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Abstract— Understanding the fundamental crystal chemical controls on visible and near‐infrared reflectance spectra of pyroxenes is critical to quantitatively assessing the mineral chemistry of pyroxenes viewed by remote sensing. This study focuses on the analysis of spectroscopic measurements of a comprehensive set of synthetic Mg‐Fe pyroxenes from the visible through the near‐infrared (0.3–2.6 μm) to address the constraints of crystal structure and Fe2+ content on spin‐forbidden and spin‐allowed crystal field absorptions in Ca‐free orthopyroxenes. The chemistry and oxidation state of the synthetic pyroxenes are characterized. Coordinated Mössbauer spectroscopy is used to determine site occupancy of Fe2+ in the M1 and M2 crystallographic sites. Properties of visible and near‐infrared absorption bands of the synthetic pyroxenes are quantified using the modified Gaussian model. The 1 and 2 μm spin‐allowed crystal field absorption bands move regularly with increasing iron content, defining a much tighter trend than observed previously. A spin‐allowed crystal field absorption band at 1.2 μm is explicitly verified, even at low total iron contents, indicating that some portion of Fe2+ resides in the M1 site. The 1.2 μm band intensifies and shifts to longer wavelengths with increasing iron content. At visible wavelengths, spin‐forbidden crystal field absorptions are observed in all iron‐bearing samples. The most prominent absorption near 506 nm, attributed to iron in the M2 site, shifts to slightly longer wavelengths with iron content. The purity and extent of this pyroxene series allows visible wavelength absorption bands to be directly assigned to specific transitions of Fe2+ in the M1 and M2 sites. 相似文献
264.
Catherine Heymans Michael L. Brown Marco Barden John A. R. Caldwell Knud Jahnke Chien Y. Peng Hans-Walter Rix y Taylor Steven V. W. Beckwith Eric F. Bell rea Borch Boris Häußler Shardha Jogee Daniel H. McIntosh Klaus Meisenheimer Sebastian F. Sánchez Rachel Somerville Lutz Wisotzki Christian Wolf 《Monthly notices of the Royal Astronomical Society》2005,361(1):160-176
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Ariyeh H. Maller Avishai Dekel Rachel Somerville 《Monthly notices of the Royal Astronomical Society》2002,329(2):423-430
We model the acquisition of spin by dark-matter haloes in semi-analytic merger trees. We explore two different algorithms: one in which halo spin is acquired from the orbital angular momentum of merging satellites, and another in which halo spin is gained via tidal torquing on shells of material while still in the linear regime. We find that both scenarios produce the characteristic spin distribution of haloes found in N -body simulations, namely, a log-normal distribution with mean ≈ 0.04 and standard deviation ≈ 0.5 in the log. A perfect match requires fine-tuning of two free parameters. Both algorithms also reproduce the general insensitivity of the spin distribution to halo mass, redshift and cosmology seen in N -body simulations. The spin distribution can be made strictly constant by physically motivated scalings of the free parameters. In addition, both schemes predict that haloes that have had recent major mergers have systematically larger spin values. These algorithms can be implemented within semi-analytic models of galaxy formation based on merger trees. They yield detailed predictions of galaxy properties that strongly depend on angular momentum (such as size and surface brightness) as a function of merger history and environment. 相似文献
267.
Siobahn M. Morgan Jennifer N. Wahl Rachel M. Wieckhorst 《Monthly notices of the Royal Astronomical Society》2007,374(4):1421-1426
[Fe/H]–φ31 – P relations are found for c-type RR Lyrae stars in globular clusters. The relations are analogous to that found by Jurcsik & Kovács for field ab-type RR Lyrae stars, where a longer period correlates with lower metallicity values for similar values of the Fourier coefficient φ31 . The relations obtained here are used to determine the metallicity of field c-type RR Lyrae stars, those within ω Cen, the Large Magellanic Cloud and toward the galactic bulge. The results are found to compare favourably to metallicity values obtained elsewhere. 相似文献
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Rachel Sleeter Benjamin M. Sleeter Brianna Williams Dianna Hogan Todd Hawbaker Zhiliang Zhu 《Carbon balance and management》2017,12(1):2
Background
Carbon storage potential has become an important consideration for land management and planning in the United States. The ability to assess ecosystem carbon balance can help land managers understand the benefits and tradeoffs between different management strategies. This paper demonstrates an application of the Land Use and Carbon Scenario Simulator (LUCAS) model developed for local-scale land management at the Great Dismal Swamp National Wildlife Refuge. We estimate the net ecosystem carbon balance by considering past ecosystem disturbances resulting from storm damage, fire, and land management actions including hydrologic inundation, vegetation clearing, and replanting.Results
We modeled the annual ecosystem carbon stock and flow rates for the 30-year historic time period of 1985–2015, using age-structured forest growth curves and known data for disturbance events and management activities. The 30-year total net ecosystem production was estimated to be a net sink of 0.97 Tg C. When a hurricane and six historic fire events were considered in the simulation, the Great Dismal Swamp became a net source of 0.89 Tg C. The cumulative above and below-ground carbon loss estimated from the South One and Lateral West fire events totaled 1.70 Tg C, while management activities removed an additional 0.01 Tg C. The carbon loss in below-ground biomass alone totaled 1.38 Tg C, with the balance (0.31 Tg C) coming from above-ground biomass and detritus.Conclusions
Natural disturbances substantially impact net ecosystem carbon balance in the Great Dismal Swamp. Through alternative management actions such as re-wetting, below-ground biomass loss may have been avoided, resulting in the added carbon storage capacity of 1.38 Tg. Based on two model assumptions used to simulate the peat system, (a burn scar totaling 70 cm in depth, and the soil carbon accumulation rate of 0.36 t C/ha?1/year?1 for Atlantic white cedar), the total soil carbon loss from the South One and Lateral West fires would take approximately 1740 years to re-amass. Due to the impractical time horizon this presents for land managers, this particular loss is considered permanent. Going forward, the baseline carbon stock and flow parameters presented here will be used as reference conditions to model future scenarios of land management and disturbance.269.
Rachel J. Harris Conrad A. Pilditch Barry L. Greenfield Vicki Moon Ingrid Kröncke 《Estuaries and Coasts》2016,39(3):815-828
Fine sediment inputs can alter estuarine ecosystem structure and function. However, natural variations in the processes that regulate sediment transport make it difficult to predict their fate. In this study, sediments were sampled at different times (2011–2012) from 45 points across intertidal sandflat transects in three New Zealand estuaries (Whitford, Whangamata, and Kawhia) encompassing a wide range in mud (≤63 μm) content (0–56 %) and macrofaunal community structure. Using a core-based erosion measurement device (EROMES), we calculated three distinct measures of sediment erosion potential: erosion threshold (? c ; N m?2), erosion rate (ER; g m?2 s?1), and change in erosion rate with increasing bed shear stress (m e ; g N?1 s?1). Collectively, these measures characterized surface (? c and ER) and sub-surface (m e ) erosion. Benthic macrofauna were grouped by functional traits (size and motility) and data pooled across estuaries to determine relationships between abiotic (mud content, mean grain size) and biotic (benthic macrofauna, microbial biomass) variables and erosion measures. Results indicated that small bioturbating macrofauna (predominantly freely motile species <5 mm in size) destabilized surface sediments, explaining 23 % of the variation in ? c (p ≤ 0.01) and 59 % of the variation in ER (p ≤ 0.01). Alternatively, mud content and mean grain size cumulatively explained 61 % of the variation in m e (p ≤ 0.01), where increasing mud and grain size stabilized sub-surface sediments. These results highlight that the importance of biotic and abiotic predictors vary with erosion stage and that functional group classifications are a useful way to determine the impact of benthic macrofauna on sediment erodibility across communities with different species composition. 相似文献
270.
Chisholm Nicole Nagare Baban Wainwright Charlotte Creegan Ed Salehpoor Leyla VandenBoer Trevor C. Bullock Terry Croft Betty Lesins Glen Osthoff Hans Fernando H. J. S. Chang Rachel Y.-W. 《Boundary-Layer Meteorology》2021,181(2-3):345-364
Boundary-Layer Meteorology - Marine aerosols play an important role in the Earth’s climate, but their effects remain highly uncertain due to a poor understanding of their sources, properties,... 相似文献