Hornblende-dehydration melting in mafic rocks and the link between massif-type charnockite and associated granulites,Eastern Ghats Granulite Belt,India

A massif-type (intrusive) charnockite body in the Eastern Ghats granulite belt, India, is associated with hornblende-bearing mafic granulite, two-pyroxene granulite and enderbitic granulite. The charnockite is characterised by pervasive gneissic foliation (S₁). This is axial planar to the folded layers of hornblende-bearing mafic granulite (F₁ folds), indicating that the granulite protoliths were present before the development of S₁. Two-pyroxene granulite and enderbitic granulite occur as lenticular patches disposed along the foliation and hence could be syngenetic to S₁. The tonalitic to granodioritic, metaluminous to weakly peraluminous compositions and relatively high Sr/Rb of the charnockite are consistent with its derivation by partial melting of a mafic protolith. Strong Y depletion, lack of Sr depletion and strongly fractionated REE patterns with high (La/Yb)_N ratio, but relatively lower HREE (Gd/Lu) fractionation with marked positive Eu anomalies, suggest major residual hornblende (as well as garnet), but not plagioclase, consistent with the hornblende dehydration melting in the source rocks. Such a residual mineralogy is broadly similar to those of some of the hornblende-bearing mafic granulite inclusions, which have compositional features indicative of a restitic nature. Quantitative modelling supports an origin for the charnockite melts by partial melting of a hornblende-rich mafic granulite source, although source heterogeneity is very likely given the rather variable trace element contents of the charnockite. The whole-rock and mineral compositions of the two-pyroxene granulites and enderbitic granulites are consistent with them representing peritectic phase segregations of hornblende-dehydration melting. A clockwise P-T path implies that melting could have occurred in thickened continental crust undergoing decompression.Editorial responsibility: T.L. Grove     

Compression mechanisms of coesite

 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s₂₃ and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.     

The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer

The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.     

The Arunta Inlier: a complex ensialic mobile belt in central Australia. Part 1: Stratigraphy,correlations and origin

The Arunta Inlier is a 200 000 km² region of mainly Precambrian metamorphosed sedimentary and igneous rock in central Australia. To the N it merges with similar rocks of lower metamorphic grade in the Tennant Creek Inlier, and to the NW it merges with schist and gneiss of The Granites‐Tanami Province. It is characterized by mafic and felsic meta‐igneous rocks, abundant silicic and aluminous metasediments and carbonate, and low‐ to medium‐pressure metamorphism. Hence, the Arunta Inlier is interpreted as a Proterozoic ensialic mobile belt floored by continental crust. The belt evolved over about 1500 Ma, and began with mafic and felsic volcanism and mafic intrusion in a latitudinal rift, followed by shale and limestone deposition, deformation, metamorphism and emergence. Flysch sedimentation and volcanism then continued in geosynclinal troughs flanking the ridge of meta‐igneous rocks, and were followed by platform deposition of thin shallow‐marine sediments, further deformation, and episodes of metamorphism and granite intrusion.     

Institutional forces and retail change: a case study of Metropolitan Toronto

There is a growing interest in the development of purpose-built shopping centres, which now dominate the retail environments of many cities. Much of the past research has been directed at the impact of shopping centres on more traditional retail structures. More recently, however, there has been a recognition of the importance of those institutional forces that shape the internal character of shopping centres and ultimately determine their economic impact. This paper draws attention to these factors and discusses the control that leasing agreements and corporate policy have on shopping centre development. The whole discussion is set within the framework of metropolitan Toronto, which has for some time experienced the full impact of these institutional forces.     

The origin of reaction textures in mantle peridotite xenoliths from Sal Island, Cape Verde: the case for “metasomatism” by the host lava

Reaction zones around minerals in mantle xenoliths have been reported from many localities worldwide. Interpretations of the origins of these textures fall into two groups: mantle metasomatic reaction or reaction during transport of the xenoliths to the surface. A suite of harzburgitic mantle xenoliths from Sal, Cape Verde show clear evidence of reaction during transport. The reactions resulted in the formation of olivine–clinopyroxene and Si- and alkali-rich glass reaction zones around orthopyroxene and sieve-textured clinopyroxene and sieve textured spinel, both of which are associated with a Si- and alkali-rich glass similar to that in the orthopyroxene reaction zones. Reaction occurred at pressures less than the mantle equilibration pressure and at temperatures close to the liquidus temperature of the host magma. In addition, there is a clear spatial relation of reaction with the host lava: reaction is most intense near the lava/xenolith contact. The residence time of the xenoliths in the host magma, determined from Fe–Mg interdiffusion profiles in olivine, was approximately 4 years. Our results cannot be reconciled with a recent model for the evolution of the mantle below the Cape Verde Archipelago involving mantle metasomatism by kimberlitic melt. We contend that alkali-rich glasses in the Sal xenoliths are not remnants of a kimberlitic melt, but rather they are the result of reaction between the host lava or a similar magma and xenolith minerals, in particular orthopyroxene. The formation of a Si- and alkali-rich glass by host magma–orthopyroxene reaction appears to be a necessary precursor to formation of sieve textured spinel and clinopyroxene.     

Effects of melt viscosity and silica activity on the rate and mechanism of quartz dissolution in melts of the CMAS and CAS systems

The dissolution rate of quartz in melts of the CMAS and CAS systems at 1,600°C and 1.5 GPa is a function of both the silica activity of the melt and its viscosity. In melts with low silica activity quartz dissolves more quickly than in higher aSiO₂ melts regardless of viscosity. For melts with equal aSiO₂, dissolution is faster in the low viscosity melt. Quartz dissolution is controlled by interface kinetics in three of the four melts used in this study for times much greater than predicted by the model of Zhang et al. (in Contrib Mineral Petrol 102:492–513 1989). One melt which was previously shown to adhere to the predicted behaviour at lower temperature shows a significant activation time at higher temperature. All the dissolution data indicate that there are likely to be three distinct domains of dissolution behaviour, although the details of why a particular melt falls in any one domain require further study. Although the current database is small, the relationship between quartz solubility and the dissolution constant indicate that solubility may be a useful parameter for predicting dissolution rates, particularly if silica activity and melt viscosity are also known.     

Application of particle dynamics to derive a general circulation in low latitudes

Summary In Section 1 are set out the reasons for the use of particle dynamics in this investigation. In Section 2 are solved the equations of motion for particles constrained to move along a horizontal surface under the action of a constant meridional pressure gradient force to obtain (a) velocities in spherical polar co-ordinates with naturally varying Coriolis terms, and (b) velocities and trajectories in plane cartesian co-ordinates in which the Coriolis parameter is assumed constant. Results obtained in each system are compared, showing that the plane co-ordinates as used are not significantly inaccurate, and trajectories of air particles obtained by application significantly inaccurate, and trajectories of air particles obtained by application of this system in steps of 5° of latitude are plotted to show the production of belts of convergence at some distance from the equator under the action of meridional pressure gradient forces.The approximation of these idealised particle trajectories to actual streamlines of the air flow are discussed in Section 3, and the concept of the production of belts of convergence is used to formulate a theory of formation and maintenance of the sub-tropical anticyclones. In Section 4 this theory is applied to observed average temperature data and the calculated results compared with observed average pressure data. A possible synoptic application of the theory is then indicated in Section 5.

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Zusammenfassung Im ersten Abschnitt werden Gründe für die Anwendung der Dynamik von Massenteilchen in der vorliegenden Arbeit dargelegt. Abschnitt 2 enthält die Lösungen der Gleichungen für die Bewegung von Massenteilchen auf horizontalen Flächen unter der Einwirkung eines konstanten meridionalen Druckgradienten. Die Lösungen ergeben a) die Geschwindigkeiten in sphärischen Polarkoordinaten mit variablem Coriolis-Term (entsprechend natürlichen Verhältnissen) und b) Geschwindigkeiten und Trajektorien in ebenen kartesischen Koodinaten in denen der Coriolis-Parameter als konstant angenommen wird. Die Ergebnisse für beide Koordinatensysteme werden verglichen und es zeigt sich, daß bei Verwendung der ebenen Koordinaten keine wesentlichen Ungenauigkeiten auftreten. Zeichnet man schrittweise von 5 zu 5° (Fig. 1) die Trajektorien der Luftteilchen, so ergeben sich als Folge der meridionalen Druckgradienten Konvergenzzonen in einigem Abstand vom Äquator.Die Annäherung dieser idealisierten Trajektorien an tatsächliche Stromlinien der Luft wird in Abschnitt3 diskutiert. An Hand der Vorstellungen von der Entstehung der Konvergenzzonen wird eine Theorie der Entstehung und Erhaltung subtropischer Antizyklonen gegeben. Im vierten Abschnitt wird diese Theorie auf beobachtete Mitteltemperaturen angewendet und die Ergebnisse der Berechnung werden mit beobachteten mittleren Luftdruckwerten verglichen. Auf eine mögliche synoptische Anwendung der vorliegenden Ergebnisse wird in Abschnitt 5 hingewiesen.

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Résumé La première partie contient les motifs de l'emploi de la dynamique de points pesants dans la présente étude. La deuxième partie donne les solutions des équations du mouvement de points pesants sur des surfaces horizontales sous l'effet d'un gradient méridien constant. Ces solutions fournissent les vitesses en coordonnées polaires sphériques avec un terme Coriolis variable, ainsi que les vitesses et les trajectoires en coordonnées cartésiennes planes en admettant un paramètre de Coriolis constant. On compare les résultats pour les deux systèmes de coordonnées et l'on constate que l'emploi des coordonnées planes n'introduit pas d'erreurs appréciables. Si l'on dessine les trajectoires de 5 en 5 degrés on voit apparaître des zones de convergence à quelque distance de l'équateur par suite des gradients méridiens.Dans la troisième partie on discute la similitude plus ou moins grande de ces trajectoires idéalisées avec les lignes de courant réelles. Parant de l'origine possible des zones de convergence, on établit une théorie de l'origine et du maintien des anticyclones subtropicaux. Dans la quatrième partie on applique cette théorie aux températures moyennes observées et l'on compare les résultats avec les valeurs moyennes observées de la pression. Dans la cinquième partie enfin on montre l'application possible des résultats obtenus à la synoptique.

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With 1 Figure.

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This paper is published with the permission of the Director of the meteorological Office.