Silicate absorption in heavily obscured galaxy nuclei

Spectroscopy at 8–13 μm with T-ReCS on Gemini-S is presented for three galaxies with substantial silicate absorption features, NGC 3094, NGC 7172 and NGC 5506. In the galaxies with the deepest absorption bands, the silicate profile towards the nuclei is well represented by the emissivity function derived from the circumstellar emission from the red supergiant, μ Cephei which is also representative of the mid-infrared absorption in the diffuse interstellar medium in the Galaxy. There is spectral structure near 11.2 μm in NGC 3094 which may be due to a component of crystalline silicates. In NGC 5506, the depth of the silicate absorption increases from north to south across the nucleus, suggestive of a dusty structure on scales of tens of parsecs. We discuss the profile of the silicate absorption band towards galaxy nuclei and the relationship between the 9.7-μm silicate and 3.4-μm hydrocarbon absorption bands.     

Institutionalizing the High North: Will the harvest of redfeed be a critical juncture for the solidification of the Svalbard Fisheries Protection Zone?

The Svalbard Fisheries Protection Zone is an international institution on the brink of being challenged in a critical phase of being institutionalized as a Norwegian property regime. The potential disturbance comes from the zooplankton redfeed, a new and valuable resource harvestable within the zone. Though the pressures on Norway’s inspection routines in the zone are challenged at times, this article suggests that the zone as a management regime is a surprisingly robust institution still. Nevertheless, in such a critical phase it is important not to allow possible exogenous shocks to appear, and creating a separate redfeed regime for the plankton will allow the Norwegian government to bypass this possible disturbance and allow for continued solidification of the zone into an EEZ for Norway.     

Objective classification of galaxy spectra using the information bottleneck method

A new method for classification of galaxy spectra is presented, based on a recently introduced information theoretical principle, the information bottleneck . For any desired number of classes, galaxies are classified such that the information content about the spectra is maximally preserved. The result is classes of galaxies with similar spectra, where the similarity is determined via a measure of information. We apply our method to ∼6000 galaxy spectra from the ongoing 2dF redshift survey, and a mock-2dF catalogue produced by a cold dark matter (CDM) based semi-analytic model of galaxy formation. We find a good match between the mean spectra of the classes found in the data and in the models. For the mock catalogue, we find that the classes produced by our algorithm form an intuitively sensible sequence in terms of physical properties such as colour, star formation activity, morphology, and internal velocity dispersion. We also show the correlation of the classes with the projections resulting from a principal component analysis.     

Initial Results from the Southern Edgeworth-Kuiper belt Survey

We present preliminary results of the analysis of the first 500 squaredegrees of the Southern Edgeworth-Kuiper belt Survey, a large sky survey whichran from January 2000 to January 2003 and comprises 2900° in total. Early testspredict that we should discover ～10 bright TNOs in our data, doubling the currentknown population.     

Limitations of Current Approaches for Predicting Groundwater Vulnerability from PFAS Contamination in the Vadose Zone

Published literature for reported sorption coefficients (K_d) of eight anionic per- and polyfluoroalkyl substances (PFAS) in soil was reviewed. K_d values spanned three to five log units indicating that no single value would be appropriate for use in estimating PFAS impacts to groundwater using existing soil-water partition equations. Regression analysis was used to determine if the soil or solution parameters might be used to predict K_d values. None of the 15 experimental parameters collected could individually explain variability in reported K_d values. Significant associations between K_d and soil calcium and sodium content were found for many of the selected PFAS, suggesting that soil cation content may be critical to PFAS sorption, as previously noted in sources like Higgins and Luthy (2006), while organic carbon content was significant only at elevated levels (>5%). Unexplained discrepancies between the results from studies where PFAS were introduced to soil and desorbed in the laboratory and those that used material from PFAS-impacted sites suggest that laboratory experiments may be overlooking some aspects critical to PFAS sorption. Future studies would benefit from the development and use of standardized analytical methods to improve data quality and the establishment of soil parameters appropriate for collection to produce more complete data sets for predictive analysis.     

Old Smokey coal fire, Floyd County, Kentucky: Estimates of gaseous emission rates

Vent emissions of the Old Smokey coal fire, Floyd County, Kentucky, were studied in May and July, 2010. Vent emissions were generally lower in July, perhaps due to a shift in the fire front, change in vent structure, or another unidentified factor. Volatile organics in the vent gasses contain dangerous levels of toxic, carcinogenic, and other hazardous compounds. Benzene ranges to nearly 400 parts per billion (volume) at one vent. Toluene exceeds 104 parts per billion (volume) at the same vent.Flux rates for CO₂ and CO range to 85,000 mg/s/m² and 89 mg/s/m², respectively, for various vents for the two measuring times. Estimates of total CO₂ emissions, possibly less than 1000 t/year, are within the range of other eastern Kentucky coal fires.     

Second-Hand Spaces: Restructuring Retail Geographies in an Era of E-Commerce

Are online markets replacing or remaking second-hand markets in cities? The restructuring of secondary markets in light of virtual outlets like eBay is not well understood. In this article, we describe secondary markets and their important historic, economic, cultural, and social roles in cities. The literature on e-Commerce suggests that virtual retailers compete with bricks-and-mortar stores and potentially displace them. We question whether the internet can substitute for second-hand stores, which have traditionally relied on a loyal and local customer base, personalized shopping experiences, and surprise encounters. Given the historically embedded nature of exchange, we focus on one large Mid-western city, drawing upon survey and interview data from Chicago retailers. Our exploration of supply, demand, and geographic practices reveals subtle and complex alterations in second-hand exchange, rather than a displacement of second-hand markets by eBay. We also find substantive integration, fluidity, and hybridization within and across market sectors. Rather than supplant the production of new goods, secondary markets are intertwined with and deepen primary markets, calling into question some of the presumed benefits of and meanings associated with second-hand exchange as well as the usefulness of categorical distinctions. [Key words: secondary markets, second-hand, resale, thrift, e-commerce, eBay.]     

Arsenic Remediation Field Study Using a Sulfate Reduction and Zero‐Valent Iron PRB

Toxic and carcinogenic effects of arsenic in drinking water continue to impact people throughout the world and arsenic remains common in groundwater at cleanup sites and in areas with natural sources. Advances in groundwater remediation are needed to attain the low concentrations that are protective of human health and the environment. In this article, we present the successful use of a permeable reactive barrier (PRB) utilizing sulfate reduction coupled with zero‐valent iron (ZVI) to remediate the leading edge of a dissolved arsenic plume in a wetland area near Tacoma, Washington. A commercially available product (EHC‐M®, Adventus Americas Inc., Freeport, Illinois) that contains ZVI, organic carbon substrate, and sulfate was injected into a reducing, low‐seepage‐velocity aquifer elevated in dissolved arsenic and iron from a nearby, slag‐containing landfill. Removal effectiveness was strongly correlated with sulfate concentration, and was coincident with temporary redox potential (Eh) reductions, consistent with arsenic removal by iron sulfide precipitation. The PRB demonstrates that induced sulfate reduction and ZVI are capable of attaining a regulatory limit of 5 µg/L total arsenic, capturing of 97% of the arsenic entering the PRB, and sustaining decreased arsenic concentrations for approximately 2 years, suggesting that the technology is appropriate for consideration at other sites with similar hydrogeochemical conditions. The results indicate the importance of delivery and longevity of minimum sulfate concentrations and of maintaining sufficient dissolved organic carbon and/or microscale ZVI to precipitate FeS, a precursor phase to arsenic‐bearing pyrite that may provide a stable, long‐term sink for arsenic.