Geochemistry of the Mian-Lue ophiolites in the Qinling Mountains, central China: Constraints on the evolution of the Qinling orogenic belt and collision of the North and South China Cratons

The Anzishan ophiolite, a typical ophiolitic block of early Carboniferous age in the Mian-Lue suture zone of the Qinling Mountains, central China, consists of amphibolites/metabasalts, gabbros and gabbroic cumulates. All of these rocks, as well as those in the Hunshuiguan-Zhuangke (HZ) block, have compositions similar to normal MORB and back-arc basin basalts (BABB) with high ε_Nd(t) values, indicating that they were derived from a depleted mantle source. The Mian-Lue suture zone also contains blocks of other lithologies, e.g., rift volcanic rocks in the Heigouxia block and arc volcanic rocks in the Sanchazi block. Although they are in fault contact with each other, the presence of these different blocks in the Mian-Lue suture zone may represent a complete Wilson cycle, from initial rifting to open ocean basin to final subduction and continent-continent collision, during the late Paleozoic-early Triassic. In this region, the North and South China Cratons were separated by Paleo-Tethys at least until the early Carboniferous, and final amalgamation of both cratons along the Qinling orogenic belt took place in the Triassic.     

生物炭对磷石膏中磷的固化作用

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。     

鄂尔多斯盆地的三维可视化及其应用

地形三维可视化作为测绘行业的一项新技术正处于蓬勃发展阶段。本文以鄂尔多斯盆地为例，着重介绍了基于ARCGIS9．0的三维可视化建库、实现过程，并指出其在矿产勘探中的具体应用。     

由一次西周日食记载得到的地球自转变化

本文结合１９９７年３月９日全食的新疆观测及地球自转变化趋势讨论了发生在中国西周时期的一次日食的记载，以及由此得到的地球自转速度变化值。     

基于GPS掩星技术反演大气参数模型的优化

准确掌握地球大气中的水气分布，了解水气变化趋势对天气现象、全球气候变化、数值预报具有理论研究及实用价值。以无线电掩星技术为基础，利用掩星数据反演大气参数剖面。对原反演模型的不足进行了论证，并给出了反演个例。详细地论述了通过引入MM5先验温度T再通过线性迭代的方法反演对流层下部水汽廓线原理，给出了优化后模型反演个例。并对模型优化后反演廓线中存在的问题进行了分析，提出了下一步优化方向。     

Adsorption of anionic dye on magnesium hydroxide-coated pyrolytic bio-char and reuse by microwave irradiation

Magnesium hydroxide-coated pyrolytic bio-char composite was prepared by chemical precipitation, and the adsorption behavior of anionic dye (directly frozen yellow) onto magnesium hydroxide-coated pyrolytic bio-char was investigated in the batch mode. The Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy and X-ray fluorescence spectroscopy of adsorbents were characterized. Adsorption studies were performed at different pH, salt concentration, contacting time and dye concentration. The pH value of the solution influenced the adsorption capacity significantly, and adsorption is favored of pH 6–8. Salt coexisted in solution increased slightly directly frozen yellow adsorption capacity. The isotherm data were analyzed by Langmuir and Freundlich isotherm model, and Langmuir model was better to predict the equilibrium data. Thermodynamic calculations showed that the adsorption was a spontaneous and endothermic process. Exhausted magnesium hydroxide-coated pyrolytic bio-char was treated by microwave irradiation, and yield of regeneration was 98 % in the case of microwave irradiated time 5 min at 320 W. The magnesium hydroxide-coated pyrolytic bio-char can be reused.     

华北及其邻区块体转动模式和动力来源

块体的转动是地壳中重要的构造运动形式。根据地质、地球物理和地震活动性等资料，可将华北及其邻区划分为３个亚板块，华北亚板块可进一步细分为多个级块体，这些不同级别的块体或多或少都显示出一定的刚体特性。根据地质构造、地震和古地磁测量等资料，详细地论细地论述了不同级块体的转动问题，即华北及其邻区的黑龙江、华北和华南等３个近东西向亚板块自老第三纪以来相对于新疆地区顺时针转动了１．６°～３．５°；华北亚板块内     

鄂西北构家河金矿床成矿流体特征

构家河金矿床位于南秦岭武当山西缘,产于绢云绿泥石英片岩和变石英砂岩之中,受韧性滑脱剪切构造带控制。矿化类型主要有破碎带蚀变岩型和石英脉型,其中前者形成了破碎带蚀变岩型主矿体,呈似层状或透镜状分布于近南北向断裂中,次矿体分布在北西和北东向次级断裂中,为石英脉型矿体。成矿作用包括3个阶段:石英-硫化物阶段、石英-硫化物-金银矿化阶段和石英-碳酸盐阶段。对主矿体石英-硫化物-金银矿化阶段和石英-碳酸盐阶段的流体包裹体进行了显微观察和测温,同时对不同阶段的石英和方解石、白云石等进行了D、O、C同位素测试。结果显示,包裹体以原生气液两相包裹体为主,且主要为富液相包裹体;石英-硫化物-金银矿化阶段包裹体均一温度集中于180~270℃,峰值为220℃,盐度和密度分别为1.40%~14.46%和0.60~0.97g/cm~3;石英-碳酸盐阶段均一温度峰值为170℃,盐度和密度分别为1.34%~7.31%和0.86~0.96g/cm~3;石英-硫化物-金银矿化阶段和石英-碳酸盐阶段石英的δD_(v-SMOW)值分别为-93.3%~70.9‰和-91.6%‰~-67.2‰,δ~(18)O_(v-SMOW)值为12.9‰~14.5‰和11.9‰~13.8‰;方解石和白云石的δ~(13)C_(V.PDB)值为-12.4‰~-12.0‰,δ~(18)O_(v-PDB)值为-18.4‰~-18.1‰。成矿流体特征显示该矿床初始成矿流体为中温、低盐度的变质热液,再结合区域成矿地质与成矿构造背景,认为构家河金矿为造山型金矿床。     

华南区域季节性降水的差异分析

运用EOF方法研究华南区域降水时空分布特征,结果表明：（1）华南地区各季节降水在年际和年代际的时间变化上有区域一致性,但有季节性差异,其中春季和秋季在20世纪80年代后降水明显减少,旱年增多;而夏季90年代后降水明显增加,涝年增多;冬季变化则不明显。（2）华南地区各季节降水在空间分布上也有差异,其中春季降水呈现东多西少的分布特征,大值中心位于广西东北部、广东中部及西南沿海。夏季和秋季降水相似,呈南多北少的分布特征,大值中心位于广西沿海和广东西南沿海。冬季降水呈东北多西南少的分布特征,大值中心位于粤北。