Determination of lead, naphthalene, phenanthrene, anthracene and pyrene in street dust

Street dust is a potential source of lead exposure to humans, however scarce information about the pollution levels with lead and polyromatic hydrocarbons exists in Venezuela, limiting the appropriate evaluation of the levels of risk of the people. This work was aimed in the determination of the concentrations of lead, naphtalene, anthracene, phenanthrene and pyrene in the street dust of the most transited avenues and streets of Maracay city. Thirty street dust samples were collected at the streets and avenues, troll and bus main station. Lead was determined by atomic absorption spectrometry after acid digestion (Pb-total), also the fractions of lead soluble in 1 M MgCl₂ and 0.5 M ammonium acetate (pH = 7) were quantified. The polyaromatic hydrocarbons concentrations were determined by capillary gas chromatography equipped with a flame ionization detector. The Pb-total ranged between 734 and 11.439 μg/g with the higher values at the most transited streets and avenues. About 60 % of samples exhibited concentrations between 1.000 and 2.500 μg/g, similar to the values reported in the literature for soils of urban areas. The fraction of lead soluble in magnesium accounted for less than 3 % of Pb-Total, while the 0.5 M ammonium acetate solution represented more than the 75 % of the total loads of the pollutant. The most contaminated samples were those taken at the toll with concentrations of 695.5 and 252.1 μg/g phenanthrene and anthracene were the most abundant, while at the bus station all compounds were detected.     

Quartz‐in‐garnet and Ti‐in‐quartz thermobarometry: Methodology and first application to a quartzofeldspathic gneiss from eastern Papua New Guinea

Mineral inclusions are ubiquitous in metamorphic rocks and elastic models for host‐inclusion pairs have become frequently used tools for investigating pressure–temperature (P–T) conditions of mineral entrapment. Inclusions can retain remnant pressures () that are relatable to their entrapment P–T conditions using an isotropic elastic model and P–T–V equations of state for host and inclusion minerals. Elastic models are used to constrain P–T curves, known as isomekes, which represent the possible inclusion entrapment conditions. However, isomekes require a temperature estimate for use as a thermobarometer. Previous studies obtained temperature estimates from thermometric methods external of the host‐inclusion system. In this study, we present the first P–T estimates of quartz inclusion entrapment by integrating the quartz‐in‐garnet elastic model with titanium concentration measurements of inclusions and a Ti‐in‐quartz solubility model (QuiG‐TiQ). QuiG‐TiQ was used to determine entrapment P–T conditions of quartz inclusions in garnet from a quartzofeldspathic gneiss from Goodenough Island, part of the (ultra)high‐pressure terrane of Papua New Guinea. Raman spectroscopic measurements of the 128, 206, and 464 cm^?1 bands of quartz were used to calculate inclusion pressures using hydrostatic pressure calibrations (), a volume strain calculation (), and elastic tensor calculation (), that account for deviatoric stress. values calculated from the 128, 206, and 464 cm^?1 bands’ hydrostatic calibrations are significantly different from one another with values of 1.8 ± 0.1, 2.0 ± 0.1, and 2.5 ± 0.1 kbar, respectively. We quantified elastic anisotropy using the 128, 206 and 464 cm^?1 Raman band frequencies of quartz inclusions and stRAinMAN software (Angel, Murri, Mihailova, & Alvaro, 2019,  234 :129–140). The amount of elastic anisotropy in quartz inclusions varied by ~230%. A subset of inclusions with nearly isotropic strains gives an average and of 2.5 ± 0.2 and 2.6 ± 0.2 kbar, respectively. Depending on the sign and magnitude, inclusions with large anisotropic strains respectively overestimate or underestimate inclusion pressures and are significantly different (<3.8 kbar) from the inclusions that have nearly isotropic strains. Titanium concentrations were measured in quartz inclusions exposed at the surface of the garnet. The average Ti‐in‐quartz isopleth (19 ± 1 ppm [2σ]) intersects the average QuiG isomeke at 10.2 ± 0.3 kbar and 601 ± 6°C, which are interpreted as the P–T conditions of quartzofeldspathic gneiss garnet growth and entrapment of quartz inclusions. The P–T intersection point of QuiG and Ti‐in‐quartz univariant curves represents mechanical and chemical equilibrium during crystallization of garnet, quartz, and rutile. These three minerals are common in many bulk rock compositions that crystallize over a wide range of P–T conditions thus permitting application of QuiG‐TiQ to many metamorphic rocks.     

Chemical Characterization of Biosolids from Three Spanish WWTPs: Transfer of Organics and Metallic Pollution from Urban Wastewater to Biosolids

The production of biosolids in three Spanish wastewater treatment plants (WWTPs) has been investigated. Biosolids produced from the treatment of urban wastewater in Spain are usually intended for agricultural use. The reliable production of biosolids mainly depends on both the quantity of suspended solids and the organic load influent to the treatment systems. The quality of the generated biosolids was independent of both the amount of treated water and the treatment process applied, with 20 to 25% dried matter, and 60 to 75%, 7% and 4% of organic matter, N and P, respectively, of the total matter. The biosolids contained ca. 11 to 19 g/kg of total metals in the dry matter, with Fe, Zn, Cu and Mn representing 97% of all of the metals present, and Hg being the minority metal. Such biosolids had the ability to concentrate the organic matter and metals from the wastewater up to 417 and 869 times, respectively, and thus, can be used in agricultural practice.     

Substrate influence and temporal changes on periphytic biomass accrual and metabolism in a tropical humic lagoon

We performed a field experiment in a tropical humic coastal lagoon to evaluate periphyton biomass accrual and metabolism on three different substrates (1) plastic ribbons, (2) green and (3) senescent leaves of the emergent macrophyte Typha domingensis) over 30 days. The contribution of autotrophic biomass decreased as total biomass increased over the time. Mean periphytic ash free dry weight ranged from 0.8 to 5.6 mg cm⁻², but periphyton chlorophyll a concentrations presented shorter amplitudes, which oscillated from 0.12 to 0.44 μg cm⁻² throughout the experiment. Periphyton metabolism was overall heterotrophic on all substrates, especially on senescent leaves. Our data show that substrate type influenced both biomass accrual and periphyton net productivity and respiration rates throughout periphyton development and highlighted the dominance of heterotrophic metabolism. The periphyton respiration may be subsidized by both water- and substrate-derived allochthonous energy pathways, shedding light on the role of periphytic assemblages to the carbon cycling, as a source of CO₂ to the system.     

Evaluation of total load sediment transport formulas using ANN

The calculated results from various sediment transport formulas often differ from each other and from measured data. Some parameters in the sediment transport formulas are more effective than others to estimate total sediment load. In this study, an Artificial Neural Network （ANN） model is trained using four dominant parameters of sediment transport formulas. ANN models are able to reveal hidden laws of natural phenomena such as sediment transport process. The results of ANN and some total bed material load sediment transport formulas have been compared to indicate the importance of variables which can be used in developing sediment transport formulas. To train ANN, average flow velocity, water surface slopes, average flow depth, and median particle diameter are used as dominant parameters to estimate total bed material load. Two hundreds and fifty samples are used to train the ANN model. Twenty-four sets of field data not used in the training nor calibration of ANN are used to compare or verify the accuracy of ANN and some well-known total bed material load formulas. The test results show that the ANN model developed in this study using minimum number of dominant factors is a reliable and uncomplicated method to predict total sediment transport rate or total bed material load transport rate. Results show that the accuracy of formulas in descending order are those by Yang （1973）, Laursen （1958）, Engelund and Hansen （1972）, Ackers and White （1973）, and Toffaleti （1969）. These results are similar to those made by ASCE （1982） based on laboratory and field data not used in this paper. Study results also show that the formulas based on physical laws of sediment transport, like those formulas that were developed based on power concept, are more accurate than other formulas for estimating total bed material sediment load in rivers.     

Field observations of an evolving rip current on a meso-macrotidal well-developed inner bar and rip morphology

The Aquitanian Coast (France) is a high-energy meso-macrotidal environment exhibiting a highly variable double sandbar system. The inner and the outer bar generally exhibit a bar and rip morphology and persistent crescentic patterns, respectively. In June 2007, an intense five-day field experiment was carried out at Biscarrosse Beach. A large array of sensors was deployed on a well-developed southward-oriented bar and rip morphology. Daily topographic surveys were carried out together with video imaging to investigate beach morphodynamic evolution. During the experiment, offshore significant wave height ranged from 0.5 to 3 m, with a persistent shore-normal angle. This paper identifies two types of behavior of an observed rip current: (1) for low-energy waves, the rip current is active only between low and mid tide with maximum mean rip current velocity reaching 0.8 m/s for an offshore significant wave height (H_s) lower than 1 m; (2) for high-energy waves (H_s≈ 2.5–3 m), the rip current was active over the whole tide cycle with the presence of persistent intense offshore-directed flows between mid and high tide. For both low and high-energy waves, very low-frequency pulsations (15–30 min) of the mean currents are observed on both feeder and rip channels.A persistent slow shoreward migration of the sandbar was observed during the experiment while no significant alongshore migration of the system was measured. Onshore migration during the high-energy waves can be explained by different sediment transport processes such as flow velocity skewness, wave asymmetry or bed ventilation. High-frequency local measurements of the bed evolution show the presence of significant (in the order of 10 cm) fluctuations (in the order of 1 h). These fluctuations, observed for both low- and high-energy waves, are thought to be ripples and megaripples, respectively and may play an important but still poorly understood role in the larger scale morphodynamics. The present dataset improves the knowledge of rip dynamics as well as the morphological response of strongly alongshore non-uniform meso-macrotidal beaches.     

A Linking Test to reduce the number of hydraulic parameters necessary to simulate groundwater recharge in unsaturated soils

In environmental studies, numerical simulation models are valuable tools for testing hypothesis about systems functioning and to perform sensitivity studies under scenarios of land use or climate changes. The simulations depend upon parameters which are not always measurable quantities and must be calibrated against observations, using for instance inverse modelling. Due to the scarcity of these observations, it has been found that parameter sets allowing a good matching between simulated and measured quantities are often non-unique, leading to the problem of equifinality. This can lead to non-physical values, erroneous fluxes and misleading sensitivity analysis. Therefore, a simple but robust inverse method coined the Linking Test is presented to determine if the parameters are linked. Linked parameters are then sub-divided into classes according to their impact on water fluxes. The Linking Test establishes the causes of non-uniqueness of parameter sets and the feasibility of the inverse modelling.     

The role of chilean mountain areas in time of drought and energy crisis: New pressures and challenges for vulnerable ecosystems

In the summer of 2010/2011 Chile suffered the third most severe energy and water supply crisis in only one decade.This may be surprising as the Andes which accompany the country along 4,200 km are a water tower and could provide more electricity and water than needed.On top of that,it has to be mentioned that Chile also counts with sunny and windy climates and with excellent geothermal energy resources and thus has a huge potential as far as renewable energies are concerned.After analyzing the existing natural conditions,the infrastructure and the present challenges of climate change,it has to be asked in which way Chile can make use of this potential in the near future,considering the legal and political situation and the technological opportunities.It seems that the resources are still hidden in the Andes,and only the key is missing to realize the country’s natural potential.This research has been based on the analysis of existing literature,media,quantitative data from government institutions and other antecedents obtained by the authors in field work done in the South of Chile in 2010.The added value of this compilation lies in the comprehensive perspective,linking the knowledge of climatologists,hydrologists,mountain researchers and energy experts in order to support a sustainable energy and water supply for the future in Chile.From this present research,it can be concluded that Chile necessarilyhas to adopt new energy-related strategies,particularly those aimed at diminishing the strong dependence on traditional sources of energy and establishing new techniques and technologies for generating electricity and utilizing the vast potential that the country is ready to offer,such as that provided by the Andes along 4,200 kilometers.     

Localized algal blooms induced by river inflows in a canyon type reservoir

The local response of the phytoplankton community to river inflow processes was investigated with modeling and field analyses in a long and narrow, stratified reservoir in mid-summer. The river water had high concentrations of phosphorus and nitrogen (ammonium and nitrate) and temperature had large variations at diurnal scales. As a consequence of the large variation in river temperature, the level of neutral buoyancy (the depth where the river water spreads laterally in the reservoir) oscillated between the surface (overflows) during the day, and the depth of the metalimnion (interflows) during the night. The reservoir remained strongly stratified, which favoured the presence of cyanobacteria. It is shown that under these conditions, nutrient-rich river water injected during overflows into the surface layers promoted the occurrence of localized algal blooms in the zones where the overflow mixed with the quiescent water of the reservoir. A series of hydrodynamic simulations of the reservoir were conducted both with synthetic and realistic forcing to assess the importance of river temperatures and wind-driven hydrodynamics for algal blooms. The simulations confirmed that the river inflow was the main forcing mechanism generating the localized bloom.