Sediment transport at the network scale and its link to channel morphology in the braided Vjosa River system

In this article we apply the CASCADE network-scale sediment connectivity model to the Vjosa River in Albania. The Vjosa is one of the last unimpaired braided rivers in Europe and, at the same time, a data scarce environment, which limits our ability to model how this pristine river might respond to future human disturbance. To initialize the model, we use remotely sensed data and modeled hydrology from a regional model. We perform a reach-by-reach optimization of surface grain size distribution (GSD) and bedload transport capacity to ensure equilibrium conditions throughout the network. In order to account for the various sources of uncertainty in the calculation of transport capacity, we performed a global sensitivity analysis. The modeled GSD distributions generated by the sensitivity analysis generally match the six GSDs measured at different locations within the network. The modeled bedload sediment fluxes increase systematically downstream, and annual fluxes at the outlet of the Vjosa are well within an order of magnitude of fluxes derived from previous estimates of the annual suspended sediment load. We then use the modeled sediment fluxes as input to a set of theoretically derived functions that successfully discriminate between multi-thread and single-thread channel patterns. This finding provides additional validation of the model results by showing a clear connection between modeled sediment concentrations and observed river morphology. Finally, we observe that a reduction in sediment flux of about 50% (e.g., due to dams) would likely cause existing braided reaches to shift toward single thread morphology. The proposed method is widely applicable and opens a new avenue for application of network-scale sediment models that aid in the exploration of river stability to changes in water and sediment fluxes.     

Trapping and adsorption of CO2 in amorphous ice: A FTIR study

The interaction of carbon dioxide and amorphous water ice at 95 K is studied using transmission infrared spectroscopy. Samples are prepared in two ways: co-deposition of the gases admitted simultaneously or sequential deposition, in which amorphous water ice (ASW) is grown first and CO₂ vapor is added subsequently. In either case, a fraction of the CO₂ molecules is found to interact with water in a way that gives rise to shifts and splittings in the infrared bands with respect to those of a pure CO₂ solid. In co-deposition experiments, a larger amount of carbon dioxide is trapped within the amorphous water than in sequential deposition samples, where a substantial proportion of molecules appears to be trapped in macropores of the ASW. The specific surface area of sequential samples is evaluated and compared to previous literature results. When the sequential samples are heated to 140 K, beyond the onset temperature at which water ice undergoes a phase transition, the CO₂ molecules at the pores relocate inside the bulk in a structure similar to that found in co-deposited samples, as deduced by changes in the shape of the CO₂ infrared bands.     

Euro-Cordex Regional Projection Models: What Kind of Agreement for Europe?

Mathematical Geosciences - EURO-CORDEX is an international initiative which provides regional climate projections based on multiple dynamical and empirical–statistical downscaling models. The...     

Metals in eggs and hatchlings of Dermochelys coriacea (testudines) in Espírito Santo,Brazil and their relation to hatching and emergence success

Certain concentration of metal may influence survival in embryonic stages, reducing the birthrate and hatching emergence. This study aimed to evaluate concentration of metal in eggs and hatchlings of Dermochelys coriacea and correlate metal concentrations in eggs with hatching and emergence success. The samples were collected at Biological Reserve Station, ES, Brazil. At the nests' opening, unhatched eggs and stillborn hatchlings were collected to survey the successful hatching and emergence of D. coriacea. The eggs shell, egg content, and dead hatchlings metal concentrations were compared to hatching and emergence success. A positive correlation was found between the concentration of copper (Cu) in the hatchlings and the success of the emergence (r² = .28, p < .05), and a moderate positive correlation between the concentrations of iron (Fe) and barium (Ba; r² = .44, p < .05) and success hatching. The concentrations of metals in eggs and hatchlings of D. coriacea in the Espírito Santo are below the levels that could be considered harmful to the species. In summary, there is a positive correlation between metals levels and hatching and emergence success.     

Relationships between the AE, ap and Dst indices near solar minimum (1974) and at solar maximum (1979)

Three-hourly average values of the Dst, AE and ap geomagnetic activity indices have been studied for 1 years duration near the solar minimum (1974) and also at the solar maximum (1979). In 1979 seven intense geomagnetic storms (Dst < –100 nT) occurred, whereas in 1974 only three were reported. This study reveals: (1) the yearly average of AE is greater in 1974 than in 1979, whereas the inverse seems to be true for the yearly average of Dst, when a higher number of intense storms is present. These averages indicate the kind of activity occurring on the sun as shown in earlier work. (2) The seasonal variation of Dst is higher than that of ap and is almost negligible in AE. (3) The correlation coefficient of ap × AE is in general the highest, as the magnetometers that monitor both indices are close, and is surpassed only by the ap × Dst correlation during geomagnetic storms, when the influence of the ring current is dominant. The correlation of ap × Dst also shows a seasonal variability. (4) For the first time a study of correlation between ap and a linear combination of AE and Dst has also been made. We found higher correlation coefficients in this case as compared to those between ap × Dst and ap ×xs AE.     

Multiple Random Walk Simulation: A Fast Method to Map Grade Uncertainty with Large Datasets

Multiple Random Walk Simulation consists of a methodology adapted to run fast simulations if close-spaced data are abundant (e.g., short-term mining models). Combining kriging with the simulation of random walks attempts to approximate traditional simulation algorithm results but at a computationally faster way when there is a large amount of conditioning samples. This paper presents this new algorithm illustrating the situations where the method can be used properly. A synthetic study case is presented in order to illustrate the Multiple Random Walk Simulation and to analyze the speed and goodness of its results against the ones from using Turning Bands Simulation and Sequential Gaussian Simulation.     

Integrating Stalagmite, Vertebrate, and Pollen Sequences to Investigate Holocene Vegetation and Climate Change in the Southern Midwestern United States

Speleothem carbon and oxygen isotopic records from Onondaga Cave, south-central Missouri, and Beckham Creek Cave, north-central Arkansas, are compared with the Cupola Pond and Oldfield Swamp pollen series from southeastern Missouri and the Rodgers Shelter and Modoc Shelter vertebrate biostratigraphic sequences from central Missouri and southwestern Illinois. Similar, and roughly contemporaneous, shifts between deciduous forest and steppe indicators throughout the Holocene are revealed in each database. These independent proxies record steppe conditions between approximately 9000 and 1500 cal yr B.P. A shift toward lighter speleothem carbon may reflect a change from warm and dry to cool and dry conditions between 4500 and 3000 yr B.P. The sensitive response of speleothem δ¹³C to changes in vegetation emphasizes their importance as paleoclimate records in an area containing few other millenial-scale climate proxies.     

Stable isotope paleohydrology and chemostratigraphy of the Albian Wayan Formation from the wedge-top depozone,North American Western Interior Basin

Understanding of the role of atmospheric moisture and heat transport in the climate system of the Cretaceous greenhouse world represents a major challenge in Earth system science.Stable isotopic paleohydrologic data from mid-Cretaceous paleosols in North America,from paleoequatorial to paleoArctic latitudes,have been used to constrain the oxygen isotope mass balance of the Albian hydrologic cycle.Over the range from 40°-50°N paleolatitude,sideritic paleosols predominate,indicating paleoenvironments with positive precipitation-evaporation(P-E)balances.Local exceptions occur on leeward side of the Sevier Orogen,where calcic paleosols in the wedge-top depozone record paleoenvironments with negative P-E balances in the orographic rain shadow.Stratigraphic sections in the Wayan Formation of Idaho(WF)were sampled from the wedge-top depozone.The units consist of stacked m-scale mudstone paleosols separated by m-scale sandstone-siltstone beds.Sections were sampled for organic carbon isotope profiles,and B-horizons from 6 well-developed paleosols were sampled for detrital zircons to determine maximum depositional ages.The first of these from the WF has produced a U-Pb concordia age of 101.0±1.1 Ma.This same WF section has produced a stratigraphic trend of upwardly decreasingδ~(13)C values ranging from-24‰upwards to-27‰VPDB,suggesting correlation to the late Albian C15 C-isotope segment.Pedogenic carbonates from the WF principally consist of micritic calcite,with carbon-oxygen isotope values that array along meteoric calcite lines(MCLs)withδ~(18)O values that range from-9.47‰up to-8.39‰VPDB.At approximately 42°N paleolatitude,these MCL values produce calculated paleoprecipitation values of-8.12‰to-7.04‰VSMOW,a range that is consistent with the estimates produced from other proxies at the same paleolatitudes across North America.These results indicate that despite the orographic rain shadow effect,the processes of meridional atmospheric moisture transport in this locale were similar to those in more humid mid-latitude paleoenvironments elsewhere in the continent.     

Assessment of soil factors controlling ephemeral gully erosion on agricultural fields

The soil factor is crucial in controlling and properly modeling the initiation and development of ephemeral gullies (EGs). Usually, EG initiation has been related to various soil properties (i.e. sealing, critical shear stress, moisture, texture, etc.); meanwhile, the total growth of each EG (erosion rate) has been linked with proper soil erodibility. But, despite the studies to determine the influence of soil erodibility on (ephemeral) gully erosion, a universal approach is still lacking. This is due to the complex relationship and interactions between soil properties and the erosive process. A feasible soil characterization of EG erosion prediction on a large scale should be based on simple, quick and inexpensive tests to perform. The objective of this study was to identify and assess the soil properties – easily and quickly to determine – which best reflect soil erodibility on EG erosion. Forty‐nine different physical–chemical soil properties that may participate in establishing soil erodibility were determined on agricultural soils affected by the formation of EGs in Spain and Italy. Experiments were conducted in the laboratory and in the field (in the vicinity of the erosion paths). Because of its importance in controlling EG erosion, five variables related to antecedent moisture prior to the event that generated the gullies and two properties related to landscape topography were obtained for each situation. The most relevant variables were detected using multivariate analysis. The results defined 13 key variables: water content before the initiation of EGs, organic matter content, cation exchange capacity, relative sealing index, two granulometric and organic matter indices, seal permeability, aggregates stability (three index), crust penetration resistance, shear strength and an erodibility index obtained from the Jet Test erosion apparatus. The latter is proposed as a useful technique to evaluate and predict soil loss caused by EG erosion. Copyright © 2018 John Wiley & Sons, Ltd.