A Raman spectroscopic study on the structural disorder of monazite–(Ce)

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.     

Deciphering the Variscan tectonothermal overprint and deformation partitioning in the Cadomian basement of the Teplá–Barrandian unit, Bohemian Massif

The Teplá–Barrandian unit (TBU) has long been considered as a simply bivergent supracrustal ‘median massif’ above the Saxothuringian subduction zone in the Variscan orogenic belt. This contribution reveals a much more complex style of the Variscan tectonometamorphic overprint and resulting architecture of the Neoproterozoic basement of the TBU. For the first time, we describe the crustal-scale NE–SW-trending dextral transpressional Krakovec shear zone (KSZ) that intersects the TBU and thrusts its higher grade northwestern portion severely reworked by Variscan deformation over a southeastern very low grade portion with well-preserved Cadomian structures and only brittle Variscan deformation. The age of movements along the KSZ is inferred as Late Devonian (~380–370?Ma). On the basis of structural, microstructural, and anisotropy of magnetic susceptibility data from the KSZ, we propose a new synthetic model for the deformation partitioning in the Teplá–Barrandian upper crust in response to the Late Devonian to early Carboniferous subduction and underthrusting of the Saxothuringan lithosphere. We conclude that the Saxothuringian/Teplá–Barrandian convergence was nearly frontal during ~380–346?Ma and was partitioned into pure shear dominated domains that accommodated orogen-perpendicular shortening alternating with orogen-parallel high-strain domains that accommodated dextral transpression or bilateral extrusion. The synconvergent shortening of the TBU was terminated by a rapid gravity-driven collapse of the thickened lithosphere at ~346–337?Ma followed by, or partly simultaneous with, dextral strike-slip along the Baltica margin-parallel zones, driven by the westward movement of Gondwana from approximately 345?Ma onwards.     

Surface changes on crystalline stones due to salt crystallisation

This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness.     

Evolution of geochemistry and depositional settings of Early Palaeozoic siliciclastics of the Barrandian (Teplá-Barrandian Unit,Bohemian Massif,Czech Republic)

Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004.     

On the visible shape of the cold plasma jets in the solar chromosphere

Lines of equal optical thickness are calculated for cold plasma jets propagating in the simplest magnetic configuration. The paraxial approximation is used in the case of jets directed along the axis of a magnetic dipole. The results explain the apparently convergent as well as divergent shapes of the jets in a divergent magnetic configuration.     

Kleť minor planet discovery frequency by months (comparison)

Abstrakt The Kle search programme for minor planets using 0,63m Maksutov camera of Kle Observatory was begun in 1977 as a long-term project continuing up to the present day. The discovery frequency according to seasons in the year shows multiple differences between particular months.The comparison with the number of observing nights and obtained search plates; weather conditions and other influences will be discussed. The Kle minor planet discovery frequency also will be compared with the data base of all numbered minor planets.     

Low velocity shock-cloud encounters I.

Shocks propagating in the interstellar medium (ISM) play an important role in the life of molecular clouds. Through a theoretical study of interaction between clouds and shocks we can understand, for example, the density distribution of observed molecular clouds and the first steps of star formation. The only way to study of interaction in detail is via a numerical hydrodynamical simulation. In this paper we present the first results of a hydrocode which is able to follow the processes after the collision between the cloud and shock front.Our main theoretical result is that the chemical processes (e.g. H₂ dissociation) can affect the dynamical processes significantly. Global parameters of the cloud are calculated for the comparision of the simulation and the observations.     

On the stability of the zodiacal cloud

The problem of the stability of the zodiacal cloud is scrutinized. The central idea of the paper sticks in the theoretical treatment of the action of the solar electromagnetic radiation on small interplanetary dust particles (IDPs). It is suggested that the virtual problem of the (in-)stability of the zodiacal cloud originated from the physically incorrect application of the Poynting-Robertson effect on IDPs. Real particles are not of spherical shape and so the braking acceleration is not proportional to -v/c. Depending on the shape (and other optical properties) of the particle, also spiralling outward from the Sun may occur.     

Solar-Cycle Variation of Subsurface Zonal Flow

We study the solar-cycle variation of the zonal flow in the near-surface layers of the solar convection zone from the surface to a depth of 16 Mm covering the period from mid-2001 to mid-2013 or from the maximum of Cycle 23 through the rising phase of Cycle 24. We have analyzed Global Oscillation Network Group (GONG) and Helioseismic and Magnetic Imager (HMI) Dopplergrams with a ring-diagram analysis. The zonal flow varies with the solar cycle showing bands of faster-than-average flows equatorward of the mean latitude of activity and slower-than-average flows on the poleward side. The fast band of the zonal flow and the magnetic activity appear first in the northern hemisphere during the beginning of Cycle 24. The bands of fast zonal flow appear at mid-latitudes about three years in the southern and four years in the northern hemisphere before magnetic activity of Cycle 24 is present. This implies that the flow pattern is a direct precursor of magnetic activity. The solar-cycle variation of the zonal flow also has a poleward branch, which is visible as bands of faster-than-average zonal flow near 50° latitude. This band appears first in the southern hemisphere during the rising phase of the Cycle 24 and migrates slowly poleward. These results are in good agreement with corresponding results from global helioseismology.