Chemical fractionations in meteorites—XI. C2 chondrites

Six C2M chondrites (Boriskino, Cold Bokkeveld, Erakot, Essebi, Haripura and Santa Cruz) and the C2R chondrite Al Rais were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Sn, Te, Tl, U, and Zn. Abundances (relative to Cl chondrites) show a systematic dependence on volatility, apparently reflecting volatile loss during formation of chondrules and other high-T components. Elements of nebular condensation temperature (T_c) > 1200 K are undepleted, those of T_c < 700 K are depleted by a constant factor (0.482 ± 0.049 for C2M's) and elements of intermediate volatility are depleted by intermediate factors. The abundances do not “tend to fall monotonically as a function of [T_c],” as previously claimed by Wai and Wasson (1977) for a more restricted temperature range. For meteorites that have suffered little aqueous alteration (Mighei, Murchison, Murray), the mean abundance of volatiles agrees with the matrix content, but for the more altered meteorites, matrix contents are 20–30% higher. Only a few meteorites deviate appreciably from the mean abundance pattern. Al Rais, a C2R chondrite with a significant metal content, is systematically lower in 12 volatiles, but is enriched in Ni and Pd. Haripura and Erakot are enriched in Bi and Tl, possibly from the late condensate, mysterite.     

Growth,dynamics and deglaciation of the last British–Irish ice sheet: the deep-sea ice-rafted detritus record

The evolution and dynamics of the last British–Irish Ice Sheet (BIIS) have hitherto largely been reconstructed from onshore and shallow marine glacial geological and geomorphological data. This reconstruction has been problematic because these sequences and data are spatially and temporally incomplete and fragmentary. In order to enhance BIIS reconstruction, we present a compilation of new and previously published ice-rafted detritus (IRD) flux and concentration data from high-resolution sediment cores recovered from the NE Atlantic deep-sea continental slope adjacent to the last BIIS. These cores are situated adjacent to the full latitudinal extent of the last BIIS and cover Marine Isotope Stages (MIS) 2 and 3. Age models are based on radiocarbon dating and graphical tuning of abundances of the polar planktonic foraminifera Neogloboquadrina pachyderma sinistral (% Nps) to the Greenland GISP2 ice core record. Multiple IRD fingerprinting techniques indicate that, at the selected locations, most IRD are sourced from adjacent BIIS ice streams except in the centre of Heinrich (H) layers in which IRD shows a prominent Laurentide Ice Sheet provenance. IRD flux data are interpreted with reference to a conceptual model explaining the relations between flux, North Atlantic hydrography and ice dynamics. Both positive and rapid negative mass balance can cause increases, and prominent peaks, in IRD flux. First-order interpretation of the IRD record indicates the timing of the presence of the BIIS with an actively calving marine margin. The records show a coherent latitudinal, but partly phased, signal during MIS 3 and 2. Published data indicate that the last BIIS initiated during the MIS 5/4 cooling transition; renewed growth just before H5 (46 ka) was succeeded by very strong millennial-scale variability apparently corresponding with Dansgaard–Oeschger (DO) cycles closely coupled to millennial-scale climate variability in the North Atlantic region involving latitudinal migration of the North Atlantic Polar Front. This indicates that the previously defined “precursor events” are not uniquely associated with H events but are part of the millennial-scale variability. Major growth of the ice sheet occurred after 29 ka with the Barra Ice Stream attaining a shelf-edge position and generating turbiditic flows on the Barra–Donegal Fan at ～27 ka. The ice sheet reached its maximum extent at H2 (24 ka), earlier than interpreted in previous studies. Rapid retreat, initially characterised by peak IRD flux, during Greenland Interstadial 2 (23 ka) was followed by readvance between 22 and 16 ka. Readvance during H1 was only characterised by BIIS ice streams draining central dome(s) of the ice sheet, and was followed by rapid deglaciation and ice exhaustion. The evidence for a calving margin and IRD supply from the BIIS during Greenland Stadial 1 (Younger Dryas event) is equivocal. The timing of the initiation, maximum extent, deglacial and readvance phases of the BIIS interpreted from the IRD flux record is strongly supported by recent independent data from both the Irish Sea and North Sea sectors of the ice sheet.     

Variable water column structure of the South Atlantic on glacial–interglacial time scales

The structure of the glacial ocean was significantly different to that of the present day with intermediate to mid-depth waters being notably more δ¹³C enriched than deep waters. This contrast was especially pronounced in the South Atlantic suggesting the development of a sharp chemical divide, or ‘chemocline’, at around 2500 m water depth between upper and lower layers, with implications for deep-ocean carbon storage [Hodell et al., 2003. Pleistocene vertical carbon isotope and carbonate gradients in the South Atlantic sector of the Southern Ocean. Geochemistry, Geophysics, Geosystems, 4(1): doi: 1004 10.1029/2002GC000367.]. We evaluate existing benthic foraminiferal δ¹³C, Cd/Ca and derived carbon isotope air–sea exchange signature (δ¹³C_as) data sets for the Atlantic during the Last Glacial Maximum (LGM), and Marine Isotope Stages (MIS) 6 and 8 in order to examine the regional extent of the chemocline in the South Atlantic. Benthic δ¹³C data north of the approximate latitude of the LGM Subantarctic Front (LGM-SAF, 43°S) linearly decrease with water depth, indicative of mixing between upper ‘well’ and lower ‘poorly’ ventilated water masses, with little evidence of the sharp chemical divide. Conversely, benthic δ¹³C data south of the LGM-SAF below 2500 m water depth are uniformly around ?0.8‰. The apparent δ¹³C gradient across the LGM-SAF suggests enhanced mid-depth ventilation north of the SAF and reduced ventilation to the south. From this pattern we conclude that the regional chemocline in the South Atlantic constituted a dominantly meridional, rather than a vertical gradient, and was developed during at least the past three glacial periods. Benthic Cd/Ca data indicate that the gradient was not nutrient related, although further data from the South Atlantic are needed for a better assessment of this suggestion. The combined benthic δ¹³C and Cd/Ca data indicate the source of well-ventilated upper waters in the South Atlantic changed from Northern Component Water (NCW) during early glacial phases to Upper Southern Component Water (USCW) during mid-to-late glacial phases when the Southern Ocean may have become isolated. USCW maintained a positive δ¹³C and δ¹³C_as signature simulating a North Atlantic origin that has been implicated in previous studies. The data demonstrate that secular imprints on δ¹³C must be taken into consideration when assessing the implications of the vertical δ¹³C gradient. This data also supports a variable water column architecture and modes of water mass formation as primary means to draw down atmospheric CO₂ and storage in the abyssal ocean by involving processes occurring on either side of the SAF in the glacial Southern Ocean.     

A hydrographic time series station in the Wadden Sea (southern North Sea)

In the tidal inlet between the East Frisian islands of Langeoog and Spiekeroog, southern North Sea, a time-series station was set up in autumn 2002 as part of the research programme BioGeoChemistry of Tidal Flats run by the University of Oldenburg. The purpose of the station is to provide continuous data on physical, biological and chemical parameters. In addition to instruments recording basic hydrographic and meteorological parameters, the time-series station is equipped with acoustic Doppler profilers for measuring surface waves and current profiles. Compact optical spectrometers are being used for spectral measurements of seawater transmission and for daylight reflectance. Additional sensors were installed for measuring oxygen, nutrients and methane in the seawater. The data shall help to quantify the flux of dissolved and suspended matter between the backbarrier tidal flat and the open sea and to characterise the material transformation in the tidal flat area by biogeochemical processes over the tidal cycle. Due to its novel design, operation of the station is also possible during winter and under extreme weather conditions (gales, storm surges, and sea ice) when data sampling with conventional platforms such as research vessels, buoys, or smaller poles could not be performed in the past. In this way, time series of data are obtained, which include events that are most relevant to the evolution of this coastal area. The performance of the station and its equipment are presented with data covering 6 years of operation. Time series of air and water temperature as well as seawater salinity demonstrate the multiyear dynamics of these parameters in the East Frisian Wadden Sea. Hydrographic data collected under specific meteorological conditions such as gales and storm surges exemplify the all-weather capabilities of the station and its value for studying hydrographic processes in the Wadden Sea.     

The Ardón L6 ordinary chondrite: A long‐hidden Spanish meteorite fall

We report and describe an L6 ordinary chondrite fall that occurred in Ardón, León province, Spain (longitude 5.5605°W, latitude 42.4364°N) on July 9th, 1931. The 5.5 g single stone was kept hidden for 83 yr by Rosa González Pérez, at the time an 11 yr old who had observed the fall and had recovered the meteorite. According to various newspaper reports, the event was widely observed in Northern Spain. Ardón is a very well‐preserved, fresh, strongly metamorphosed (petrologic type 6), and weakly shocked (S3) ordinary chondrite with well‐equilibrated and recrystallized minerals. The mineral compositions (olivine Fa_23.7±0.3, low‐Ca pyroxene Fs_20.4±0.2Wo_1.5±0.2, plagioclase An_10.3±0.5Ab_84.3±1.2), magnetic susceptibility (log χ = 4.95 ± 0.05 × 10^?9 m³ kg^?1), bulk density (3.49 ± 0.05 g   cm^?3), grain density (3.58 ± 0.05 g   cm^?3), and porosity (2.5 vol%) are typical for L6 chondrites. Short‐lived radionuclides confirm that the meteorite constitutes a recent fall. The ²¹Ne and ³⁸Ar cosmic ray exposure ages are both about 20–30 Ma, similar to values for many other L chondrites. The cosmogenic ²²Ne/²¹Ne ratio indicates that preatmospheric Ardón was a relatively large body. The fact that the meteorite was hidden in private hands for 83 yr makes one wonder if other meteorite falls may have experienced the same fate, thus possibly explaining the anomalously low number of falls reported in continental Spain in the 20th century.