Geochemistry and petrogenesis of anorogenic basic volcanic-plutonic rocks of the Kundal area,Malani Igneous Suite,western Rajasthan,India

The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic and intergrannular textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible elements as compared to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies. Petrographical study and petrogenetic modeling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (< 30%) partial melting of source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested, which is in conformity with the similar setting for Malani Igneous Suite.     

Anisotropy from full waveform inversion of multicomponent seismic data using a hybrid optimization method

Seismic waveforms contain valuable information about the media, but the waveform inversion is a non‐linear problem. We present a waveform inversion method that combines a local optimization method with a genetic algorithm to determine the anisotropic parameters of a horizontally stratified medium. Synthetic seismograms for a horizontally stratified anisotropic medium are calculated using the reflectivity technique. In the initial stage of the inversion, the global space‐sampling properties of the genetic algorithm are used to direct the search to the region close to the global solution. This solution is then further improved using a conjugate‐gradient method. The numerical experiments performed with noisy synthetic data show that our hybrid optimization method satisfactorily reconstructs the anisotropic parameters at a reasonable computing cost while the range of slowness is adequate. We found that (i) for small‐angle data neither single‐ nor multiple‐component data are sufficient to determine the anisotropic parameters uniquely; (ii) for medium‐angle data the multiple‐component data are sufficient to determine the anisotropic parameters exactly whereas the single‐component data are not sufficient; and (iii) for wide‐angle data, either single‐ or multiple‐component data are sufficient to determine the anisotropic parameters accurately.     

Preparation and characterization of biosorbents and copper sequestration from simulated wastewater

This paper reports the potential of chemically treated wood chips to remove copper (II) ions from aqueous solution a function of pH, adsorbent dose, initial copper (II) concentration and contact time by batch technique. The wood chips were treated with (a) boiling, (b) formaldehyde and (c) concentrated sulphuric acid and characterized by Fourier transform infrared spectroscopy, scanning electron microscopy and energy dispersive analysis X-ray. pH 5.0 was optimum with 86.1, 88.5 and 93.9 % copper (II) removal by boiled, formaldehyde-treated and concentrated sulphuric acid-treated wood chips, respectively, for dilute solutions at 20 g L^?1 adsorbent dose. The experimental data were analysed using Freundlich, Langmuir, Dubinin–Radushkevich and Temkin isotherm models. It was found that Freundlich and Langmuir models fitted better the equilibrium adsorption data and the adsorption process followed pseudo-second-order reaction kinetics. The results showed that the copper (II) is considerably adsorbed on wood chips and it could be an economical option for the removal of copper from aqueous systems.     

SPI-based evaluation of drought events in Xinjiang, China

Daily precipitation data for 1957?C2009 from 53 stations in the Xinjiang, China, are analyzed, based on the Standardized Precipitation Index (SPI) with the aim to investigate spatio-temporal patterns of droughts. The Mann?CKendall trend test is used to detect the trends in the SPI values of monthly drought series, drought severity and drought duration. The frequencies of moderate, severe and extreme droughts are higher in the North Xinjiang, while mild droughts occur more often in the South Xinjiang. A decreasing frequency of droughts in the North Xinjiang is found in winter, but a drying tendency is detected in the western parts of the North Xinjiang during spring, summer and autumn, which may be harmful for agriculture. The South Xinjiang seems to be getting wetter in summer, while the south parts of the South Xinjiang seem to be getting drier in spring. The middle of the East Xinjiang is identified to be in a slightly dry tendency. The drought severity is decreasing and drought duration is getting shorter in the North Xinjiang, while both of them increase in the southern parts of the South Xinjiang. In addition, droughts in the middle parts of the East Xinjiang are intensifying.     

Crustal accretion beneath the Koyna coastal region (India) and Late Cretaceous geodynamics

In 1967 a major earthquake in the Koyna region attracted attention to the hitherto considered stable Indian shield. The region is covered by a thick pile of Deccan lava flows and characterized by several hidden tectonic features and complex geophysical signatures. Although deep seismic sounding studies have provided vital information regarding the crustal structure of the Koyna region, much remains unknown. The two available DSS profiles in the region have been combined along the trend of Bouguer gravity anomalies. Unified 2-D density modelling of the Koyna crust/mantle suggests a ca. 3 km thick and 40 km wide high velocity/high density anomalous layer at the base of the crust along the coastline. The thickness of this anomalous layer decreases gradually towards the east and ahead of the Koyna gravity low the layer ceases to be visible. Based on the seismic and gravity data interpretation in the geodynamical/rheological boundary conditions the anomalous layer is attributed to igneous crustal accretion at the base of the crust. It is suggested that the underplated layer is the imprint of the magmatism caused by the deep mantle plume when the northward migrating Indian plate passed over the Reunion hotspot.     

Magnetite Dyke in Precambrian Banded Iron Formation,Singhbhum Craton,India: Mineralogical and Chemical Characteristics

Banded iron formation (BIF) of the Gorumahisani–Sulaipat–Badampahar (GSB) belt in Singhbhum Craton, India, consists predominantly of magnetite. This BIF is intruded by a magnetite dyke. The magnetite dyke is massive and compact with minor sulphide minerals while the host banded magnetite ore, a component of the BIF, shows thin lamination. The magnetite ore of the dyke is fine to medium grained and exhibits interlocking texture with sharp grain boundaries, which is different from the banded magnetite that is medium to coarse grained and show irregular martitised and goethitised grain boundaries. Relics of Fe–Ca–Mn–Mg‐carbonate and iron silicates (grunerite and cummingtonite) are observed in the banded magnetite. The intrusive magnetite is distinctly different in minor, trace and REE geochemistry from the banded magnetite. The banded magnetite contains higher amounts of Si, Al, Mn, Ca, Mg, Sc, Ga, Nb, Zr, Hf, Co, Rb and Cu. In contrast, the massive magnetite is enriched in Cr, Zn, V, Ni, Sr, Pb, Y, Ta, Cs and U with higher abundance of HREE. In the chondrite normalized plot, the massive magnetite shows a slight positive Eu anomaly while the banded ore does not show any Eu anomaly. Field disposition, morphology, mineralogy and chemistry show that the intrusive magnetite dyke is of igneous origin, while magnetite in BIF formed from a carbonate protolith through the process of sedimentation.     

Empirical Orthogonal Function (EOF) analysis of monsoon rainfall and satellite-observed outgoing long-wave radiation for Indian monsoon: a comparative study

Summary The present study involves the use of Empirical Orthogonal Function (EOF) analysis/Principal Component Analysis (PCA) to compare the dominant rainfall patterns from normal rainfall records over India, coupled with the major modes of the Outgoing Long-wave Radiation (OLR) data for the period (1979–1988) during the monsoon period (June–September). To understand the intraseasonal and interannual variability of the monsoon rainfall, daily and seasonal anomalies have been obtained by using the (EOF) analysis. Importantly, pattern characteristics of seasonal monsoon rainfall covering 68 stations in India are highlighted.The purpose is to ascertain the nature of rainfall distribution over the Indian continent. Based on this, the percentage of variance for both the rainfall and OLR data is examined. OLR has a higher spatial coherence than rainfall. The first principal component of rainfall data shows high positive values, which are concentrated over northeast as well as southeast, whereas for the OLR, the area of large positive values is concentrated over northwest and lower value over south India apart from the Indian ocean. The first five principal components explain 92.20% of the total variance for the rainfall and 99.50% of the total variance for the outgoing long-wave radiation. The relationship between monsoon rainfall and Southern Oscillations has also been examined and for the Southern Oscillations, it is 0.69 for the monsoon season. The El-Niño events mostly occurred during Southern Oscillations, i.e. Walker circulation. It has been found that the average number of low pressure system/low pressure system days play an important role during active (flood) or inactive (drought) monsoon year, but low pressure system days play more important role in comparison to low pressure systems and their ratio are (16:51) and (13:25) respectively. Significantly, the analysis identifies the spatial and temporal pattern characteristics of possible physical significance.     

Hydrogeochemical Characterization and Groundwater Quality of Jamshedpur Urban Agglomeration in Precambrian Terrain,Eastern India

This paper reports petrography, geochemistry and Rb-Sr age data on the rare metal bearing Neoarchean fertile (Nb-Ta) granite at Allapatna and elucidates its petrogenesis and role in Nb-Ta-Li-Be mineralization. The Allapatna granite (AG) intrudes the Tonalitic-Trondhjemitic - Granodioritic (TTG) Peninsular Gneiss and analysed SiO₂ (72.3-75.6 wt%), K₂O (4.0-5.7wt%), Na2O (3.0-4.4wt%), CaO (0.7-1wt%), MgO (0.13-0.25wt%) and K₂O/Na₂O (>1) indicating evolved nature. The presence of muscovite, biotite and garnet in the mode, peraluminous nature and high initial ⁸⁷Sr/⁸⁶Sr ratio (0.7284±0.0083) attest to their S-type characteristics. Varying Nb/Ta ratio and high Li with moderate abundance of Cs further indicate affinity to Li-Cs-Ta (LCT) type granite-pegmatite system. TheAG showing whole rock Rb-Sr isochron age of 2803± 68 Ma, is the oldest reported fertile granite in India parental to rare metal pegmatites hosting Nb-Ta, Be, and Li resources. Partial melting of a mixed source consisting of both basement TTG rocks and metapelites has generated such type of granitic magma. Fractionation of such granitic magma possibly has given rise to the rare metal (Ta-Nb-Li-Be) bearing pegmatites intruding the nearby schist belt.     

Interannual variability and predictability of sea level along the Indian Coast

Summary The Indian coast stretching more than 7,500 km constitutes the major portion of the South Asian coastline in the North Indian Ocean region. The South Asian region is significantly influenced by meteorological/oceanographic phenomena like monsoons, El Ni?o/Southern Oscillation (ENSO) and tropical cyclones. Direct/indirect impacts of these phenomena, which exhibit large interannual variabilities, on sea level changes in this region are considerable. Our results show that the mean sea level along the eastern coast of India, which is highly vulnerable to the incidence of severe tropical cyclones, is considerably higher than normal during the intense cyclonic period of a year falling in the positive phase of the Southern Oscillation (La Ni?a epoch), thereby enhancing the hazardous potential of tropical cyclones. Further, in the closing phase of the La Ni?a southwest monsoon, higher sea level anomalies prevail along the Indian coast raising the flooding potential of such monsoons. Over the west coast of India significant simultaneous correlations have been found between the amount of southwest monsoon rainfall and the mean sea level during the period from June to September. Over the east coast of India at Visakhapatnam, mean sea level is predictable with a fair degree of confidence one month in advance, by using the Sea Surface Temperature (SST) and the Southern Oscillation Index (SOI) as predictors. These results will be useful in the annual preparedness programmes aimed at mitigating the impacts of natural disasters like tropical cyclones and floods in the South Asian region. Received November 9, 2001     

Copula-based risk evaluation of droughts across the Pearl River basin, China

Daily precipitation data for the period of 1960–2005 from 42 precipitation gauging stations in the Pearl River basin were analyzed using the Mann–Kendall trend test and copula functions. The standardized precipitation index method was used to define drought episodes. Primary and secondary return periods were also analyzed to evaluate drought risks in the Pearl River basin as a whole. Results indicated that: (1) in general, the drought tendency was not significant at a 95 % confidence level. However, significant drought trends could be found in November, December, and January and significant wetting trends in June and July. The drought severity and drought durations were not significant at most of the precipitation stations across the Pearl River basin; (2) in terms of drought risk, higher drought risk could be observed in the lower Pearl River basin and lower drought risk in the upper Pearl River basin. Higher risk of droughts of longer durations was always corresponding to the higher risk of droughts with higher drought severity, which poses an increasing challenge for drought management and water resources management. When drought episodes with higher drought severity occurred in the Pearl River basin, the regions covered by higher risk of drought events were larger, which may challenge the water supply in the lower Pearl River basin. As for secondary return periods, results of this study indicated that secondary return periods might provide a more robust evaluation of drought risk. This study should be of merit for water resources management in the Pearl River basin, particularly the lower Pearl River basin, and can also act as a case study for determining regional response to drought changes as a result of global climate changes.