Advances in the Research of Impact of Decadal Solar Cycle on Modern Climate

Role of solar activity on modern climate change, particularly in the decadal scale is an important scientific issue. This paper reviews the recent observation of decadal solar signal in earth’s climate, with focus on the mechanism of solar radiation, ultraviolet radiation and cosmic rays on climate system ,and its validation. The paper points out that the assessment of uncertainty in observations, amplification process of the climate system, as well as possible future impact of solar extreme events are challenges in the present study. Finally, the keys of breakthrough are pointed, to provide a reference for future research.     

Zircon U–Pb Dating and Geochemistry of the Linong Granitoid and Its Relationship to Cu Mineralization in the Yangla Copper Deposit,Yunnan, China

The Yangla copper deposit (Cu reserves: 1.2 Mt) in the Jinshajiang–Lancangjiang–Nujiang region in China is spatially associated with the Linong granitoid. Zircon U–Pb dating shows the granitoid formed at 234.1 ± 1.2 to 235.6 ± 1.2 Ma, and the KT2 ore body of the deposit yields a molybdenite Re–Os model age of 230.9 ± 3.2 Ma. The ages of mineralization and crystallization of the granitoid are identical within the measurement uncertainties, suggesting the Yangla deposit is genitically related to the Indosinian Linong granitoid.     

华北地区晚石炭世岩相古地理特征及聚煤规律研究

通过分析华北地区晚石炭世的沉积环境及煤层分布特点,探讨了该区晚石炭世沉积相的典型类型,综合分析得出华北克拉通板块晚石炭世主要为陆表海环境,期间发生多次海侵海退事件,在郯庐断裂以东地区,主要发育有台地沉积体系、障壁一渴湖沉积体系及潮坪沉积体系;在盆地的北西缘地区发育潮坪泥炭沼泽,形成了海侵事件沉积,海退时期,中北部地区有利于发育潮坪泥炭沼泽和岛后泥炭沼泽,成为煤层的聚煤中心。     

中国东北部陆缘内生金矿床成因类型、成矿时代及地球动力学背景

中国东北部陆缘是我国内生金矿床较为发育的地区之一,以成矿作用复杂、蕴藏丰富的金资源量倍受国内外地质学家关注。通过对该区内生金矿的地质和成矿年代的系统研究,初步将该区内生金矿床划分为中温热液金矿床、接触交代-热液金矿床、斑岩型/类斑岩型金铜矿床和浅成低温热液金矿床4种主要成因类型和3个重要成矿期（170～160 Ma、130～110 Ma和110～90 Ma）。结合同位素地球化学特征,进一步确定中温热液金矿床的成矿物质主要来自下地壳源,成矿作用与中生代燕山早期古太平洋板块俯冲作用引发的中国东部大陆边缘岩石圈减薄及拆沉的动力学过程密切相关;接触交代-热液金矿床的成矿物质来源于年轻地壳,成矿作用与古太平洋板块俯冲引起的岩石圈减薄拆沉的伸展构造背景下的岩浆接触交代作用更为密切;而斑岩型/类斑岩型金铜矿床和浅成低温热液金矿床的成矿物质来源为壳幔混合源,其成矿发生在古太平洋板块向亚洲大陆正北向俯冲转入Izanagi Farallon板块西向俯冲的构造转换期。     

Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.     

Determination of total sulfur in geothermal water by inductively coupled plasma-atomic emission spectrometry

Sulfur speciation and concentration in geothermal water are of great significance for the research and utilization of the water resources. In most situations, it is necessary to determine the total sulfur in geothermal water. In this study, the method was established for the determination of determining total sulfur content — the inductively coupled plasma-atomic emission spectrometry (ICP-AES), with the wavelength of 182.034 nm selected in spectral line of sulfur. It was identified that the optimal working conditions of the ICP-AES instrument were 1 200 W for high frequency generator power 9 mm for vertical observation height, 0.30 MPa atomizer pressure, and 50 r/min analytical pump speed. The matrix interference of the method was eliminated by the matrix matching method. Using this method, sulfur detection limit and minimum quantitative detection limit were 0.028 mg/L and 0.110 mg/L, respectively, whilst the linear range was 0.0–100.0 mg/L. The recovery rate of sample was between 90.67% and 108.7%, and the relative standard deviation (RSD) was between 0.36% and 2.14%. The method was used to analyze the actual samples and the results were basically consistent with the industry standard method. With high analysis efficiency, the method has low detection limit and minimum quantitative detection limit, wide linear range, good precision and accuracy, and provides an important detection method for the determination of total sulfur in geothermal water.     

基于斯通利波及电成像测井数据对火成岩裂缝地层的特征分析

随着石油勘探类型的转变和发展,如何高效且准确地识别地层中的裂缝变得十分重要。本文构建了斯通利波在裂缝地层中传播的理论模型,得到了斯通利波在经过裂缝带时会形成反射斯通利波,以及地层中裂缝的条数越多、斯通利波反射系数越大的理论结果。在此基础上,对辽河盆地火成岩地层的声波测井数据进行了斯通利波波场分离（中值滤波）,得到反射斯通利波,并计算了裂缝地层的反射系数。同时对该地层的电成像测井数据进行了孔隙度分布谱和区间孔隙度分析。研究表明：在裂缝发育的地层,反射斯通利波能量增强,反射系数变大;裂缝发育地层电成像孔隙度分布谱明显变宽,电成像区间孔隙度中大孔隙占比增大,显示次生孔隙（裂缝）发育。     

起伏地表地震波场角度域照明分析

角度域照明可以更加细致地对地下复杂地质体进行照明分析。提出了一种适用于起伏地表条件下的角度域照明分析方法,其主要过程是利用局部倾斜叠加技术分解波场,对起伏地表处采用加权函数判定局部时窗内的振幅包络位置,以区分其位于地表之上或之下;并引入相似系数函数计算反假频局部平面波场,根据局部斜率与平面波场入射角关系,得到局部角度域地震波场;根据帕斯瓦尔等式下的时间-角度域照明关系式,计算得出角度域照明强度。通过起伏地表高速侵入矿体模型试算,得到给定观测系统下角度域照明强度与地下分析点照明随炮点、波场入射角的变化关系。此方法可用于起伏地表条件的观测系统优化、叠前AVA分析等方面。     

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc-back-arc system in the northern Great Xing'an Range,NE China

The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.     

Impact of transferred water on the hydrochemistry and water quality of surface water and groundwater in Baiyangdian Lake,North China

The hydrochemical composition of surface water and groundwater is a key parameter for understanding the evolution of water and its quality.In particular, little is known about the impact of transferred water on surface water and groundwater.In this study, Baiyangdian Lake was selected as a typical area for extensive groundwater exploration and surface water transfer in the North China Plain.Surface water and groundwater samples were sampled in dry/wet seasons and then analyzed before/after the water transfer, respectively.Generally, surface water and groundwater are extensively hydrologically connected based on hydrochemical evidence.It was found that the hydrochemical composition of the shallow groundwater is affected by the surface water and that the water quality of the deep groundwater is stable.However, inter-aquifer recharge processes from the shallow groundwater to the deep groundwater existed in the anthropogenic region impacted with high nitrate-ion concentrations.Also, the hydrochemical composition of the surface water and groundwater was dominated by rock-weathering and evaporation-precipitation processes.Due to the existence of the deep vadose zone in the alluvial fan, Na~+was exchanged into soil matrices during the leakage of the surface water.In addition, the transferred water resulted in surface water with good quality, and it also played as an important recharge source to groundwater.As the most important water resource for irrigation and drinking, deep groundwater should be paid more attention in the alluvial fan with frequent water transfer and extensive groundwater exploration.