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71.
Although widely investigated in relation to acid mine drainage systems at pH > 1.0, we know little about the impact of sulfuric acid (H2SO4) on the geochemistry and mineralogy of clays at pH < 1.0 (including negative pH values). Thus, laboratory batch experiments were conducted on three mixed clay samples with different mass ratios of phyllosilicates (smectite, illite, and kaolinite) to investigate the impact of H2SO4 from pH 1.0 to −3.0 for exposure periods of 14, 90, 180, and 365 days. Si and Al K- and L2,3-edge X-ray absorption near edge structure (XANES) spectroscopy were employed on these samples to determine the chemical and structural changes that occur during acidic dissolution of phyllosilicates that cannot be distinguished using X-ray diffraction analyses. A series of silicate, phyllosilicate, and Al-bearing standard compounds were also studied to provide an explanation for the observed changes in the clay samples. The Si XANES results indicated the preferential dissolution of the phyllosilicates (pH ? 1.0, t ? 14 d), the persistence of quartz even at pH ? −3.0 and t ? 365 d, and the formation of an amorphous silica-like phase that was confined to the surface layer of the altered clay samples at pH ? 0.0 and t ? 90 d). Al XANES results demonstrated dissolution of Al-octahedral layers (pH ? 1.0, t ? 14 d), the persistence of four-fold relative to six-fold coordinated Al, and the precipitation of an Al-SO4-rich phase (pH ? −1.0, t ? 90 d). An existing conceptual model of phyllosilicate dissolution under extremely acidic conditions was modified to include the results of this study.  相似文献   
72.
We introduce new symmetry-based methods to test for isotropy in cosmic microwave background (CMB) radiation. Each angular multipole is factored into unique products of power eigenvectors, related multipoles and singular values that provide two new rotationally invariant measures mode by mode. The power entropy and directional entropy are new tests of randomness that are independent of the usual CMB power. Simulated Galactic plane contamination is readily identified. The ILC– WMAP data maps show seven axes well aligned with one another and the direction Virgo. Parameter free statistics find 12 independent cases of extraordinary axial alignment, low power entropy, or both having 5 per cent probability or lower in an isotropic distribution. Isotropy of the ILC maps is ruled out to confidence levels of better than 99.9 per cent, whether or not coincidences with other puzzles coming from the Virgo axis are included. Our work shows that anisotropy is not confined to the low l region, but extends over a much larger l range.  相似文献   
73.
74.
Travel time uncertainty has significant impacts on individual activity-travel scheduling, but at present these impacts have not been considered in most accessibility studies. In this paper, an accessibility evaluation framework is proposed for urban areas with uncertain travel times. A reliable space-time service region (RSTR) model is introduced to represent the space-time service region of a facility under travel time uncertainty. Based on the RSTR model, four reliable place-based accessibility measures are proposed to evaluate accessibility to urban services by incorporating the effects of travel time reliability. To demonstrate the applicability of the proposed framework, a case study using large-scale taxi tracking data is carried out. The results of the case study indicate that the proposed accessibility measures can evaluate large-scale place-based accessibility well in urban areas with uncertain travel times. Conventional place-based accessibility indicators ignoring travel time reliability can significantly overestimate the accessibility to urban services.  相似文献   
75.
A three-dimensional numerical model is used to simulate sea level and velocity variations in the South China Sea for 1992–1995. The model is driven by daily wind and daily sea surface temperature fields derived from the NCEP/NCAR 40-year reanalysis project. The four-year model outputs are analyzed using time-domain Empirical Orthogonal Functions (EOF). Spatial and temporal variations of the first two modes from the simulation compare favorably with those derived from satellite altimetry. Mode 1, which is associated with a southern gyre, shows symmetric seasonal reversal. Mode 2, which contributes to a northern gyre, is responsible for the asymmetric seasonal and interannual variations. In winter, the southern and northern cyclonic gyres combine into a strong basin-wide cyclonic gyre. In summer, a cyclonic northern gyre and an anticyclonic southern gyre form a dipole with a jet leaving the coast of Vietnam. Interannual variations are particularly noticeable during El Niño. The winter gyre is generally weakened and confined to the southern basin, and the summer dipole structure does not form. Vertical motions weaken accordingly with the basin-wide circulation. Variations of the wind stress curl in the first two EOF modes coincide with those of the model-derived sea level and horizontal velocities. The mode 1 wind stress curl, significant in the southern basin, coincides with the reversal of the southern gyre. The mode 2 curl, large in the central basin, is responsible for the asymmetry in the winter and summer gyres. Lack of the mode 2 contribution during El Niño events weakens the circulation. The agreement indicates that changes in the wind stress curl contribute to the seasonal and interannual variations in the South China Sea.  相似文献   
76.
A new hominid skeleton from Sterkfontein Member 2 attaches to foot bones recovered from loose blocks during the 1980s and first described in 1995. Several flowstone horizons are present above and below the skeleton and have given clear palaeomagnetic signatures. Five changes in magnetic polarity have been identified; when constrained by the available biostratigraphy, this sequence can be placed confidently between 3.22 and 3.58 Ma. Interpolation of sedimentation rates over the small intervals between reversals allows this range to be reduced to 3.30–3.33 Ma. The skeleton is thus the oldest yet discovered and is considered to belong to a species of Australopithecus other than africanus. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
77.
Traditionally seismic design of structures supported on piled raft foundation is performed by considering fixed base conditions, while the pile head is also considered to be fixed for the design of the pile foundation. Major drawback of this assumption is that it cannot capture soil-foundation-structure interaction due to flexibility of soil or the inertial interaction involving heavy foundation masses. Previous studies on this subject addressed mainly the intricacy in modelling of dynamic soil structure interaction(DSSI) but not the implication of such interaction on the distribution of forces at various elements of the pile foundation and supported structure. A recent numerical study by the authors showed significant change in response at different elements of the piled raft supported structure when DSSI effects are considered. The present study is a limited attempt in this direction, and it examines such observations through shake table tests. The effect of DSSI is examined by comparing dynamic responses from fixed base scaled down model structures and the overall systems. This study indicates the possibility of significant underestimation in design forces for both the column and pile if designed under fixed base assumption. Such underestimation in the design forces may have serious implication in the design of a foundation or structural element.  相似文献   
78.
基于IC卡综合换乘信息的公交乘客上车站点推算   总被引:1,自引:0,他引:1  
现有研究在缺少公交车运营信息的情况下,利用公交线间正交换乘信息的方法来识别公交车持卡乘客的上车站点,但在实际运用中很多班次无正交换乘的乘客,容易导致公交乘客上车站点匹配困难。因此,本文提出了一种基于IC卡综合换乘信息的公交乘客上车站点推算方法,该方法充分利用IC卡数据中的综合换乘信息(公交线间的正交和非正交换乘信息、地铁和公交线间的换乘信息)与公交网数据确定班次行驶方向,对班次内的乘客进行分组,充分利用综合换乘信息确定基准组及其对应的上车站点;然后,通过最小偏差规则匹配待定组的上车站点,实现公交乘客上车站点的推估。利用换乘信息确定班次行驶方向弥补了现有研究无法确定班次行驶方向的不足,使公交乘客上车站点推算方法更科学;最后,基于2011年8月的“深圳通”IC卡数据进行实例分析,对比只利用正交换乘信息确定的基准组数量和利用综合换乘信息确定的基准组数量,结果表明:该方法可使确定上车站点的组数占总组数的比值提高,克服了只利用正交换乘信息推算上车站点方法中存在的单个班次无基准组从而无法进行站点匹配的困难。本文方法比只利用正交换乘信息匹配站点,具有更高的可行性与准确率。  相似文献   
79.
Coastal and terrestrial landforms that formed with lowered relative sea levels during the early postglacial period in Atlantic Canada were submerged during the Holocene transgression. However, these landforms are seldom seen on sea floor imagery. Factors that contribute to their destruction include the brevity of sea level lowstands and high wave energy on shallow modern shelves. We identify one situation within which preservation has been relatively good: large coastal lakes that existed for many thousands of years before being connected to the ocean by rising sea level in the mid-Holocene. We describe Bedford Basin, near Halifax, Nova Scotia, and deal more exhaustively with the Bras d'Or Lakes, an inland sea in Cape Breton, Nova Scotia. The preservation of shore platforms, barrier beaches and spits, and fluvial systems, was due to the rapid onset of the transgression and the relatively low wave energy in the subsequent marine phases. The well-preserved early Holocene coastlines are highly favourable targets in the search for evidence of human occupation in the early- to mid-Holocene.  相似文献   
80.
Clustering of temporal event processes   总被引:1,自引:0,他引:1  
A temporal point process is a sequence of points, each representing the occurrence time of an event. Each temporal point process is related to the behavior of an entity. As a result, clustering of temporal point processes can help differentiate between entities, thereby revealing patterns of behaviors. This study proposes a hierarchical cluster method for clustering temporal point processes based on the discrete Fréchet (DF) distance. The DF cluster method is divided into four steps: (1) constructing a DF similarity matrix between temporal point processes; (2) constructing a complete linkage hierarchical tree based on the DF similarity matrix; (3) clustering the point processes with a threshold determined by locating the local maxima on the curve of the pseudo-F statistic (an index which measures the separability between clusters and the compactness in clusters); and (4) identifying inner patterns for each cluster formed by a series of dense intervals, each of which contains at least one event of all processes of the cluster. The contributions of the article are: (1) the proposed DF cluster method can cluster temporal point processes into different groups and (2) more importantly, it can identify the inner pattern of each cluster. Two synthetic data sets were created to illustrate the DF distance between temporal point process clusters (the first data set) and validate the proposed DF cluster method (the second data set), respectively. An experiment and a comparison with a method based on dynamic time warping show that DF cluster successfully identifies the preconfigured patterns in the second synthetic data set. The cluster method was then applied to a population migration history data set for the Northern Plains of the United States, revealing some interesting population migration patterns.  相似文献   
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