyzed. The hydrogeological and ecological characteristics of the two parks are somewhat different as are their respective degrees of deterioration. The Tablas de Daimiel National Park is located on the Central Plateau of Spain. It used to consist of a marshy area of about 20 km² around the confluence of two relatively small rivers. The area was marshy mainly because it was the natural discharge zone for a Tertiary aquifer system about 100 m thick extending over an area of some 5,000 km², composed of calcareous and detrital material of continental origin. The average annual recharge has been estimated at approximately 350 hm³/yr. Current groundwater withdrawal is around 450 hm³/yr, mainly used to irrigate a surface area of some 1,000 km². This overdevelopment has led to a continuous depletion of the regional water table and eventually to the drying out of the marshy area. Spontaneous combustion or fires caused by man have occurred in about 10 km² of the desiccated areas since the spring of 1986. The Doñana National Park is located on the estuary of the River Guadalquivir. The aquifer system of the Lower Guadalquivir estuary consists essentially of a permeable formation of unconsolidated Plioquaternary materials with an area of some 3,000 km². Under the marshy area (about 1,800 km²) the aquifer system is confined below low-permeability estuary deposits which can be over 100 m thick. Around most of the marshland the aquifer crops out and is recharged by rain. The Doñana National Park is over 700 km² in size, part of which is in the marshland and part in the recharge area where the aquifer is phreatic. In the 1970s Spain's largest irrigation project using groundwater, covering a surface area of 240 km², was planned in an area bordering on the national park. The initial project has been scaled down considerably as a result of protests by conservation groups. However, it seems likely that the water table depletion as a result of pumpage for irrigation could cause a large part of the ecotone situated at the contact-line between the marshland and the phreatic aquifer to disappear. This ecotone exists because it is a natural groundwater dischange area.