Reconstruction of Physicochemical Environment of Hydrothermal Mineralization at Malanjkhand Copper Deposit,Central India: Constraints from Sulfur Isotope Ratios in Pyrite,Molybdenite and Chalcopyrite

δ³⁴S values of pyrite, molybdenite and chalcopyrite were determined from the Malanjkhand copper deposit. These minerals constitute the primary sulfide phases that were deposited after the initial magnetite deposition in the main orebody and host granitoid. Pyrite exhibits a depleted range of values (?2.63 to ?0.56‰), chalcopyrite, a very narrow range of values around zero (?0.039 to 0.201‰) and molybdenite furnishes a range of enriched values (0.68 to 1.98‰). On back calculation of the δ³⁴S values of H₂S in the fluid from which the minerals were likely to have precipitated, using standard expressions for equilibrium fractionation at the temperature range obtained from fluid inclusion and mineral fluid equilibria, it is observed that H₂S in the fluid at pyrite deposition was depleted and gradually became enriched towards molybdenite and chalcopyrite deposition. This trend is best explained as being due to inorganic reduction of SO₄^2? in the fluid and is very much in agreement with the paragenetic sequence indicating increasing activity of H₂S in the fluid. The very restricted range in the δ³⁴S values of sulfide minerals in the fluid does indicate a single, possibly magmatic, source of sulfur that also agrees well with the earlier deduced model of genesis of the deposit as an ancient geothermal system associated with granitic magmatism.     

Harmonics of Low Amplitude Anisotropic Wave Train Events in Cosmic Ray Intensity

The unusually low amplitude anisotropic wave train events (LAWEs) in cosmic ray intensity using the ground based Deep River neutron monitor data has been studied during the period 1991–1994. It has been observed that the amplitude of the diurnal anisotropy for LAWE events significantly remains quite low and statistically constant as compared to the quiet day annual average amplitude for majority of the events. The time of maximum of the diurnal anisotropy of LAWE significantly shifts towards earlier hours as compared to the co-rotational direction and remains in the direction of quiet day annual average anisotropy for majority of the events. On the other hand, the amplitude of the semi/tri-diurnal anisotropy remains statistically the same and high whereas, phase shift towards later hours as compared to the quiet day annual average values for majority of the LAWEs. The diurnal anisotropy vectors are found to shifts towards earlier hours for 50% of the events; whereas they are found to shifts towards later hours for rest of the events (50%) relative to the average vector for the entire period. It is also noted that the amplitude of these vectors are found to increase significantly with the shift of the diurnal anisotropy vectors towards later hours. The high-speed solar wind streams do not play a significant role in causing the LAWE events on short-term basis, however it may be responsible in causing these events on long-term basis (Mishra and Mishra 2007). Occurrence of LAWE is dominant, when the polarity of Bx and Bz remains positive and polarity of By remains negative, which is never been reported earlier. The amplitude of first harmonic shows good anti-correlation and direction of first and third harmonic shows nearly good anti-correlation with solar wind velocity, whereas the direction of second harmonic shows nearly good anti-correlation with interplanetary magnetic field strength.     

Effect of magnetic activity on ionospheric time delay at low latitude

The purpose of this work is to investigate the effect of magnetic activity on ionospheric time delay at low latitude Station Bhopal (geom. lat. 23.2°N, geom. long. 77.6°E) using dual frequency (1575.42 and 1227.60 MHz) GPS measurements. Data from GSV4004A GPS Ionospheric Scintillation and TEC monitor (GISTM) have been chosen to study these effects. This paper presents the results of ionospheric time delay during quiet and disturbed days for the year 2005. Results show that maximum delay is observed during quiet days in equinoxial month while the delays of disturbed period are observed during the months of winter. We also study the ionospheric time delay during magnetic storm conditions for the same period. Results do not show any clear relationship either with the magnitude of the geomagnetic storm or with the main phase onset (MPO) of the storm. But most of the maximum ionospheric time delay variations are observed before the main phase onset (MPO) or sudden storm commencement (SSC) as compared to storm days.     

Low amplitude anisotropic wave trains in cosmic rays

In the present study the occurrence of an unusual class of low amplitude anisotropic wave trains in the cosmic ray neutron intensity, which is distinctly different from the average diurnal variation as well as from other recognized types of low amplitude anisotropic wave trains are noted and the directional distribution in the interplanetary space determined. The major objective of this paper is to study the first three harmonics of low amplitude anisotropic wave trains of cosmic ray intensity over the period 1981–1994 for Deep River neutron monitoring station. The significant characteristic of these events is that the low amplitude wave trains shows a maximum intensity of diurnal component in a direction earlier than 18:00 h/co-rotational direction. It is noticed that these events are not caused either by the high-speed solar wind streams or by the sources on the Sun responsible for producing these streams such as polar coronal holes. However the possibility of occurrence of these events during high-speed solar wind streams cannot be denied. The occurrence of low amplitude events is dominant for positive polarity of B_z. The disturbance storm time index i.e. D_st, remains consistently negative only for majority of the low amplitude wave train events, which is never been reported earlier. The amplitude as well as direction of first two harmonics seems to remain unaffected with the variation in the D_st and A_p-index. However, the amplitude as well as direction of third harmonic found to deviates with the increase of D_st and A_p-index. The corotating streams produce significant deviations in cosmic ray intensity as well as in solar wind speed during low amplitude anisotropic wave train events.     

Distributions of O3, CO and NMHCs over the rural sites in central India

The surface level measurements of O₃, CO, CH₄ and light NMHCs were made at eight different rural sites in the central part of India during February, 2004. The online analyzer was used for in-situ measurement of O₃ while air samples were collected for the analyses of CO, CH₄ and NMHCs using the gas chromatography techniques. The average mixing ratios of O₃, which were in the range of 60–90 ppbv, are significantly higher compared to the typical values reported for urban sites of India. The increase rates of O₃ in the forenoon hours were estimated to be in the range of about 8.8–10 ppbv h⁻¹. The slopes of ∆O₃/∆CO, which is an indicator of the efficiency of photochemical production, were in the range of 0.24–0.33 ppbv ppbv⁻¹. However, levels of primary pollutants e.g., NMHCs, CO, etc. at these sites were much lower than urban sites, but higher compared to previously observed values surrounding marine region of India. The estimated ratios of NMHCs and CO indicate fossil fuel combustion process as the dominant source of primary pollutants in this corridor.     

Emission characteristic of ozone related trace gases at a semi-urban site in the Indo-Gangetic plain using inter-correlations

Measurements of surface O₃, CO, NO_x and light NMHCs were made during December 2004 at Hissar, a semi-urban site in the state of Haryana in north-west region of the Indo-Gangetic Plain (IGP). The night-time O₃ values were higher when levels of CO, NO and NO₂ were lower but almost zero values were observed during the episodes of elevated mixing ratios of CO (above 2000 ppbv) and NO_x (above 50 ppbv). Slopes derived from linear fits of O₃ versus CO and O₃ versus NO_x scatter plots were also negative. However, elevated levels of O₃ were observed when CO and NO_x were in the range of 200–300 ppbv and 20–30 ppbv, respectively. Slope of CO-NO_x of about 33 ppbv/ppbv is much larger than that observed in the US and Europe indicating significant impact of incomplete combustion processes emitting higher CO and lesser NO_x. Correlations and ratios of these trace gases including NMHCs show dominance of recently emitted pollutants mostly from biomass burning at this site.     

Intra-seasonal variability in Oceansat-2 scatterometer sea-surface winds over the Indian summer monsoon region

In September 2009, the Indian Space Research Organisation launched a Ku-band microwave scatterometer (OSCAT) onboard the polar orbiting satellite ‘Oceansat-2’. In this article, the capabilities of the newly available OSCAT sea-surface winds are demonstrated by studying the monsoon intra-seasonal variabilities during the 2010 summer monsoon season. A preliminary validation of OSCAT surface winds with European Centre for Medium Range Weather Forecasting (ECMWF) analysis surface winds carried out during June to August 2010 suggests that the quality of the OSCAT winds are able to meet the mission specifications. The observed mean monthly features of the Indian summer monsoon in July and August 2010 from OSCAT match well with those of ECMWF reanalysis winds. The OSCAT winds capture the known characteristics of the Indian summer monsoon, such as the northward propagation of a low level jet, and its preferred locations during active and break monsoon conditions, reasonably well. The Morlet wavelet transform is used for time series analysis. The OSCAT measured sea-surface winds were found to possess two dominant modes of variability during the 2010 monsoon season: one with a periodicity between 32 and 64?days, and another with a periodicity between 8 and 16?days. Rainfall activity over the Indian summer monsoon region is closely associated with the phases of the two above-mentioned dominant intra-seasonal variabilities. This study demonstrates that the OSCAT winds can be used very well and with confidence for meteorological studies.     

On the diurnal ranges of Sea Surface Temperature (SST) in the north Indian Ocean

This paper describes the variability in the diurnal range of SST in the north Indian Ocean using in situ measurements and tests the suitability of simple regression models in estimating the diurnal range. SST measurements obtained from 1556 drifting and 25 moored buoys were used to determine the diurnal range of SSTs. The magnitude of diurnal range of SST was highest in spring and lowest in summer monsoon. Except in spring, nearly 75–80% of the observations reported diurnal range below 0.5°C. The distributions of the magnitudes of diurnal warming across the three basins of north Indian Ocean (Arabian Sea, Bay of Bengal and Equatorial Indian Ocean) were similar except for the differences between the Arabian Sea and the other two basins during November–February (winter monsoon) and May. The magnitude of diurnal warming that depended on the location of temperature sensor below the water level varied with seasons. In spring, the magnitude of diurnal warming diminished drastically with the increase in the depth of temperature sensor. The diurnal range estimated using the drifting buoy data was higher than the diurnal range estimated using moored buoys fitted with temperature sensors at greater depths. A simple regression model based on the peak solar radiation and average wind speed was good enough to estimate the diurnal range of SST at ∼1.0 m in the north Indian Ocean during most of the seasons except under low wind-high solar radiation conditions that occur mostly during spring. The additional information on the rate of precipitation is found to be redundant for the estimation of the magnitude of diurnal warming at those depths.     

Sr–Nd isotope geochemistry of the early Precambrian sub-alkaline mafic igneous rocks from the southern Bastar craton, Central India

Sr–Nd isotope data are reported for the early Precambrian sub-alkaline mafic igneous rocks of the southern Bastar craton, central India. These mafic rocks are mostly dykes but there are a few volcanic exposures. Field relationships together with the petrological and geochemical characteristics of these mafic dykes divide them into two groups; Meso-Neoarchaean sub-alkaline mafic dykes (BD1) and Paleoproterozoic (1.88 Ga) sub-alkaline mafic dykes (BD2). The mafic volcanics are Neoarchaean in age and have very close geochemical relationships with the BD1 type. The two groups have distinctly different concentrations of high-field strength (HFSE) and rare earth elements (REE). The BD2 dykes have higher concentrations of HFSE and REE than the BD1 dykes and associated volcanics and both groups have very distinctive petrogenetic histories. These rocks display a limited range of initial ¹⁴³Nd/¹⁴⁴Nd but a wide range of apparent initial ⁸⁷Sr/⁸⁶Sr. Initial ¹⁴³Nd/¹⁴⁴Nd values in the BD1 dykes and associated volcanics vary between 0.509149 and 0.509466 and in the BD2 dykes the variation is between 0.510303 and 0.510511. All samples have positive ? _Nd values; the BD1 dykes and associated volcanics have ? _Nd values between +0.3 and +6.5 and the BD2 dykes between +1.9 to +6.0. Trace element and Nd isotope data do not suggest severe crustal contamination during the emplacement of the studied rocks. The positive ? _Nd values suggest their derivation from a depleted mantle source. Overlapping positive ? _Nd values suggest that a similar mantle source tapped by variable melt fractions at different times was responsible for the genesis of BD1 (and associated volcanics) and BD2 mafic dykes. The Rb–Sr system is susceptible to alteration and resetting during post-magmatic alteration and metamorphism. Many of the samples studied have anomalous apparent initial ⁸⁷Sr/⁸⁶Sr suggesting post-magmatic changes of the Rb–Sr system which severely restricts the use of Rb–Sr for petrogenetic interpretation.     

Neoproterozoic tectonic evolution of the Hongseong area, southwestern Gyeonggi Massif, South Korea; implication for the tectonic evolution of Northeast Asia

Two types of Neoproterozoic metabasites occur together with regionally intruded arc-related Neoproterozoic granitoids (ca. 850–830 Ma) in the Hongseong area, southwestern Gyeonggi Massif, South Korea, which is the extension of the Dabie–Sulu collision belt in China. The first type of metabasite (the Bibong and Baekdong metabasites) is a MORB-like back-arc basin basalt or gabbro formed at ca. 890–860 Ma. The Bibong and Baekdong metabasites may have formed during back-arc opening by diapiric upwelling of deep asthenospheric mantle which was metasomatized by large ion lithophile element (LILE) enriched melt or fluid derived from the subducted slab and/or subducted sediment beneath the arc axis. The second type of metabasite (the Gwangcheon metabasite) formed in a plume-related intra-continental rift setting at 763.5 ± 18.3 Ma and is geochemically similar to oceanic island basalt (OIB). These data indicate a transition in tectonic setting in the Hongseong area from arc to intra-continental rift between ca. 830 and 760 Ma. This transition is well correlated to the Neoproterozoic transition from arc to intra-continental rift tectonic setting at the margin of the Yangtze Craton and corresponds to the amalgamation and breakup of Rodinia Supercontinent.