Investigation of pyrite oxidation and acid mine drainage characterization associated with Razi active coal mine and coal washing waste dumps in the Azad shahr–Ramian region,northeast Iran

Acid mine drainage (AMD) pollution is considered to be the most serious water pollution problem in mining areas. AMD containing iron sulfates and other components can affect the receiving water bodies. Pyrite oxidation and AMD generation can be considered as important processes that may take place in the wastes produced by coal mining and coal washing operations in the Golestan province (northeast Iran). The study area is characterized by appropriate atmospheric conditions that favor pyrite oxidation and the presence of a large amount of water bodies. This study attempts to consider pyrite oxidation and AMD generation in the Azad shahr–Ramian region. The impact of AMD on the quality of the surface water bodies was investigated by taking samples and analyzing them for hydro-geochemical parameters. Stiff and Piper diagrams were used to represent chemical analyses of water samples. The coal samples taken from different depths at four points on two different coal waste dumps were analyzed to find the fraction of pyrite that remained in the waste particles to investigate the pyrite oxidation process. A computational fluid dynamic package called PHOENICS was used to model pyrite oxidation process numerically. The results obtained from the geochemical analyses of water and coal samples and numerical simulation show pyrite oxidation and acid generation in the region. However, the presence of carbonate rocks raised the pH of the water samples. The drainages of the Razi mine may be recognized as natural alkaline mine drainages.     

The Laal-Kan fluorite deposit,Zanjan Province,NW Iran: constraints on REE geochemistry and fluid inclusions

The Laal-Kan fluorite deposit (west of Zanjan city, NW Iran) mainly occurred as some open-space filling and vein/veinlet in the schist of the Paleozoic age. Mineralogically, calcite, fluorite types (white, smoky, and violet), and quartz are the principal constituents accompanied by a number of minor accessory minerals such as hemimorphite, hematite, barite, and clays. Based on chemical analyses, fluorites of various colors were found to have low rare earth element (REE) concentrations (4.16–25.67 ppm). The chondrite-normalized REE patterns indicated that early fluorites were enriched in LREE, relative to HREE, whereas late fluorites were enriched in HREE relative to LREE. This study, therefore, indicated that fugacity of oxygen likely played a significant role in the occurrence of positive Ce and negative anomaly in the late fluorite. Furthermore, the Gd behavior of the fluorite samples could be attributed to the Gd-F complex in ore-forming fluids. On the other hand, low pH hydrothermal fluids under alkaline conditions were probably the main mechanism responsible for the deposition of the early fluorites in this district. Fluorite-hosted fluid inclusion analyses also indicated that fluorite-forming fluids consisted of NaCl, MgCl₂, CaCl₂, and LiCl with a narrow T_H (118–151 °C) and high salinities (18.96–23.47 wt.% NaCl equiv.). Further, the diagram of Tb/La-Tb/Ca ratios revealed that fluorites were predominantly deposited in the hydrothermal environment and the late stage fluorites could be considered as the product of the secondary mineralization of the early fluorites due to the interaction of the fluid with the early fluorites.     

Assessing the hydrogeochemistry and water quality of the Aji-Chay River,northwest of Iran

Aji-Chay River is one of the most important surface reservoirs of northwest of Iran, because it passes through Tabriz city and discharges to Urmia Lake, one of the largest permanent salty lakes in the world. The main objectives of the present study are to evaluate its overall water quality and to explore its hydrogeochemical characteristics, including the potential contamination from heavy metals and metalloids such as Co, Pb, Zn, Cd, Cu, Cr, Al and As. For this purpose, 12 water samples were collected from the main river body and its tributaries within Tabriz plain. The Piper diagram classified water samples mainly into Na–Cl and secondary into Ca–HCO₃ and mixed Ca–Mg–Cl types, denoting a profound salinization effect. The cross-plots showed that natural geochemical processes including dissolution of minerals (e.g., carbonates, evaporites and silicates), as well as ion exchange, are the predominant factors that contribute to fluvial hydrogeochemistry, while anthropogenic activities (industrial and agricultural) impose supplementary effects. Cluster analysis classified samples into two distinct clusters; samples of cluster B appear to have elevated electrical conductivity (EC) values and trace metals concentrations such as Co, Pb and Cd, while SiO₂ and Zn are low in comparison with the samples of the cluster A. The main processes controlling Aji-Chay River hydrogeochemistry and water quality were identified to be salinization and rock weathering. Both are related with geogenic sources which enrich river system with elevated values of Na⁺, Cl^?, Ca²⁺, Mg²⁺, K⁺, SO₄ ^2? and EC as a direct effect of evaporites leaching and elevated values of Pb and Cd as an impact from the weathering process of volcanic formations. According to the US salinity diagram, all of the water samples are unsuitable for irrigation as having moderate to bad quality.     

Identification of hydrogeochemical processes and pollution sources of groundwater resources in the Marand plain,northwest of Iran

The main aims of the present study are to identify the major factors affecting hydrogeochemistry of groundwater resources in the Marand plain, NW Iran and to evaluate the potential sources of major and trace elements using multivariate statistical analysis such as hierarchical clustering analysis (HCA) and factor analysis (FA). To achieve these goals, groundwater samples were collected in three sampling periods in September 2013, May 2014 and September 2014 and analyzed with regard to ions (e.g., Ca²⁺, Mg²⁺, Na⁺ and K⁺, HCO₃ ^?, SO₄ ^2?, Cl^?, F^? and NO₃ ^?) and trace metals (e.g., Cr, Pb, Cd, Mn, Fe, Al and As). The piper diagrams show that the majority of samples belong to Na–Cl water type and are followed by Ca–HCO₃ and mixed Ca–Na–HCO₃. Cross-plots show that weathering and dissolution of different rocks and minerals, ion exchange, reverse ion exchange and anthropogenic activities, especially agricultural activities, influence the hydrogeochemistry of the study area. The results of the FA demonstrate that 6 factors with 81.7% of total variance are effective in the overall hydrogeochemistry, which are attributed to geogenic and anthropogenic impacts. The HCA categorizes the samples into two clusters. Samples of cluster C1, which appear to have higher values of some trace metals like Pb and As, are spatially located at the eastern and central parts of the plain, while samples of cluster C2, which express the salinization of the groundwater, are situated mainly westward with few local exceptions.     

Web GIS: Implementation issues

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Deterioration of groundwater quality in the vicinity of an active open-tipping site in West Malaysia

There is an urgent need for characterization of leachate arising from waste disposal to ensure a corresponding effective leachate management policy. Field and laboratory studies have been carried out to investigate the impact of municipal landfill leachate on the underlying groundwater at a site in West Malaysia. The solid waste was disposed of directly onto an unprotected natural soil formation. This situation was made worse by the shallow water table. The hydrochemical composition of groundwater in the vicinity of the site (background) is a dilute mixed cation, bicarbonate water. The high ionic balance error of ~13.5% reveals that the groundwater body underneath the site was a highly contaminated leachate rather than contaminated groundwater. Elevated concentration of chloride (355.48 mg/L), nitrate (10.40 mg/L as NO₃), nitrite (14.59 mg/L), ammoniacal-N (11.61 mg/L), sodium (227.56 mg/L), iron (0.97 mg/L), and lead (0.32 mg/L) measured downgradient indicate that the contamination plume has migrated further away from the site. In most cases, the concentration of these contamination indicators, together with the ranges of sodium percentage (66.3–89.9%) and sodium adsorption ratio (10.1–19.7%), were found to be considerably higher than the limit values of safe water for both domestic and irrigation purposes, respectively.     

Groundwater investigation in Kuala Selangor using vertical electrical sounding (VES) surveys

Integrated geoelectrical and hydrochemical surveys were used to investigate and delineate different types of groundwater in the Kuala Selangor alluvial aquifer. Previous hydrogeological borehole investigation showed that this aquifer contains several types of groundwater in relation to its salinity. The high salinity of the groundwater in some areas is believed to be due to either saltwater intrusion from the nearby sea or river infiltration during high tide season. The vertical electrical sounding (VES) method was employed to study and map the subsurface variation of resistivity in the area. For each sounding measurement, a total spread length of 300 m was obtained with a vertical depth penetration of about 60 to 75 m. Chemical analysis of the groundwater samples taken from both shallow and deep boreholes was carried out for the water quality determination. A total of 45 VES stations were succesfully established along three parallel roads with a direction almost perpendicular to the coastal line. The distance between stations varies from 1 to 2 km with a maximum length of about 60 km surveyed line. Results of the vertical electrical soundings as well as the hydrochemistry of the groundwater samples show that the soil and groundwater in the study area can be grouped into fresh and brackish water zones. The subsurface resisitivity sections derived from the VES study suggest that the area is dominated by brackish soil and groundwater zones, especially in the area towards the coast. This result appears to agree well with the groundwater pumped from boreholes scattered around in the area. Water drawn from boreholes near the coast showed higher salinity compared to the water pumped from inland boreholes. Chloride values greater than 250 mg/L are considered to represent the brackish zones whilst values less than 250 mg/L represents zones of fresh soil and groundwater.     

Application of the FMEA in insurance of high-risk industries: a case study of Iran's gas refineries

The purpose of this paper is to categorize and analyze various risk factors in Irans gas refineries for insurance purposes. Using the failure modes and effects analysis method as a subset of probability risk assessment technique and gas refineries data for the period March 2011 till March 2012, risk priorities numbers are calculated from the perspectives of both the insured party (gas industries) and the insurer (insurance companies). Our empirical results indicate that various property damage risk factors embodied in gas refineries including fire, explosion, error and omission, and machinery breakdown are insurable risks. Risks of pressurized vessels defects are in safe category and can be tolerated by the industry owner. The policy implication of this paper for Iranian policy makers in the energy sector is that, gas refineries are insurable in the market with reasonable risk premium. Insuring gas refineries will definitely reduce capital losses which can otherwise be enormous for the economy in general and for oil and gas industries in particular.