Paleomagnetic study of some Cretaceous and tertiary rocks on Hispaniola

Summary A reconnaissance paleomagnetic study of Hispaniola shows that three igneous units in the Dominican Republic possess meaningful directions of magnetism. A Late Cretaceous tonalite, an Eocene pyroxene diorite and a Miocene andesite porphyry have been investigated. The rock material studied is fresh, and has not been affected by secondary oxidation except in the case of the andesite which is occasionally weathered and reveals some hydrothermal alteration. Alternating field and thermal demagnetization result in removal of viscous remanence in some samples, while others reveal a good stability of NRM and little change in direction. The results disclose directions of magnetization substantially different from that of the present earth's field in Hispaniola and from those obtained from contemporaneous rocks of North America. They yield paleomagnetic poles at 23.1° N, 144.9° W for the Cretaceous tonalite and at 17.4° N, 138.0° W for the Eocene diorite, the positions of which are not significantly different from each other, suggesting no change of geomagnetic field direction during the two epochs. These poles have generally similar positions to those obtained from Late Cretaceous rocks on Jamaica and Puerto Rico. The Miocene data fall into two groups, one having a direction corresponding to a pole closely coinciding with the Miocene North American pole and the other giving a paleomagnetic pole at 68.3° N, 151.9° W coinciding with the Miocene pole for Jamaica. Paleotectonic interpretation of the results suggests that like other Greater Antilles, Hispaniola has been subject to large anticlockwise rotation since Late Cretaceous.     

An application of R-mode factor analysis to the study of metamorphic petrogenesis

R-mode factor analysis of modal and chemical data clarifies the trends of mineralogical evolution and associated chemical variations in amphibolites from the Northwest Adirondack Mountains, New York and the Willyama Complex, Broken Hill District. In both areas the principal mineralogical reaction attending metamorphism, as described by the first factor, appears to have been Hornblende + Quartz → Calcic pyroxene + Orthopyroxene + Plagioclase. For the Adirondack amphibolites, the derived reaction coefficients viewed against the modal contents of the pyroxenes suggest another hornblende breakdown reaction producing calcic pyroxene, which is corroborated by the first appearance of the phase a little NE of Emeryville. The other factors extracted reveal the underlying parameters responsible for the development of biotite, sphene, opaques and quartz in the Adirondack metabasites and albite, anorthite, ilmenite and quartz in the Willyama Complex amphibolites.The analysis also demonstrates that the principal mineralogical reactions in both the areas have been combinations of thermal and ionic types and further that to decipher the net mineralogical changes in high grade metamorphic basic and pelitic rocks it is necessary to extend the integration of the ‘part reactions’ occurring in different domains to the level of a hand specimen.     

Coronas from the Thessaloniki gabbros,North Greece

Chemical composition of the phases occurring as corona structures in the Thessaloniki gabbros are subjected to algebraic method of treatment following Korzhinskii [1]. The analysis reveals that the mineralogical reactions responsible for the growth of the corona structures were possibly allochemical in nature in regard to the non-volatile components. The chemical similarity of the pyroxenes occurring within and beyond the corona structures in the gabbros appears compatible with such a model.     

Stability of manganocordierite and related phase equilibria in part of the system MnO-Al2O3-SiO2-H2O

The pressure temperature stability of the phase Mn-cordierite hitherto not recorded as a mineral has been determined at temperatures ranging from 400° C up to the melting mainly using standard hydrothermal techniques at the oxygen fugacities provided by the buffering power of the bomb walls. Manganocordierite is a pronounced low-pressure phase with a maximum pressure stability of about 1 kb near 400° C and decreasing pressure limits at higher temperatures. Throughout the temperature range investigated the stable high-pressure breakdown assemblage of Mn-cordierite is spessartine, an Al-silicate, and a SiO₂-polymorph. Due to the variable water contents of Mn-cordierite and spessartine there is a pronounced curvature in the negative dP/dT-slope of the requisite upper pressure breakdown curve of Mn-cordierite. Only theoretical deductions were possible concerning the stable hydrous low-temperature breakdown assemblage of Mn-cordierite below about 400° C.The manganocordierites synthesized are orthorhombic low-cordierites with distortion indices increasing with temperature, water pressure, and duration of heating. Their mean refractive indices increase with rising contents of absorbed water in the structural channels. Based on experiments with natural material the upper temperature stability limit of the mineral carpholite must lie at temperatures below about 400° C for water pressures up to 2.5 kb.The absence of Mn-cordierite from natural rocks studied thus far cannot be explained on chemical grounds, but must be due to its narrow pressure temperature stability range. The phase may yet be discovered as a mineral in manganiferous metasediments formed by lowpressure contact metamorphism.     

Facies pattern of the middle Permian Barren Measures Formation, Jharia basin, India: The sedimentary response to basin tectonics

In the Lower Gondwana succession of the Jharia basin of eastern India, the Barren Measures Formation is characterized by the cyclic disposition of fine-grained lacustrine deposits and relatively coarse-grained fluvial deposits. The cyclic variation in the rate of coarse clastic input is attributed to the sedimentary response to basin tectonics. The sandstone-shale alternations of the Barren Measures succession can be correlated with the tectonic cyclothems developed on the hangingwall dip-slope and adjoining trough in a continental half-graben setting. Enhancement of the gradient of the hangingwall dip-slope during reactivation of the basin margin faults led to progradation of the existing fluvial system towards the half-graben trough and deposition of the coarser clastics on the fine-grained lacustrine deposits of the trough. Peneplanation of the hangingwall slope and slow increase in the lake level caused lacustrine transgression and retrogration of the fluvial system on the hangingwall block. The fluvial sediments were onlapped by the fine-grained lacustrine deposits. Episodic rejuvenation of the basin margin faults thus caused development of tectonic cyclothem on the hangingwall block. The paleocurrent pattern indicates that a persistent northward paleoslope was maintained during Barren Measures sedimentation. The inferred depositional settings were much more extensive than the present limit of the outcrop. The faults, presently defining the northern limit of the Barren Measures Formation, were possibly emplaced after Barren Measures sedimentation. The final movement along these fault planes caused preservation of the downthrown hangingwall block and the Barren Measures sediments on the footwall block were eroded during subsequent denudation. The Southern Boundary Fault came into existence after the deposition of the Barren Measures sediments.     

Mid-crustal contact metamorphism around the Chimakurthy mafic-ultramafic complex, Eastern Ghats Belt, India

Pelitic rocks were thermally metamorphosed at the contact of the Chimakurthy mafic-ultramafic igneous complex, Eastern Ghats Belt, India. The rocks show progressive change in mineralogy from biotite-sillimanite-quartz-garnet-K-feldspar (association I, 150 m from the intrusive contact) to garnet-spinel-cordierite-K-feldspar-sillimanite (association II, 20–30 m from the intrusive contact) to cordierite-K-feldspar-(cordierite-orthopyroxene-K-feldspar symplectite after osumilite)-spinel-FeTiAl oxides with/without garnet (associations III and IV, 5 m from the intrusive contact), and finally to spinel-orthopyroxene-cordierite-K-feldspar (association V, xenoliths). Oxide mineral clots in associations III and IV resemble emery-type rocks. Initial mineral reactions involved biotite-dehydration melting with partial segregation of the melt. Down-temperature mineral reactions were largely diffusion controlled and preservation of symplectitic and coronitic textures in microdomains is common. Interpretation of reaction textures in relevant petrogenetic grids for the sytems KFMASH and FMAS and combined with geothermobarometry suggest that the pelitic rocks were thermally metamorphosed at c. 6 kbar pressure along a heating-cooling trajectory within the temperature interval between c. 750 °C and c. 1000 °C. Received: 20 October 1996 / Accepted: 17 June 1997     

Mixing behavior in quaternary garnet solid solution and an extended Ellis and Green garnet-clinopyroxene geothermometer

Applications of the different formulations of garnet-clinopyroxene geothermometers to crustal granulites and particularly to metamorphosed manganese formations show a wide scatter of estimates. This is primarily related to the uncertainty associated with the formulation of the activity-composition relationship in garnet solid solution besides that in the clinopyroxene solid solution. The largest uncertainty appears to have resulted from the adopted Mg-Mn interaction parameter in garnet which is yet to be experimentally determined. A fresh statistical regression of eleven pairs of garnet and clinopyroxene equilibrated at identical P-T conditions from a manganese formation in India yields W _Mg-Mn ^Gt (=W_Mn-Mg) value of 1600±500 cal/mols. An extension of the Ellis and Green (1979) geothermometer, known to work well in normal granulites, incorporating terms associated with the activity coefficients of the exchangeable cations, now yields consistent temperature estimation from normal granulites as well as from metamorphosed manganese formations. The geothermometer, however, will not work well for garnet having X_Fe0.65 and clinopyroxenes containing appreciable Na, Al and/or Fe³⁺.     

Geochemistry of braunite and associated phases in metamorphosed non-calcareous manganese ores of India

In the metamorphosed manganese oxide ores of India, braunite is ubiquitous in all assemblages from chlorite to sillimanite grades. Chemical analyses of braunite from different prograde assemblages confirm the presence of a fixed R²⁺ (=Mn²⁺+Mg+Ca) SiO₃ molecule in the mineral. Element partitioning between coexisting braunite and bixbyite indicates a near-ideal mixing of Fe⁺³/ -Mn⁺³ in the phases. This also indicates that braunite became relatively ferrian while equilibrating with associated phases such as bixbyite, hollandite and jacobsite during prograde reactions. Petrogenetic studies show that as a general trend, prograde lower oxide phases appeared by deoxidation of higher oxide phases. But braunite, a more reduced phase than bixbyite, appeared early from deoxidation of pyrolusite in presence of quartz. Bixbyite could appear later from the reacting pyrolusite-braunite-quartz assemblage. Inferred mineral reaction paths and the general trend of pro-grade deoxidation reactions suggest that the composition of ambient fluid phase was internally buffered during metamorphism.     

A modified iterative sandwich method for determination of near-solidus partial melt compositions. I. Theoretical considerations

The sandwich technique for determining the composition of partial melts in equilibrium with mantle lithologies may be a particularly powerful method for determining melt compositions at the onset of melting if the method is applied iteratively. However, conventional iterative sandwich experiments, in which the liquid from a preceding experiment is used as the “meat” of the sandwich in the following experiment, may require many iterations before the melts produced can be directly relatable to the melting relations of the target bulk rock composition. A modified iterative sandwich experimental (MISE) technique is proposed that may circumvent many of the problems of more conventional techniques. Consideration of experimental uncertainties, including both random and systematic errors in determination of partial melt compositions as well as the influence of errors in estimates of the solidus temperature of the rock of interest, suggests that the MISE technique may produce robust results even when melt composition errors are significant and that errors in estimation of the solidus location are detectable and therefore avoidable.