Transmission of light by slit designed for astronomical spectrograph

The paper discusses an investigation of linear polarization produced by the transmission of light through an astronomical spectrograph slit. An experimental apparatus was designed and set up to carry out this work. The parallel beam of plane polarized light was rotated in the measuring system, by optically active of half-wave plate. The intensity of normally incident of polarized light of wavelength 0.436 μm transmitted by various slit was measured as a function of slit width. The results indicate:

1. That the degree of polarization increased as thedepth of the narrow slit was increased.
2. That the degree of polarization increased as thewidth of the narrow slit was decreased.
3. That when the width of slit was widened the degree of polarization tended to approach a constant value asymptotically.
4. That the theoretical calculation of Slater (1942) predicts the measured experimental values more accurately than Thiessen (1947) and Jones and Richards (1954).

It is shown that the existence and order of magnitude of all these effects may be predicted from the propagation losses of the electromagnetic theory of light in metallic wave guide. The paper brings out the salient points related to the degree of polarization of light by a dielectric slit of finite depth. The polarization effects from one such slit have been investigated and the results were compared with those for metallic slits.     

Electrokinetic migration of permanganate through low-permeability media

This research was conducted to evaluate the combination of electromigration and potassium permanganate as a potential remediation method for low-permeability media (e.g., soil and sediment) contaminated with dissolved and sorbed organic contaminants. The experimental procedure was composed of two stages: determination of migration rates of permanganate through homogeneous cores and a primarily qualitative analysis of migration in more heterogeneous, two-dimensional scenarios. Results indicated that transport of permanganate through fine-grained porous media and clays can be undertaken using electromigration, and electromigration rates were found to be at least 400% faster than diffusion alone. In addition, the use of an applied electric field in a flushing scenario was shown to result in almost 100% sweep efficiency of a domain consisting of clay blocks interspersed in a glass bead medium. The results of the study show that there is potential for this method to be able to deliver permanganate and other potential remedial agents to treat contaminated zones within heterogeneous and low-permeability porous media through in situ chemical oxidation or other processes.     

Sediment transport in high‐speed flows over a fixed bed: 1. Particle dynamics

Particle dynamics are investigated experimentally in supercritical high‐speed open channel flow over a fixed planar bed of low relative roughness height simulating flows in high‐gradient non‐alluvial mountain streams and hydraulic structures. Non‐dimensional equations were developed for transport mode, particle velocity, hop length and hop height accounting for a wide range of literature data encompassing sub‐ and supercritical flow conditions as well as planar and alluvial bed configurations. Particles were dominantly transported in saltation and particle trajectories on planar beds were rather flat and long compared with alluvial bed data due to (1) increased lift forces by spinning motion, (2) strongly downward directed secondary currents, and (3) a planar flume bed where variation in particle reflection and damping effects were minor. The analysis of particle saltation trajectories revealed that the rising and falling limbs were almost symmetrical contradicting alluvial bed data. Furthermore, no or negligible effect of particle size and shape on particle dynamics were found. Implications of experimental findings for mechanistic saltation‐abrasion models are briefly discussed. Copyright © 2017 John Wiley & Sons, Ltd.     

Effects of additional HONO sources on visibility over the North China Plain

The objective of the present study was to better understand the impacts of the additional sources of nitrous acid （HONO） on visibility, which is an aspect not considered in current air quality models. Simulations of HONO contributions to visibility over the North China Plain （NCP） during August 2007 using the fully coupled Weather Research and Forecasting/Chemistry （WRF/Chem） model were performed, including three additional HONO sources： （1） the reaction of photo-excited nitrogen dioxide （NO~） with water vapor; （2） the NO2 heterogeneous reaction on aerosol surfaces; and （3） HONO emissions. The model generally reproduced the spatial patterns and diurnal variations of visibility over the NCP well. When the additional HONO sources were included in the simulations, the visibility was occasionally decreased by 20%-30% （3-4 km） in local urban areas of the NCP. Monthly-mean concentrations of NO3, NH＋, SO]- and PM2.5 were increased by 20%-52% （3-11μg m-3）, 10%-38%, 6%-10%, and 6%-11% （9-17 μg m-3）, respectively; and in urban areas, monthly-mean accumulation- mode number concentrations （AMNC） and surface concentrations of aerosols were enhanced by 15%-20% and 10%-20%, respectively. Overall, the results suggest that increases in concentrations of PM2.5, its hydrophilic components, and AMNC, are key factors for visibility degradation. A proposed conceptual model for the impacts of additional HONO sources on visibility also suggests that visibility estimation should consider the heterogeneous reaction on aerosol surfaces and the enhanced atmospheric oxidation capacity due to additional HONO sources, especially in areas with high mass concentrations of NOx and aerosols.     

Nickel removal from electroplating waste water using stand-alone and electrically assisted ion exchange processes

Wastewater discharged from metal-finishing processes usually contains nickel, a hazardous substance that is used extensively in the surface finishing industry. In the present study, an acidic solution containing nickel was treated using strong acid cation exchange resin. A continuous lab-scale cation exchange arrangement permitting the assessment of electric current as an enhancement mechanism was designed and utilized at different flow rates successfully. Applying the electrical potential enhanced the nickel removal by 12.7 % at flow rate 240 ml/h, and 2.5 % at flow rate 500 ml/h. Nickel recovery has been also investigated using hydrochloric acid as an eluent with and without electric current enhancement.     

Ramadan and Bussorah Street: the spirit of place

The presence of ‘seasonal spaces’ such as the Ramadan-related activities associated with Bussorah Street, Singapore, during the holy Muslim month of Ramadan surfaces significant issues on the convergence and management of identity, heritage, space and conservation important to all Singaporeans. Conservation projects to ‘prettify’ or commodify the historic district of Kampong Glam, which contains Bussorah Street had to be revised to include the local tradition of the Ramadan food bazaar but at the adjoining Kandahar Street. Undoubtedly, what is being underlined by this seasonal space is the affirmation of identity, the reclamation of space and the possibility for improved management and economic viability of the Kampong Glam district. However, as stressed in the paper, that while the spirit of Bussorah Street can be construed as forms of spatial or cultural resilience, the new Malay Heritage Centre (Taman Warisan Melayu) located in the district acts as a strong reminder that, ultimately, ‘seasonal spaces’ are still subjected to the calculated considerations of the Singapore urban planners or the governing elite with significant implications for those with strong ethnic and religious connections with the area and its Islamic heritage.

Improving WRF-Hydro runoff simulations of heavy floods through the sea surface temperature fields with higher spatio-temporal resolution

This study investigates the impact of the spatio-temporal accuracy of four different sea surface temperature (SST) datasets on the accuracy of the Weather Research and Forecasting (WRF)-Hydro system to simulate hydrological response during two catastrophic flood events over the Eastern Black Sea (EBS) and the Mediterranean (MED) regions of Turkey. Three time-variant and high spatial resolution external SST products (GHRSST, Medspiration and NCEP-SST) and one coarse-resolution and time-invariant SST product (ERA5- and GFS-SST for EBS and MED regions, respectively) already embedded in the initial and the boundary conditions datasets of WRF model are used in deriving near-surface atmospheric variables through WRF. After the proper event-based calibration is performed to the WRF-Hydro system using hourly and daily streamflow data in both regions, uncoupled model simulations for independent SST events are conducted to assess the impact of SST-triggered precipitation on simulated extreme runoff. Some localized and temporal differences in the occurrence of the flood events with respect to observations depending on the SST representation are noticeable. SST products represented with higher cross-correlations (GHRSST and Medspiration) revealed significant improvement in flood hydrographs for both regions. The GHRSST dataset shows a substantial improvement in NSE (~70%), RMSE reduction up to 20%, and an increase in correlation from 0.3 to 0.8 with respect to the invariable SST (ERA5) in simulated runoffs over the EBS region. The use of both GHRSST and Medspiration SST data characterized with high spatio-temporal correlation resulted in runoff simulations exactly matching the observed runoff peak of 300 m³/s by reducing the overestimation seen in invariable SST (GFS) in the MED region. Improved precipitation simulation skills of the WRF model with the detailed SST representation show that the hydrographs of GHRSST and Medspiration simulations show better performance compared to the simulated hydrographs by observed precipitation.     

Ionic liquid as a medium to remove iron and other metal ions: a case study of the North Kelantan Aquifer,Malaysia

An alternative iron removal treatment method using liquid-liquid extraction with the room-temperature ionic liquid, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide, as a solvent medium was studied. The chelating agent 1,10-phenanthroline was used as the extractant. The extraction of Fe(III) and Fe(II) was influenced significantly by the pH of the aqueous phase. The successful removal of iron was achieved; more than 95 % of the initial iron concentration was removed from the groundwater samples. However, detailed research is needed before the ionic liquid method can replace the conventional groundwater treatment protocol because the recovery rate was very low upon reuse (approximately 25–60 %). This low recovery was due to the ion exchange process; the appearance of anions from ionic liquids was also detected in groundwater samples.     

Knickpoints along the upper Indus River,Pakistan: an exploratory survey of geomorphic processes

This article summarizes an exploratory study carried out to investigate the significance of various geomorphic features on the formation of observed knickpoints along the upper Indus River in northern Pakistan. These features include bedrock lithology, active faults, sediment flux from tributary channels, and landslide dams which have blocked the main channel. The knickpoints and their related geomorphic parameters (channel profile, concavity, drainage area and normalized steepness index, etc.) were extracted from Advanced Spaceborne Thermal Emission and Reflection (ASTER) Global Digital Elevation Models (GDEMs) with 30 m resolution using ArcGIS, River Tools, and Matlab software. A total of 251 major and minor knickpoints were extracted from the longitudinal profile along a ~ 750 km reach upstream of Tarbela Reservoir. The identified knickpoints and their respective normalized steepness index (k_sn values) were compared with bedrock lithology, mapped faults, regional landslide/rockslide inventory, and the locations of historic landslide dams. The analyses revealed that the knickpoints do not correlate with the bedrock lithology except where major unit boundaries coexist with mapped faults, especially in reaches criss-crossed by active thrust faults in the Nanga Parbat Haramosh (NPHM) region. Neither did the river’s major confluences exhibit any notable knickpoints, but the correlations between knickpoints, mapped landslides, and historic rockslide avalanche dams accounted for approximately 75% of the observed knickpoints, a surprising finding. These observations suggest that more detailed studies aided by high resolution data should be undertaken to further explore the characteristics of knickpoints triggered by tectonic uplift, local fault offset, bedrock erodibility, and landslide/rockslide dams.