Transition probabilities and dissociation energy of astrophysical molecule GeH

The Franck-Condon factors andr-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable numerical integration procedure for the bands of A ² Δ - X² π_r system of astrophysical molecule GeH, using a suitable potential. The dissociation energy for the electronic ground state of astrophysical molecule GeH has been estimated precisely as D ⁰ ₀ = 2.69 ± 0.05 eV by fitting the empirical potential function to the experimental potential energy curve using correlation coefficient. This revised version was published online in July 2006 with corrections to the Cover Date.     

Coastal Placer Deposits of Central Tamil Nadu, India

Placer mineral exploration has been undertaken along the beach of Central Tamil Nadu coast from Pondicherry to Vedaranyam. On the basis of the drainage network, geomorphology, and the coastal environment, the study area has been grouped into three sectors, North, Central, and South. Heavy mineral by Wt% shows a slightly higher abundance in the Northern sector, an enrichment of opaques in the Central sector from stations between Poompuhar and Karaikal, and a total depletion in the Southern sector. An abundance of heavies in the Northern sector is considered to be the result of a higher wave energy, and the cymatogenic downwarping of the basin during the present transgression. An enrichment of heavies in the Central sector from Poompuhar to Karaikal is attributable to the reworking of the beach ridges, which were submerged during the present transgression, and to the role of density sorting. A depletion of heavies in the Southern sector is accounted for by the absence of a terrigenous supply and the prevalence of wave shadow conditions throughout the year. The nature of the heavy mineral assemblage reflects the derivation of sediments principally from khondalites, granites, metamorphic rocks and paleo-sediments. Factor analysis also supplements the predominant role of a density factor in the segregation of heavy minerals in the study area. A five-stage model is proposed for the formation of placer deposits in the study region. The present study has disclosed rich concentrations of ilmenites in the central sector between Poompuhar and Karaikal that can be commercially exploited.     

Astrophysical Molecules AlD and CaH: Transition Probabilities and Dissociation Energy

The Franck-Condon (FC) factors and r-centroids for the bands systemC ¹ Σ ⁺ → X ¹ Σ ⁺ of AlD and E ² Π → X ² Σ ⁺ of CaH have been evaluated by means of a reliable numerical integration procedure by using a suitable potential. The dissociation energy, D _e, for the electronic ground states of AlD and CaH have been estimated by the curve fitting method to the RKRV experimental potential curve turning out to be 3.01 eV and 2.32 eV, respectively. This revised version was published online in July 2006 with corrections to the Cover Date.     

Transition probabilities and dissociation energy of astrophysical molecule CoH

The Franck-Condon (FC) factors (transition probabilities) and r-centroids have been evaluated by the reliable numerical integration procedure for the bands of the A ³ φ₄ →X ³ φ₄ system of astrophysical molecule CoH, using a suitable potential. The dissociation energy D ⁰ ₀ = 2.5 ± 0.05 eV for the electronic ground state of CoH has been estimated by fitting Hulburt-Hirschfelder function to the experimental potential energy curve, using the correlation coefficient. This revised version was published online in July 2006 with corrections to the Cover Date.     

Franck-Condon factors and r-centroids for certain band systems pf astrophysical molecule BeF

The Franck-Condon factors and r-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable numerical integration procedure for the bands of B ² Σ⁺ - X ² Σ⁺, C ²Σ⁺ - X ² Σ⁺ andC ² Σ⁺ - A ² Π_r systems of the astrophysical molecule BeF, using a suitable potential. This revised version was published online in July 2006 with corrections to the Cover Date.     

Astrophysically Useful Parameters for Some Vibronic Transitions of AlH and BH

For molecular identification in astrophysical sources, an astrophysicist needs some spectroscopic parameters such as dissociation energy, vibrational or rotational temperature of the source, band or line wavelengths, transition probability parameters, etc. The Franck-Condon(FC) factors are proportional to the transition probabilities. In this study, the FC factors and r-centroids for the vibronic (vibration-electronic) transitions C ¹ Σ ⁺ → X ¹ Σ ⁺ of aluminium hydride (AlH), b ³ Σ ^{( −)} → a ³ Π, C ¹ Σ ⁺ → A ¹ Π & C ^′1 Δ → Δ ¹ Π of boron hydride (BH) have been evaluated and the results are presented in tables which include band origin/head wavelengths. The physical & astrophysical significances of our evaluated FC factors & r-centroids have been discussed and the possible presence of AlH in sunspot umbral spectra is also predicted. PACS: 33 · 70 · Ca     

Identification of AlF Molecular Lines in Sunspot Umbral Spectra

High resolution FTS sunspot umbral spectra from NSO/Kitt Peak were used to detect rotational lines due to 11 electronic transitions of the molecule AlF, in the wavelength region 4400 – 9000 Å. The presence of lines due to bands C – A (0,0), (0,1), (0,2) and (1,2), D – A (0,0) and (0,1), F – A (0,0), G – A (0,0), and F – B (0,0) is confirmed. Further, the presence of lines due to C – A (1,0) and (1,1) transitions is treated as doubtful because of heavy blending in the region, by rotational lines of TiO. Among the identified lines, those which are well resolved were selected for measurement of equivalent widths. The measured values for the bands D – A (0,0) and F – A (0,0) were used to estimate the respective effective rotational temperatures to be 1240 ± 120 K and 2390 ± 400 K.     

Rb–Sr and Sm–Nd isotope systematics and geochemical studies on metavolcanic rocks from Peddavura greenstone belt: Evidence for presence of Mesoarchean continental crust in easternmost part of Dharwar Craton,India

Linear, north–south trending Peddavura greenstone belt occurs in easternmost part of the Dharwar Craton. It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock types to understand the evolution of the Dharwar Craton. Due to source heterogeneity Sm–Nd isotope system has not yielded any precise age. Rb–Sr whole-rock isochron age of 2551 ± 19 (MSWD = 1.16) Ma for BBA group could represent time of seafloor metamorphism after the formation of basaltic rocks. Magmas representing BBA group of samples do not show evidence for crustal contamination while magmas representing type-II rhyolites had undergone variable extents of assimilation of Mesoarchean continental crust (>3.3 Ga) as evident from their initial ε _Nd isotope values. Trace element and Nd isotope characteristics of type I rhyolites are consistent with model of generation of their magmas by partial melting of mixed sources consisting of basalt and oceanic sediments with continental crustal components. Thus this study shows evidence for presence of Mesoarchean continental crust in Peddavura area in eastern part of Dharwar Craton.     

Coastal Placer Deposits of Central Tamil Nadu,India

ABSTRACT

Placer mineral exploration has been undertaken along the beach of Central Tamil Nadu coast from Pondicherry to Vedaranyam. On the basis of the drainage network, geomorphology, and the coastal environment, the study area has been grouped into three sectors, North, Central, and South. Heavy mineral by Wt% shows a slightly higher abundance in the Northern sector, an enrichment of opaques in the Central sector from stations between Poompuhar and Karaikal, and a total depletion in the Southern sector. An abundance of heavies in the Northern sector is considered to be the result of a higher wave energy, and the cymatogenic downwarping of the basin during the present transgression. An enrichment of heavies in the Central sector from Poompuhar to Karaikal is attributable to the reworking of the beach ridges, which were submerged during the present transgression, and to the role of density sorting. A depletion of heavies in the Southern sector is accounted for by the absence of a terrigenous supply and the prevalence of wave shadow conditions throughout the year. The nature of the heavy mineral assemblage reflects the derivation of sediments principally from khondalites, granites, metamorphic rocks and paleo-sediments. Factor analysis also supplements the predominant role of a density factor in the segregation of heavy minerals in the study area. A five-stage model is proposed for the formation of placer deposits in the study region. The present study has disclosed rich concentrations of ilmenites in the central sector between Poompuhar and Karaikal that can be commercially exploited.