A factor analytic approach to the identification of geomorphic processes from soil particle size characteristics

Q-mode factor analysis of soil particle size data is used to identify the three dominant geomorphic processes responsible for the spatial variability of particle size in a catchment on the basaltic Darling Downs landsurface. Three factors are shown to account for 95 per cent of the textural variability of a suite of transported and sedentary materials. The spatial characteristics of groups of samples associated with the three factors suggests that the three factors are associated with suspended sediment transport and deposition, weathering, and bedload transport and deposition respectively. These interpretations are supported by the detailed graphical analysis of the cumulative particle size curves. The spatially variable influence of the three factors and related processes is given by their respective factor loadings which are mappable for the surface layer materials.     

A Three-year Study of Nonmethane Hydrocarbons in Surface Air over Saxony (Germany)

Measurements of the nonmethane hydrocarbon (NMHC) mixing ratio over a period of 42 months were carried out for the first time in the air of a research station situated in the former East Germany during the SANA project. Apart from four species, all other species analysed showed a statistically significant downward trend at the 95% significance level. The decrease of the hydrocarbon concentrations was superimposed by seasonal variations. A drop of about 40% of the annual mean values from 1993 to 1995 was observed. This development reflects the dramatic changes in traffic, industry, power economy, and agriculture in Saxony after the reunification of Germany. The remove of two-stroke engined cars is reflected in NMHC mixing ratio changes, as is the removal of obsolete chemical plants. Generally it was not possible to relate causes and effects of a single event, but in some cases major changes in concentrations and NMHC ratios occurred coincidentally with the disappearance of a specific emission source.     

Crack nucleation in saturated porous media

Crack nucleation has been the subject of important contributions in the last two last decades. However, it seems that few attention has been granted to the case of saturated porous media. This is the question addressed in the present paper which is devoted to nucleation in traction mode. From a physical point of view, nucleation is a sudden phenomenon, so that the material response is both adiabatic and undrained. In the spirit of the variational approach, the nucleated crack is viewed as the final state of a region of space in which the material undergoes a full damage process. In traction mode, the opening of a saturated crack in undrained condition induces a drop of fluid pressure. In case of low fluid compressibility, the presence of the fluid delays the brittle failure usually associated with nucleation, as long as the fluid pressure remains above the saturation vapor pressure. Nucleation is therefore possible only if a partial vaporization of the fluid takes place.     

On the existence of a relation between the Kolmogoroff and von Kármán constants

A model is described, in which the mean vertical wind profile and turbulence spectra at different heights are calculated for a turbulent boundary layer without thermal stratification. The model makes use of Heisenberg's formula for the transfer of turbulent energy and is based on the assumption of a constant shearing stress in that boundary layer. As a result, a logarithmic wind profile follows with 0.39 as the value of von Kármán's constant, which is — in this model — strongly related to the inertial subrange of the turbulent energy spectra and therefore to the Kolmogoroff constant.This paper is based on studies done by the author during a one-year visit to CSIRO Division of Meteorological Physics, Aspendale, Australia, and was presented at the AGARD Specialists Meeting on The Aerodynamics of Atmospheric Shear Flows sponsored by the Fluid Dynamics Panel at Munich, Germany, during 15–17 Sept. 1969.     

Volume diffusion of Ytterbium in YAG: thin-film experiments and combined TEM–RBS analysis

In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method, we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results. At 1,450°C and 1 bar, we infer log D _Yb (m²/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect cannot generally be ignored.