Geochemical features of the utilization of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant using acid leaching

The decontamination of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant is complicated by the geochemical features of the waste composition: low sulfide and high carbonate content, polyelemental composition, and considerable amounts of technogenic admixtures (kerosene, oils, soda, and soluble glasses). These circumstances result in sufficient complication of the suggested technology of waste treatment, including the sulfuric-acid leaching and separate sorption recovery of hazardous and useful elements from the working solution.     

The second version of the OCARS catalog of optical characteristics of astrometric radio sources

A new version of the Optical Characteristics of Astrometric Radio Sources (OCARS) catalog is presented. The catalog includes a list of radio sources observed in astrometric and geodetic VLBI programs since 1979, their redshifts, photometric data in 13 bands in the visible and near infrared, and a table indicating identifications btween the OCARS objects and objects in other catalogs. The main sources of information for the OCARS catalog are the NED and SIMBAD databases, as well as a variety of publications. Targeted observing programs designed to supplement the optical data for the astrometric radio sources have also been organized. The catalog currently contains 9956 sources, of which 5449 have redshifts and 7473 have photometric data. The catalog is updated, on average, once every several weeks, and is continuously augmented with new sources and new optical data.     

Influence of Mussel Culture on the Vertical Export of Phytoplankton Carbon in a Coastal Upwelling Embayment (Ría de Vigo,NW Iberia)

The goal of this paper is to find out whether suspended mussel culture affects the vertical fluxes of biogenic particles in the Ría de Vigo on a seasonal scale. With this aim, vertical fluxes of particulate organic carbon (POC) and the magnitude and composition of vertical export of phytoplankton carbon (Cphyto) collected in sediment traps were examined by comparing data obtained inside a mussel farming area (RaS) with those found at a reference station (ReS) not affected by mussels. Our results indicate that mussel farming has a strong impact on sedimentation fluxes under the rafts, not only increasing POC flux but also altering the magnitude and composition of Cphyto fluxes. Average POC flux at RaS (2564?±?1936 mg m^?2 day^?1) was four times higher than at ReS (731?±?276 mg m^?2 day^?1), and much of this increase was due to biodeposit fluxes (Cbiodep) which accounted for large proportion of POC flux (35–60 %). Indeed, because of this high Cbiodep flux, only a small proportion of the POC flux was due to Cphyto flux (3–12 %). At the same time, we observed an increased sedimentation of phytoplankton cells at RaS that could be explained by a combination of mechanisms: less energetic hydrodynamic conditions under mussel rafts, ballast effect by sinking mussel feces, and diatom aggregates. Moreover, mussel farming also altered the quality of the Cphyto flux by removing part of the predatory pressure of zooplankton and thus matching diatom composition in water column and sediment traps.     

Effectiveness of vegetative filter strips in abating fecal coliform based on modified soil and water assessment tool

Pathogenic bacteria are a serious public health concern. Exposure to these microorganisms can result in illnesses or even death. Therefore, it is important to control pathogenic bacteria sources, transport mechanisms and fate. Best management practices proved to be very effective in the control of non-point source pollution. In this study, the soil and water assessment tool (SWAT) was modified and used to simulate the fecal coliform in Chao River of Miyun Reservoir watershed, China. The model was then used to explore the effectiveness of vegetative filter strips (VFS) in reducing fecal coliform abundance throughout the watershed. The water temperature equation within the SWAT was modified to align the model more closely with the characteristics of the study area and generate a more accurate simulation. The DAFS_ratio (20, 50, 80, 120 and 150) and DF_con (0.25, 0.4, 0.6 and 0.75) parameters were considered for VFS to see their effects on removal efficiency. The results show that calibration and validation results for fecal coliform and flow can be accepted. Different values for DAFS_ratio and DF_con have great influence on VFS. Increasing values resulted in a decrease in the removal efficiency of VFS.     

Design and simulation of a vertical broadband seismometer

In this paper, a new vertical broadband seismometer is designed, simulated, and evaluated. The proposed seismometer has a bandwidth from 40 s to 50 Hz and sensitivity to ground velocity of 1500 V’/m/s. The mechanical suspension used in the proposed design is a mass-leaf spring rotational pendulum. The displacement of the seismic mass is sensed by a laser interferometer and then forwarded to an electronic force feedback system which feeds a linear actuator to keep the mass almost fixed in its position. The current needed to fix the mass in its position is an indication of the ground acceleration. The performance of the simulated seismometer is evaluated by applying a data record of two actual earthquakes to the simulated model and comparing its response to the earthquakes with that of a real seismometer (Trillium-40) having the same bandwidth and sensitivity. The proposed seismometer has performed within 0.4 % residual variance for the local event and 0.03 % residual variance for the regional one compared to Trillium-40.     

The oldest (~ 1.9 Ga) metadolerites of the southern Siberian craton: age,petrogenesis, and tectonic setting

Geological, geochronological, and isotope-geochemical studies of the metadolerites of the Angaul complex, widespread in the Urik-Iya graben of the southern Siberian craton, were carried out. The metadolerites forming separate conformal bodies (sills) among the metasandstones of the Ingash Formation were studied in detail. U-Pb zircon (SHRIMP) dating of metadolerites yielded an age of 1913 ± 24 Ma, and U-Pb baddeleyite (ID-TIMS) dating of these rocks yielded an age of 1914.0 ± 1.7 Ma. Thus, the date of 1914 ± 2 Ma can be taken as the most precise age estimate for the studied rocks. The metadolerites of the Angaul complex correspond in chemical composition to the normal-alkaline tholeiitic basalts. Metadolerites are differentiated rocks with mg# of 36 to 58. They show fractionated REE patterns: (La/Yb)_n = 1.2-3.5. All metadolerites, independently of their mg# value, have low contents of Nb (1.6-10.2 ppm) and show well-pronounced negative Nb-Ta anomalies in multielement patterns (Nb/Nb* = 0.19-0.54). The metadolerites are characterized by positive ε_Nd(T) values ranging from 0.4 to 5.2, which correlate well with their SiO₂ content and mg# value. The isotope-geochemical parameters of the metadolerites of the Angaul complex indicate that fractional crystallization, along with the assimilation of the host rocks (AFC), might have been the main process during the formation of the most differentiated metadolerites. The geochemical characteristics of metadolerites with the maximum mg# values of 57-58 and ε_Nd(T) = 5.2 suggest that the parental mantle source of the metadolerites resulted from mixing of predominant depleted mantle material with the subcontinental-lithosphere material. Intrusion of the dolerites of the Angaul complex, as well as the deposition of the sedimentary strata of the Ingash Group, took place at the Paleoproterozoic stage of intracontinental extension caused by the collapse of the orogen resulted from the collision of the Biryusa block with the Tunguska superterrane in the southern Siberian craton.     

Photodegradation of dimethyl phthalate (DMP) by UV–TiO<Subscript>2</Subscript> in aqueous solution: operational parameters and kinetic analysis

In this paper, the adsorption and degradation phenomenon involved in the photocatalytic degradation of dimethyl phthalates (DMPs) by titanium dioxide (TiO₂) was studied. A variety of operating variables were selected firstly. Then, it was proved that even for such weak adsorption properties molecules as DMP, adsorption was still an important prerequisite for photolysis. A surface-mediated reaction process was proposed that the photodegradation of DMP assisted by TiO₂ particles occurred primarily at the surface of the photocatalyst rather than in the homogeneous phase. According to Langmuir–Hinshelwood model, the adsorption constant determined from the dark adsorption was far less than that obtained in the light condition. Enhanced DMP adsorption on the surface of TiO₂ under irradiation was the possible reason for the improvement of photodegradation efficiency. Under the irradiation of light, a synergistic mechanism of adsorption and photocatalysis was responsible for DMP degradation. The quantitative analysis by adding scavengers indicated that ^·OH radical was primarily responsible for the photodegradation of DMP. It was further verified that ^·OH was produced much more from conduction band electrons rather than valance band holes toward photodegradation of DMP by adding foreign Cu²⁺.