Heavy metal biosorption potential of a Malaysian Rhodophyte (<Emphasis Type="Italic">Eucheuma denticulatum</Emphasis>) from aqueous solutions

Biosorption is a promising technology for the removal of heavy metals from industrial wastes and effluents. In the present study, biosorption of Pb²⁺, Cu²⁺, Fe²⁺ and Zn²⁺ onto the dried biomass of Eucheuma denticulatum (Rhodophyte) was investigated as a function of solution pH, contact time, temperature and initial metal ion concentration. The experimental data were evaluated by Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherm models. The sorption isotherm data followed Langmuir and Freundlich models, and the maximum Langmuir monolayer biosorption capacity was found as 81.97, 66.23, 51.02 and 43.48 mg g^?1 for Pb²⁺, Cu²⁺, Fe²⁺ and Zn²⁺, respectively. The sorption kinetic data followed pseudo-second-order and intraparticle diffusion models. Thermodynamic study revealed feasible, spontaneous and endothermic nature of the sorption process. Fourier transform infrared analysis showed the presence of amine, aliphatic, carboxylate, carboxyl, sulfonate and ether groups in the cell wall matrix involved in metal biosorption process. A total of nine error functions were applied in order to evaluate the best-fitting models. We strongly suggest the analysis of error functions for evaluating the fitness of the isotherm and kinetic models. The present work shows that E. denticulatum can be a promising low-cost biosorbent for removal of the experimental heavy metals from aqueous solutions. Further study is warranted to evaluate its potential for the removal of heavy metals from the real environment.     

Summer monsoon rainfall scenario over Bangladesh using a high-resolution AGCM

Summer monsoon rainfall was simulated by a global 20 km-mesh atmospheric general circulation model (AGCM), focusing on the changes in the summer monsoon rainfall of Bangladesh. Calibration and validation of AGCM were performed over Bangladesh for generating summer monsoon rainfall scenarios. The model-produced summer monsoon rainfall was calibrated with a ground-based observational data in Bangladesh during the period 1979–2003. The TRMM 3B43 V6 data are also used for understanding the model performance. The AGCM output obtained through validation process made it confident to be used for near future and future summer monsoon rainfall projection in Bangladesh. In the present-day (1979–2003) climate simulations, the high-resolution AGCM produces the summer monsoon rainfall better as a spatial distribution over SAARC region in comparison with TRMM but magnitude may be different. Summer monsoon rainfall projection for Bangladesh was experimentally obtained for near future and future during the period 2015–2034 and 2075–2099, respectively. This work reveals that summer monsoon rainfall simulated by a high-resolution AGCM is not directly applicable to application purpose. However, acceptable performance was obtained in estimating summer monsoon rainfall over Bangladesh after calibration and validation. This study predicts that in near future, summer monsoon rainfall on an average may decrease about ?0.5 % during the period 2015–2034 and future summer monsoon rainfall may increase about 0.4 % during the period 2075–2099.     

Diamond xenolith and matrix organic matter in the Sutter's Mill meteorite measured by C‐XANES

The Sutter's Mill (SM) meteorite fell in El Dorado County, California, on April 22, 2012. This meteorite is a regolith breccia composed of CM chondrite material and at least one xenolithic phase: oldhamite. The meteorite studied here, SM2 (subsample 5), was one of three meteorites collected before it rained extensively on the debris site, thus preserving the original asteroid regolith mineralogy. Two relatively large (10 μm sized) possible diamond grains were observed in SM2‐5 surrounded by fine‐grained matrix. In the present work, we analyzed a focused ion beam (FIB) milled thin section that transected a region containing these two potential diamond grains as well as the surrounding fine‐grained matrix employing carbon and nitrogen X‐ray absorption near‐edge structure (C‐XANES and N‐XANES) spectroscopy using a scanning transmission X‐ray microscope (STXM) (Beamline 5.3.2 at the Advanced Light Source, Lawrence Berkeley National Laboratory). The STXM analysis revealed that the matrix of SM2‐5 contains C‐rich grains, possibly organic nanoglobules. A single carbonate grain was also detected. The C‐XANES spectrum of the matrix is similar to that of insoluble organic matter (IOM) found in other CM chondrites. However, no significant nitrogen‐bearing functional groups were observed with N‐XANES. One of the possible diamond grains contains a Ca‐bearing inclusion that is not carbonate. C‐XANES features of the diamond‐edges suggest that the diamond might have formed by the CVD process, or in a high‐temperature and ‐pressure environment in the interior of a much larger parent body.     

Improvement of very soft ground by a high-efficiency vacuum preloading method: A case study

This paper describes a full-scale test on a very soft clay ground around 70,000?m², which is conducted in Huizhou of Guangdong Province, China, to present a new method of vacuum preloading method. A novel moisture separator was developed, which can automatically regulate the vacuum pressure variation by changing the volume of the gas inside it. A large quantity of water drained by the proposed moisture separators can be directly used as a surcharge loading, which would shorten the ground improvement time and save costs as well. Three levels of silt-prevention prefabricated vertical drains were used in the treating process to accelerate the consolidation. In addition, the vacuum preloading method also included an effective radial drainage device which would strengthen the dredged soft clay fill in a deep layer. In the in situ test, tens of piezometers and settlement plates were installed to measure the variations of excess pore water pressures and settlement of two stages of observation points at different positions in the ground. The results show that the largest average consolidation settlement was 314.1?cm and made a saving of more than 66% in power consumption compared with traditional method. It demonstrates that this adopted method is an efficient, cost-effective, and environmentally friendly method for improving sites with low bearing capacity and high compressibility soils.     

Evolution of geophysical parameters over the Indian Ocean region during contrasting monsoon years of 2002 and 2003 using TRMM/TMI data

Summary The evolution of geophysical parameters over Indian Ocean during two contrasting monsoon years 2002 (drought) and 2003 (normal) were studied using TRMM/TMI satellite data. Analysis indicates that there was a lack of total water vapour (TWV) build up over Western Indian Ocean (WIO) during May 2002 (drought) when compared to 2003 (normal). Negative (positive) TWV anomalies were found over the WIO in May 2002 (2003). In 2002, negative SST anomaly of ∼1.5 °C is found over entire WIO when compared to 2003. Anomalously high sea surface wind speed (SWS) anomaly over the South West Indian Ocean (SWIO) and WIO would have resulted in cooling of the sea surface in May 2002 in comparison to 2003. In 2003 the wind speed anomaly over entire WIO and Arabian Sea (AS) was negative, whereas sea surface temperature (SST) anomaly was positive over the same region, which would have resulted in higher moisture availability over these regions. A negative (positive) TWV anomaly over Eastern Arabian Sea (EAS) and positive (negative) anomaly over WIO forms a dipole structure. In the month of June no major difference is seen in all these parameters over the Indian Ocean. In July 2002 the entire WIO and AS was drier by 10–15 mm as compared to 2003. The pentad (5 day) average TWV values shows high (>55 mm) TWV convergence over EAS and Bay of Bengal (BoB) during active periods of 2003, which gives high rainfall over these regions. However, during 2002 although TWV over BoB was >55 mm but it was ∼45–55 mm over EAS during entire July and hence less rainfall. The evaporation has been calculated from the bulk aerodynamic formula using TRMM/TMI geophysical products. It has been seen that the major portion of evaporative moisture flux is coming from southern Indian Ocean (SIO) between 15 and 25° S. Evaporation in June was more over AS and SIO in 2003 when compared to 2002 which may lead to reduce moisture supply in July 2002 and hence less rainfall compared to July 2003.     

Retrieval of tropical forest biomass information from ALOS PALSAR data

Advanced Land Observing Satellite Phased Array L-band Synthetic Aperture Radar (ALOS PALSAR) data from different observation modes were analysed to determine (1) which observation mode most accurately retrieves tropical forest biomass information and (2) whether different modes, when considered together, yield improved results in comparison to identical data-sets analysed independently. We performed regression analysis to estimate above-ground forest biomass using PALSAR backscatter data for natural and planted forests in south-eastern Bangladesh. The coefficient of determination (r ²) was lower or equal to 0.499 (n = 70) when PALSAR data from different observation modes were separately considered, but increased sharply when one class (rubber) is dropped and average backscatter of fine beam single (FBS) and polrimetric (PLR) modes are used in the analysis. The results presented in this article are useful for both regional and global forest biomass inventories and fixing acquisition modes for planned L-band SAR missions.     

Comparison of NCEP turbulent heat fluxes with in situ observations over the south-eastern Arabian Sea

Turbulent surface heat fluxes (latent and sensible heat) are the two most important parameters through which air–sea interaction takes place at the ocean–atmosphere interface. These fluxes over the global ocean are required to drive ocean models and to validate coupled ocean–atmosphere global models. But because of inadequate in situ observations these are the least understood parameters over the tropical Indian Ocean. Surface heat fluxes also contribute to the oceanic heat budget and control the sea surface temperature in conjunction with upper ocean stratification and ocean currents. The most widely used flux products in diagnostic studies and forcing of ocean general circulation models are the ones provided by the National Centres for Environment Prediction (NCEP) reanalysis. In this study we have compared NCEP reanalysed marine meteorological parameters, which are used for turbulent heat fluxes, with the moored buoy observation in the south-eastern Arabian Sea. The NCEP latent heat flux (LHF) and sensible heat flux (SHF) derived from bulk aerodynamic formula are also compared with that of ship and buoy derived LHF and SHF. The analysis is being carried out during the pre-monsoon and monsoon season of 2005. The analysis shows that NCEP latent as well as sensible heat fluxes are largely underestimated during the monsoon season, however, it is reasonably comparable during the pre-monsoon period. This is largely due to the underestimation of NCEP reanalysis air temperature (AT), wind speed (WS) and relative humidity (RH) compared to buoy observations. The mean differences between buoy and NCEP parameters during the monsoon (pre-monsoon) period are ~21% (~14%) for WS, ~6% (~3%) for RH, and ~0.75% (0.9%) for AT, respectively. The sudden drop in AT during rain events could not be captured by the NCEP data and, hence, large underestimations in SHF. During the pre-monsoon period, major contribution to LHF variations comes from WS, however, both surface winds and relative humidity controls the LHF variations during the monsoon. LHF is mainly determined by WS and RH during the monsoon and, WS is the main contributor during the pre-monsoon.