Magmatic history and geophysical signature of a post-collisional intrusive center emplaced near a crustal-scale shear zone: the Plechý granite pluton (Moldanubian batholith,Bohemian Massif)

The Plechy pluton, southwestern Bohemian Massif, represents a late-Variscan, complexly zoned intrusive center emplaced near the crustal-scale Pfahl shear zone; the pluton thus provides an opportunity to examine the interplay among successive emplacement of large magma batches, magmatic fabric acquisition, and the late-Variscan stress field associated with strike-slip shearing. The magmatic history of the pluton started with the emplacement of the porphyritic Plechy and Haidmühler granites. Based on gravity and structural data, we interpret that the Plechy and Haidmühler granites were emplaced as a deeply rooted, ∼NE–SW elongated body; its gross shape and internal fabric (steep ∼NE–SW magmatic foliation) may have been controlled by the late-Variscan stress field. The steep magmatic foliation changes into flat-lying foliation (particularly recorded by AMS) presumably as a result of divergent flow. Magnetic lineations correspond to a sub-horizontal ∼NE–SW finite stretch associated with the divergent flow. Subsequently, the Třístoličník granite, characterized by steep margin-parallel magmatic foliation, was emplaced as a crescent-shaped body in the central part of the pluton. The otherwise inward-younging intrusive sequence was completed by the emplacement of the outermost and the most evolved garnet-bearing granite (the Marginal granite) along the southeastern margin of the pluton. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The largest karst cave discovered in a tunnel during motorway construction in Slovenia’s Classical Karst (Kras)

Karst researchers of the Karst Research Institute ZRC SAZU are regularly consulted during the planning of Slovenia’s motorways and invited to observe and monitor construction in the karst areas. More than 350 caves have been discovered in the course of building 60 km of new motorways over the past decade. Access to the most important caves is preserved by concrete tubes closed with metal covers at the roadside. The largest cave system in a tunnel, named LC-S647, is almost entirely preserved. The protection of this cave will serve as a good example for the preservation of natural heritage in the future. Construction work for the motorway uncovered a high degree of karstification. In particular, the discovery of this cave in the Kastelec tunnel LC-S647 showed the existence of a major cave system in the geological and speleological past. A number of unconnected passages have also been found. Caves discovered during highway construction have brought new knowledge about the cavernosity and the geological history of this part of the karst.     

Giant ancient landslide in the Alma water gap (Crimean Mountains,Ukraine): notes to the predisposition,structure, and chronology

Large-scale ancient landslides of the area of more than 5 km² and volume exceeding 200 × 10⁶ m³ are characteristic features of the valleys incised in the northern periphery of the Crimean Mountains (Ukraine). The largely affected area is located in the outermost cuesta range of the Crimean Mountains which consists of rigid Sarmatian limestones overlying weak Middle Miocene and Upper Palaeogene deposits. A giant landslide arose in the Alma water gap as a reflection of several coincident preparatory factors such as suitable bedrock stratification, smectite-rich bedrock exposed to swelling activity, presence of faults parallel to the valley trend, and river capture event which preceded the landslide event. The occurrence of such ancient megaslides is particularly interesting in the area which is characterized by low precipitation (<500 mm/year) and weak contemporary seismicity. It probably reflects a more dynamic environment in humid phases of the Holocene; however, seismic triggering along the Mesozoic suture zone cannot be rejected. Compressional features such as gravitational folds in the central and distal parts of the landslide, which probably correlate with the whole landslide genesis or its significant reactivation, arose, according to the radiocarbon dating, during the Holocene climatic optimum in the Atlantic period. The slope deformation has been relatively quiescent since that time, except minor historic reactivization which took place in the frontal part of the landslide. We suppose that the studied landslide could be classified as a transitional type of slope deformation with some signs of spreading and translational block slides.     

Cause of scale inconsistencies in DORIS time series

In this paper we analyze the scale of the DORIS (Doppler Orbitography and Radiopositioning Integrated by Satellite) solutions with respect to DORIS extension of the International Terrestrial Reference Frame (ITRF) for Precise Orbit Determination DPOD2014. The main goal is to explain the scale inconsistencies and to find the optimal solution reaching low-biased and consistent scale time series. Our analysis profits from 4 different strategies based only on the Geodetic Observatory Pecný analysis center solution, using DORIS exchange format data 2.2. A difference in the sequence of the solutions directly corresponds to one of the changes in the solution settings: data elevation dependent weighting, application of data validity indicators and application of phase center - reference point correction. We process multi-satellite and single-satellite solutions for the time period 2011.0–2017.0. Our analysis examines scale inconsistency issues in 2011/2012 and in 2015. The scale increment in 2011/2012 is explained as a result of the concurrence of changes in satellite constellation and change in the provider data validity standards for Cryosat-2 and Jason-2 satellites. The scale increment in 2015 is explained as the effect of change in the standards for phase center - reference center corrections for Saral, Jason-2 and Cryosat-2 satellites. Moreover, comparing the solutions with and without elevation dependent data downweighting using the same elevation cutoff (10°), we found a significant reduction of scale bias and scale variation applying the data downweighting. The data downweighting improved also the station positioning repeatability. We demonstrate that the solution, which is completely free from the additional data associated with observations in DORIS exchange format 2.2 and includes the data downweighting law, eventuates in a consistent scale time series with the lowest offset with respect to DPOD2014 (version 1.0) (12.7 ± 2.3 mm for 2011.0–2017.0). The only remaining scale issue is the part of 2011/2012 increment of around 5 mm, explained by a change in the DORIS satellite constellation.     

Magnetic particles in atmospheric particulate matter collected at sites with different level of air pollution

Magnetic measurements of deposited atmospehric dust can serve as an additional parameter in assessing environmental pollution. This method is based on the assumption that atmospherically deposited particles contain significant portion of ferrimagnetic iron oxides of anthropogenic origin, which can be easily detected. Aim of this paper is to identify clearly magnetic fraction of daily samples of particulate matter less than 10 μm (PM10), routinely used for air quality assessment and monitoring. We used combination of thermomagnetic analyses and other physical and chemical methods, including scanning electron microscopy (SEM) and Mössbauer spectroscopy. Our results show that daily samples of PM10, collected at sites with different degree of atmospheric pollution, contain magnetite of spherical shape, which is presumably of industrial origin. Thus, magnetic methods can be applied directly to the same substances, which are used routinely in air quality assessment and monitoring.     

Nb-Ta-Ti oxides fractionation in rare-metal granites: Kr��sno-Horn�� Slavkov ore district, Czech Republic

Nb-Ta-Ti-bearing oxide minerals (Nb-Ta-bearing rutile, columbite-group minerals) represent the most common Nb-Ta host in topaz-albite granites and related rocks from the Krásno-Horní Slavkov ore district. Tungsten-bearing columbite-(Fe), W-bearing ixiolite, wodginite and tapiolite-(Fe) are extremely rare in these rocks. Rutile contains significant levels of Ta (up to 37?wt.% Ta₂O₅) and Nb (up to 24?wt.% Nb₂O₅), with Ta/(Ta?+?Nb) ratio ranging from 0.04 to 0.61. Columbite-group minerals are represented mostly by columbite-(Fe) and rarely by columbite-(Mn), with Mn/(Mn?+?Fe) ratio ranging from 0.23 to 0.94. The exceptionally rare Fe-rich, W-bearing ixiolite occurs only as inclusions in Nb-Ta-bearing rutile from quartz-free alkali-feldspar syenites (Vysoky Kámen stock). Wodginite was found only in the topaz-albite microgranite of gneissic breccia matrix that occurs in the upper most part of the Hub topaz-albite granite stock. In wodginite, the Mn/(Mn?+?Fe) ratio is 0.42?C0.51, whereas the coexisting tapiolite-(Fe) has a distinctly lower Mn/(Mn?+?Fe) ratio close to 0.06.     

Geophysical evidence of the Eastern Marginal Fault of the Cheb Basin (Czech Republic)

The western part of the Bohemian Massif hosts an intersection of two regional fault zones, the SW-NE trending Oh?e/Eger Graben and the NNW-SSE trending Mariánské Lázně Fault, which has been reactivated several times in the geological history and controlled the formation of the Tertiary Cheb Basin. The broader area of the Cheb Basin is also related to permanent seismic activity of M_L 3+ earthquake swarms. The Eastern Marginal Fault of the Cheb Basin (northern segment of the Mariánské Lázně Fault) separates the basin sediments and underlying granites in the SW from the Kru?né Hory/Erzgebirge Mts. crystalline unit in the NE. We describe a detailed geophysical survey targeted to locating the Eastern Marginal Fault and determining its geometry in the depth. The survey was conducted at the Kopanina site near the Nový Kostel focal zone, which shows the strongest seismic activity of the whole Western Bohemia earthquake swarm region. Complex geophysical survey included gravimetry, electrical resistivity tomography, audiomagnetotellurics and seismic refraction. We found that the rocks within the Eastern Marginal Fault show low resistivity, low seismic velocity and density, which indicates their deep fracturing, weathering and higher water content. The dip of the fault in shallow depths is about 60° towards SW. At greater depths, the slope turns to subvertical with dip angle of about 80°. Results of geoelectrical methods show blocky fabric of the Cheb Basin and deep weathering of the granite bedrock, which is consistent with geologic models based on borehole surveys.     

Effect of NAPL Source Morphology on Mass Transfer in the Vadose Zone

The generation of vapor‐phase contaminant plumes within the vadose zone is of interest for contaminated site management. Therefore, it is important to understand vapor sources such as non‐aqueous‐phase liquids (NAPLs) and processes that govern their volatilization. The distribution of NAPL, gas, and water phases within a source zone is expected to influence the rate of volatilization. However, the effect of this distribution morphology on volatilization has not been thoroughly quantified. Because field quantification of NAPL volatilization is often infeasible, a controlled laboratory experiment was conducted in a two‐dimensional tank (28 cm × 15.5 cm × 2.5 cm) with water‐wet sandy media and an emplaced trichloroethylene (TCE) source. The source was emplaced in two configurations to represent morphologies encountered in field settings: (1) NAPL pools directly exposed to the air phase and (2) NAPLs trapped in water‐saturated zones that were occluded from the air phase. Airflow was passed through the tank and effluent concentrations of TCE were quantified. Models were used to analyze results, which indicated that mass transfer from directly exposed NAPL was fast and controlled by advective‐dispersive‐diffusive transport in the gas phase. However, sources occluded by pore water showed strong rate limitations and slower effective mass transfer. This difference is explained by diffusional resistance within the aqueous phase. Results demonstrate that vapor generation rates from a NAPL source will be influenced by the soil water content distribution within the source. The implications of the NAPL morphology on volatilization in the context of a dynamic water table or climate are discussed.     

Post-drilling destabilization of temperature profile in borehole Yaxcopoil-1, Mexico

As part of the International Continental Scientific Drilling Program (ICDP), the 1.5-km-deep borehole Yaxcopoil-1, located in the Chixculub meteor impact structure in Mexico, has undergone further study after drilling operations ceased. Temperature logs were repeated ten times at intervals 0.3–0.8, 15, 24 and 34 months after borehole shut-in. The logs bear a distinct signature of transient heat transfer by groundwater flow manifested by a gradual distortion of the linear temperature profile when a cold wave of 0.8–1.6°C amplitude was detected propagating downward from 145 to 312 m at a rate of 4–6 m/month. To understand the nature of this moving anomaly, a 20-day monitoring of the cold wave was carried out at a depth of 307 m that showed further cooling of 0.6°C during the first 16 days of the passage followed by temperature stabilisation. As an explanation of this unusual phenomenon, a theory is proposed, whereby the drilling mud has accumulated within the overlying and cooler highly porous and permeable karstic rocks during the drilling and migrates downward. The observed migration rate suggests a permeability higher than 10^?11 m². This indicates a high vulnerability to contamination of the only freshwater aquifer in the Yucatan region.     

Spectroscopic and bond-topological investigation of interstitial volatiles in beryl from Slovakia

Nine beryl samples from Western Carpathians, Slovakia, were investigated by infrared and Raman spectroscopy and differential thermal analysis. Two types of water H₂O I and H₂O II were detected. Infrared spectroscopy proved the presence of water type I and II in the presence of alkali cations with several bands: (1) symmetric stretching vibration—ν₁; (2) antisymmetric stretching mode—ν₃; (3) bending vibration—ν₂. The presence of singly and doubly coordinated type II water (IIs and IId) was confirmed by single-crystal IR spectroscopy. From Raman spectra a band at 3606 cm^?1 was assigned to ν₁ of water type I and the range of 3597–3600 cm^?1 to water type II. The presence of doubly coordinating water indicates a relatively highly hydrated environment with the presence of alkali ions including Na as the dominant cation coordinated by H₂O II. CO₂ bands were detected only by single-crystal IR spectroscopy. Thermal analysis proved total water loss in the range of 1.4–2.0 wt% and three main dehydration events. Based on the study of bond-topological arrangements two molecules of H₂O IId are each bound with two H···O1 bonds and one Na–O_W bond with an angular distortion, and by releasing one H₂O molecule more stable H₂O IIs is produced. The H₂O I molecule is bound only by two equivalent hydrogen bonds. The H₂O IIs molecule with a Na–O_W bond strength of 0.28 vu and two H···O1 bonds of 0.14 vu without any forced angular distortion is the most stable of all.