Hindoli Group of Rocks in the Eastern Fringe of the Aravalli-Delhi Orogenic Belt-Archean Secondary Greenstone Belt or Proterozoic Supracrus tals?

The very low-grade metamorphic sequence of volcano-sedimentary rocks, sandwiched between the platform sediments of the Vindhyan Supergroup to the east and the Banded Gneissic Complex (BGC) to the west, in the eastern fringe of the Aravalli-Delhi orogenic belt, has remained a stratigraphic enigma in the Precambrian geology of Rajasthan. This sequence known earlier as the Gwalior ‘series’ and in contemporary literature as the Hindoli Group, has been considered by several workers as a Proterozoic supracrustal unit and by some others, as an Archean secondary greenstone belt, based purely on geological considerations. U-Pb zircon geochronology was conducted to find an answer to this controversy on samples of felsic volcanics, conformably intercalated with the Hindoli sediments and hence, considered contemporaneous with them. Zircons from a sample of massive rhyodacite gave a concordia age of 1854k7 Ma though zircons from a sample of felsic tuff gave a wide range of ages between 3259-1877 Ma. Careful consideration of the nature of the samples and their constituent zircons suggests that the Hindoli Group rocks represent a low-grade Proterozoic supracrustal cover sequence in the eastern part of the Bhilwara belt, broadly synchronous to the Aravalli-Bhilwara sedimentation around 1.8 Ga.     

The effect of bulk composition on the solidus of carbonated eclogite from partial melting experiments at 3 GPa

To explore the effect of bulk composition on the solidus of carbonated eclogite, we determined near-solidus phase relations at 3 GPa for four different nominally anhydrous, carbonated eclogites. Starting materials (SLEC1, SLEC2, SLEC3, and SLEC4) were prepared by adding variable proportions and compositions of carbonate to a natural eclogite xenolith (66039B) from Salt Lake crater, Hawaii. Near-solidus partial melts for all bulk compositions are Fe–Na calcio-dolomitic and coexist with garnet + clinopyroxene + ilmenite ± calcio-dolomitic solid solution. The solidus for SLEC1 (Ca#=100 × molar Ca/(Ca + Mg + Fe_T)=32, 1.63 wt% Na₂O, and 5 wt% CO₂) is bracketed between 1,050°C and 1,075°C (Dasgupta et al. in Earth Planet Sci Lett 227:73–85, 2004), whereas initial melting for SLEC3 (Ca# 41, 1.4 wt% Na₂O, and 4.4 wt% CO₂) is between 1,175°C and 1,200°C. The solidus for SLEC2 (Ca# 33, 1.75 wt% Na₂O, and 15 wt% CO₂) is estimated to be near 1,100°C and the solidus for SLEC3 (Ca# 37, 1.47 wt% Na₂O, and 2.2 wt% CO₂) is between 1,100°C and 1,125°C. Solidus temperatures increase with increasing Ca# of the bulk, owing to the strong influence of the calcite–magnesite binary solidus-minimum on the solidus of carbonate bearing eclogite. Bulk compositions that produce near-solidus crystalline carbonate closer in composition to the minimum along the CaCO₃-MgCO₃ join have lower solidus temperatures. Variations in total CO₂ have significant effect on the solidus if CO₂ is added as CaCO₃, but not if CO₂ is added as a complex mixture that maintains the cationic ratios of the bulk-rock. Thus, as partial melting experiments necessarily have more CO₂ than that likely to be found in natural carbonated eclogites, care must be taken to assure that the compositional shifts associated with excess CO₂ do not unduly influence melting behavior. Near-solidus dolomite and calcite solid solutions have higher Ca/(Ca + Mg) than bulk eclogite compositions, owing to Ca–Mg exchange equilibrium between carbonates and silicates. Carbonates in natural mantle eclogite, which have low bulk CO₂ concentration, will have Ca/Mg buffered by reactions with silicates. Consequently, experiments with high bulk CO₂ may not mimic natural carbonated eclogite phase equilibria unless care is taken to ensure that CO₂ enrichment does not result in inappropriate equilibrium carbonate compositions. Compositions of eclogite-derived carbonate melt span the range of natural carbonatites from oceanic and continental settings. Ca#s of carbonatitic partial melts of eclogite vary significantly and overlap those of partial melts of carbonated lherzolite, however, for a constant Ca-content, Mg# of carbonatites derived from eclogitic sources are likely to be lower than the Mg# of those generated from peridotite.     

A modified iterative sandwich method for determination of near-solidus partial melt compositions. II. Application to determination of near-solidus melt compositions of carbonated peridotite

We performed modified iterative sandwich experiments (MISE) to determine the composition of carbonatitic melt generated near the solidus of natural, fertile peridotite + CO₂ at 1,200–1,245°C and 6.6 GPa. Six iterations were performed with natural peridotite (MixKLB-1: Mg# = 89.7) and ∼10 wt% added carbonate to achieve the equilibrium carbonatite composition. Compositions of melts and coexisting minerals converged to a constant composition after the fourth iteration, with the silicate mineral compositions matching those expected at the solidus of carbonated peridotite at 6.6 GPa and 1,230°C, as determined from a sub-solidus experiment with MixKLB-1 peridotite. Partial melts expected from a carbonated lherzolite at a melt fraction of 0.01–0.05% at 6.6 GPa have the composition of sodic iron-bearing dolomitic carbonatite, with molar Ca/(Ca + Mg) of 0.413 ± 0.001, Ca# [100 × molar Ca/(Ca + Mg + Fe*)] of 37.1 ± 0.1, and Mg# of 83.7 ± 0.6. SiO₂, TiO₂ and Al₂O₃ concentrations are 4.1 ± 0.1, 1.0 ± 0.1, and 0.30 ± 0.02 wt%, whereas the Na₂O concentration is 4.0 ± 0.2 wt%. Comparison of our results with other iterative sandwich experiments at lower pressures indicate that near-solidus carbonatite derived from mantle lherzolite become less calcic with increasing pressure. Thus carbonatitic melt percolating through the deep mantle must dissolve cpx from surrounding peridotite and precipitate opx. Significant FeO* and Na₂O concentrations in near solidus carbonatitic partial melt likely account for the ∼150°C lower solidus temperature of natural carbonated peridotite compared to the solidus of synthetic peridotite in the system CMAS + CO₂. The experiments demonstrate that the MISE method can determine the composition of partial melts at very low melt fraction after a small number of iterations.     

Interaction between felsic granitoids and mafic dykes in Bundelkhand Craton: A field,petrographic and crystal size distribution study

In Bundelkhand Craton of central India, mafic dykes intruded when granitoids was partly crystallized. Cuspate–lobate boundary along the contact of granitoids and mafic magma indicates magma mingling in outcrop scale while textural evidence of mingling is represented by acicular apatite morphologies, titanite–plagioclase ocelli and ophitic–subophitic texture, mafic clots, resorbed plagioclase, and hornblende–zircon associations. Mingling also caused thermal exchange and fluid activity along the boundary between two coeval magmas. Crystal size distribution analyses for hornblende in the mafic rocks yield concave up curves which is also consistent with interaction of felsic and mafic magmas.     

The simulation of heavy rainfall episode over Mumbai: impact of horizontal resolutions and cumulus parameterization schemes

In this study, the simulation of an extreme weather event like heavy rainfall over Mumbai (India) on July 26, 2005 has been attempted with different horizontal resolutions using the Advanced Research Weather Research Forecast model version 2.0.1 developed at the National Center for Atmospheric Research (NCAR), USA. The study uses the Betts–Miller–Janjic (BMJ) and the Grell–Devenyi ensemble (GDE) cumulus parameterization schemes in single and nested domain configurations. The model performance was evaluated by examining the different predicted parameters like upper and lower level circulations, moisture, temperature, and rainfall. The large-scale circulation features, moisture, and temperature were compared with the National Centers for Environmental Prediction analyses. The rainfall prediction was assessed quantitatively by comparing rainfall from the Tropical Rainfall Measuring Mission products and the observed station values reported in the Indian Daily Weather Reports from India Meteorological Department (IMD). The quantitative validation of the simulated rainfall was done by calculating the categorical skill scores like frequency bias, threat scores (TS), and equitable threat scores (ETS). It is found that in all simulations, both in single and nested domains, the GDE scheme has outperformed the BMJ scheme for the simulation of rainfall for this specific event.     

Cancer risk estimation from dietary arsenic,a new approach from longitudinal cohort study

Inorganic arsenic is a carcinogen and consumption in low dose may lead to cancer. We estimated the cancer risk of the participants from arsenic endemic regions of West Bengal, India. The probable cancer risk was estimated following the assessment of daily inorganic arsenic intake through drinking water and diets of 20 participants for three consecutive years who had been using low arsenic water in the Indian context (median arsenic concentration in the study Years-I, II and III were 22, 16, 13 µg/l respectively). Probable cancer risk of the population was 2.80 × 10^?4, 2.94 × 10^?4, 3.12 × 10^?4 in the three respective study years (Year-I, II and III); just higher than the US EPA risk level of concern. The arsenic species content of the paired raw, cooked rice and urine was estimated in the as is taken basis. The major diet component, rice contained 72–86% inorganic arsenic whereas urine contains 70% organic arsenic on an average. The cancer risk assessment has been proposed to be modified by inclusion of urine arsenic release, considering the fact of arsenic release through urine. The risk became 1.28 × 10^?5, 1.13 × 10^?5, 1.01 × 10^?5 in the study Year-I, II and III respectively, considering urinary arsenic release, attributed the consideration of urine arsenic release into probable cancer risk estimation.     

Climate Change Studies Using Coupled Model: Land Surface Perspective

Community Climate System Model (CCSM3), a coupled model developed by National Center for Atmospheric Research (NCAR) containing atmosphere, ocean, sea-ice and land processes, simulation have been analysed for suitability in the Indian Monsoon region. A long control run of CCSM3 with constant forcing at every year has been done and the model climatology has been generated using 20 years of simulation. Atmospheric component of the model has been able to capture the large scale phenomena, however, regional monsoon variability not fully captured by the model simulation. A suitable modification in the flux coupler and the convective parameterization process in regional scale certainly improve the atmospheric part of the climate system. Another major component of the climate model is the representation of Land Surface Processes (LSP). A successful inclusion of LSP in climate model must address the issues related to the regional scale variation of the properties of LSP. A proper understanding of land surface processes is very crucial for climate simulations using numerical models. To understand the LSP-monsoon coupling, the offline Community Land Model (CLM), taken from CCSM3 land component, simulation forced with three hourly atmospheric boundary conditions have also been analyzed and compared with the CLM version of coupled CCSM mode. The distribution of surface heat flux in CCSM coupled mode shows some discrepancies compared to the offline CLM. Both the simulation results are compared with existing climatological features and assessment to improve CCSM3 for the regional climate change studies is made.     

Racing climate change: Collaboration and conflict in California's global climate change policy arena

Media accounts routinely refer to California's Assembly Bill 32 (AB 32), the Global Warming Solutions Act of 2006, as “landmark” climate change legislation. On its surface, this label is an accurate reflection of the state's forward-thinking stance across many environmental issues including pesticides, toxic substances, solid waste, and air quality. For all its promise, however, AB 32 can also be considered a low point in the landscape of conflict between state environmental regulators and California's environmental justice movement. While the legislation included several provisions to address the procedural and distributive dimensions of environmental justice, the implementation of AB 32 has been marked by heated conflict. The most intense conflicts over AB 32 revolve around the primacy of market mechanisms such as “cap and trade.” This article examines the drivers and the manifestations of these dynamics of collaboration and conflict between environmental justice advocates and state regulators, and pays particular attention to the scalar and racialized quality of the neoliberal discourse. The contentiousness of climate change politics in California offers scholars and practitioners around the world a cautionary tale of how the best intentions for integrating environmental justice principles into climate change policy do not necessarily translate into implementation and how underlying racialized fractures can upend collaboration between state and social movement actors.     

Atmospheric ionic species in PM2.5 and PM1 aerosols in the ambient air of eastern central India

This study elucidates the characteristics of ambient PM_2.5 (fine) and PM₁ (submicron) samples collected between July 2009 and June 2010 in Raipur, India, in terms of water soluble ions, i.e. Na⁺, NH ₄ ⁺ , K⁺, Mg²⁺, Ca²⁺, Cl^?, NO ₃ ^? and SO ₄ ^2? . The total number of PM_2.5 and PM₁ samples collected with eight stage cascade impactor was 120. Annual mean concentrations of PM_2.5 and PM₁ were 150.9?±?78.6 μg/m³ and 72.5?±?39.0 μg/m³, respectively. The higher particulate matter (PM) mass concentrations during the winter season are essentially due to the increase of biomass burning and temperature inversion. Out of above 8 ions, the most abundant ions were SO ₄ ^2? , NO ₃ ^? and NH ₄ ⁺ for both PM_2.5 and PM₁ aerosols; their average concentrations were 7.86?±?5.86 μg/m³, 3.12?±?2.63 μg/m³ and 1.94?±?1.28 μg/m³ for PM_2.5, and 5.61?±?3.79 μg/m³, 1.81?±?1.21 μg/m³ and 1.26?±?0.88 μg/m³ for PM₁, respectively. The major secondary species SO ₄ ^2? , NO ₃ ^? and NH ₄ ⁺ accounted for 5.81%, 1.88% and 1.40% of the total mass of PM_2.5 and 11.10%, 2.68%, and 2.48% of the total mass of PM₁, respectively. The source identification was conducted for the ionic species in PM_2.5 and PM₁ aerosols. The results are discussed by the way of correlations and principal component analysis. Spearman correlation indicated that Cl^? and K⁺ in PM_2.5 and PM₁ can be originated from similar type of sources. Principal component analysis reveals that there are two major sources (anthropogenic and natural such as soil derived particles) for PM_2.5 and PM₁ fractions.