The role of fluids in the formation of talc deposits of Rema area,Kumaun Lesser Himalaya

Talc deposits of Rema area in the Kumaun Inner Lesser Himalaya are hosted within high magnesium carbonates of the Proterozoic Deoban Formation. These deposits occur as irregular patches or pockets mainly within magnesite bodies, along with impurities of magnesite, dolomite and clinochlore. Textures represent different phases of reactions between magnesite and silica to produce talc. Petrography, XRD and geochemistry reveal that the talc has primarily developed at the expense of magnesite and silica, leaving dolomite largely un-reacted. Early fluid inclusions in magnesite and dolomite associated with talc are filled with H₂O+NaCl+KCl ± MgCl₂ ± CaCl₂ fluids, which represent basin fluid system during diagenesis of carbonates. Their varied degree of re-equilibration was although not pervasive but points to increased burial, and hence requires careful interpretation. H₂O-CO₂ fluid with XCO₂ between 0.06 and 0.12 was equilibrated with talc formation. The reaction dolomite+quartz → talc was not extensive because T-X_CO2 was not favourable, and talc was developed principally after magnesite+quartz.     

An analytical source function for a coupled hybrid wave model

An analytical form for the source function is formulated by comparing the fetch-limited approximation of the Ocean Wave Transport equation and the empirical equation for the fetch-dependent wave forecast nomograms. The source function thus generated has been utilised in the numerical model based on Toba’s formulation of wave transport equation and tested for the seas around the Indian subcontinent (5°S to 25°N latitude; 45°E to 100°E longitude). The grid averaged hindcast wave heights are found to be moderately matching with the GEOSAT altimeter measured significant wave heights of the 1987–1989 period, particularly for waves higher than 1 meter.     

Geotechnical Properties of Low Calcium and High Calcium Fly Ash

In this paper, a comparative study has been made for physical and engineering properties of low calcium and high calcium Indian fly ash. The grain size distribution of fly ash is independent of lime content. Fly ash particles of size >75 μm are mostly irregular in shape whereas finer fractions are spherical for low calcium fly ash. For high calcium fly ash, chemical and mineralogical differences have been observed for different size fractions. Compared to low calcium fly ash, optimum moisture content is low and maximum dry density is high for high calcium fly ash. Optimum moisture content is directly proportional and maximum dry density is inversely proportional to the carbon content. The mode and duration of curing have significant effect on strength and stress–strain behavior of compacted fly ash. The gain in strength with time for high calcium fly ash is very high compared to that of low calcium fly ash due to presence of reactive minerals and glassy phase.     

Charnockite genesis across the Archaean–Proterozoic terrane boundary in the South Indian Granulite Terrain: Constraints from major–trace element geochemistry and Sr–Nd isotopic systematics

Major, trace element compositions and Sr–Nd isotopic characteristics of charnockitic gneisses from the Southern Granulite Terrain (SGT), South India are presented. The study region encompasses the central segment of the Cauvery Shear Zone system (CSZ) and regions within the Madurai Block (MB) immediately south of it (designated here as the CSZ/MB and MB domains). Differences in the compositions and source characteristics between charnockitic rocks of the CSZ vis-à-vis those of the CSZ/MB and MB regions are highlighted. Foremost, the charnockites and enderbites of the CSZ show highly fractionated REE patterns with positive Eu-anomalies, depleted HREE, Y and near chondritic εNd₀ and initial-⁸⁷Sr/⁸⁶Sr at ca. 2.5 Ga, consistent with hydrous partial melting of amphibolitic crust with residual garnet and hornblende for the parental melts. By contrast, modeled at ca. 1.8 Ga and 0.8 Ga, the CSZ/MB and MB charnockitic rocks, which show a wider range of Ti and P, relatively lower degree of HREE depletion, commonly negative Eu-anomalies and undepleted Y, present clear evidence for involvement of Archaean crustal components in sources of their magmatic protoliths. There is also evidence for significant intracrustal melting processes within a thickened crust at elevated temperatures between 800 and 1000 °C. Implications to the controversial Archaean–Neoproterozoic terrane boundary problem of the SGT are discussed.     

Shallow lithosphere-asthenosphere boundary beneath Cambay Rift Zone of India: Inferred presence of carbonated partial melt

A vast area between Phalodi in Jodhpur and Pokaran in Jaisalmer district of western Rajasthan, is occupied distinctly by rocky, shallow gravelly surfaces and occasional hills. These surfaces exhibit quartz and quartzite pebbles, angular, sub-angular and few rounded sandstone gravels, have slightly convex outline and can be best described as desert pavements. Such land features assume significance because of their extent and variability under a dominantly dry aeolian environment. Morphology and distributional pattern of such formations indicate that sediments are either of in situ origin or may have been transported to a short distance. The present study is based on field level assessment of such surfaces in the above two desert districts. Over much of the area, the profile shows a surficial concentration of gravels followed by thick sand and silt mixed with gravels and then the parent material. There are also occasional rock outcrops of very low relief exhibiting vertical, horizontal and conchoidal pattern of fractures over these surfaces near Pokaran and north of Jaisalmer which indicate disintegration of rocks under extreme diurnal fluctuation of temperature. Such manifestations in the morphology indicate impact of both thermal as well as aeolian processes. In the east of Jaisalmer town near Basanpir and Bhojka, the pavement surfaces are found covered with abundant sub-rounded to rounded pebbles and cobbles. This type of condition would indicate a profound action by fluvial activities followed by wind sorting. Our study found significant spatial variability in the distribution of pavement surfaces, which carried imprints of climatic fluctuations and environment of deposition during Holocene.     

Rectangular tank surface aerators: scale up criteria and energy conservation

Surface aeration experiments were conducted in two types of rectangular tanks of aspect ratios i.e., length to width ratio (L/W) of 1.5 and 2 and developed simulation equations to correlate the oxygen transfer coefficient, k and power number, P₀ with a parameter governing theoretical power per unit volume X. The parameter X is defined as equal to F^4/3R^1/3, where F and R are impellers’ Froude and Reynolds numbers respectively). Results have shown that the P₀ can not be simulated singularly with either Reynolds number, R or Froude number, F, which results in scale-effects; there appears to be a need to incorporate the effects of both F and R. It was found that P⁰ is uniquely related to X for rectangular aeration tanks of both aspect ratios, however, such relationships are different depending upon the aspect ratios. It has been demonstrated that energy can be saved substantially if the aeration tanks are run at relatively higher input powers. It is also demonstrated that smaller sized tanks are more energy conservative and economical when compared to big sized tanks, while aerating the same volume of water, and at the same time by maintaining a constant input power in all the tanks irrespective of their size.     

Studies on flow characteristics of coal–oil–water slurry system

Experiments were carried out to investigate the rheological properties of coal–oil–water suspension containing solids of different sizes. Two different coal samples with mean particle sizes of 120 mesh, 175 mesh and 220 mesh were used. The coal concentration was varied from 5% to 25% by weight. Sodium silicate has been used as an additive to study the behavior of the variation of average viscosity of the suspension. A generalized correlation has been developed to predict the average viscosity of suspension in terms of particle diameter of the coal, concentration of coal, viscosity of the suspending medium and the concentration of water. Experimental investigations revealed that coal–oil–water suspensions show an increase in the viscosity with decrease in coal size but with the addition of an additive, the average viscosity tends to decrease initially up to a certain optimum dosages and thereafter it increases with further addition of additives. Two empirical correlations are proposed for average viscosity of the coal–oil–water suspension, μ_sL in terms of physical properties of the solid and viscosity of the suspending medium with and without additives.     

Sources and processes governing rainwater chemistry in New Delhi,India

Rainwater plays an important role in scavenging of aerosols and gases from atmosphere, and its chemistry helps to understand the relative contributions of atmospheric pollution sources. The present work is aimed to understand and explain the sources, seasonal patterns and the processes thereof affecting rainwater chemistry in an urban environment of Delhi, India. Rainwater samples (n = 111) collected throughout the year in New Delhi showed alkalinity in general. Eight rainwater samples, collected in late monsoon and winter season, had pH less than 5.6 indicating that Delhi continues to face the prospects of acid rain despite the introduction of compressed natural gas as the clean fuel in city transport. Organic acids could be the possible contributors of acidity in rainwater samples having the fractional acidity (FA) value of 0.174, which is greater than the annual average FA (0.011) and the (Ca²⁺ + Mg²⁺ + NH₄ ⁺)/(SO₄ ^2? + NO₃ ^?) ration of more than one. Average acid neutralization factors of cations decrease in the order Ca²⁺ (1.01) > NH₄ ⁺ (0.77) > Mg²⁺ (0.10). However, neutralization by Ca²⁺ dominates only in summer season as cation-rich dust is transported from the Great Indian Thar Desert to this region by strong summer S–SW winds, while NH₄ ⁺ dominates in rainwater of other three sampling seasons. Identified dominant sources for soluble ions in rainwater are (1) non-silicate crustal source for carbonates and sulfates of Ca and Mg, (2) emissions from catalytic convertor-fitted vehicles and agriculture fields for NH₃ and (3) mixed anthropogenic sources for SO₄ ^2?, NO₃ ^? and Cl^?. Rainwater chemistry showed significant seasonal variations. This could be due to the changes in relative proportions of natural and anthropogenic sources of soluble ions to rainwater. Dominance of anthropogenic sources over crustal sources can result in acidic rains, which can adversely affect the environment and human health in this region.