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41.
42.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
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The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River
mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations
in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from
several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling
velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral
groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River
sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to
be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material
of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon
mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally,
relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine
input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil
Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence,
stronger sedimentation of Amazon sediments would occur only west of the river mouth. 相似文献
46.
Marcelo F. L. Souza Bjrn Kjerfve Bastiaan Knoppers Weber F. Landim de Souza Raimundo N. Damasceno 《Estuarine, Coastal and Shelf Science》2003,57(5-6):843-858
Lagoa de Araruama in the state of Rio de Janeiro, Brazil, is a hypersaline lagoon with salinity varying spatially from 45 to 56. We collected water samples during monthly cruises throughout the lagoon, and along the streams feeding the system, from April 1991 to March 1992. Nutrients and other water quality parameters exhibited great spatial and temporal variations. Mass balance calculations indicate large amounts of anthropogenic nutrient inputs. The data indicate that the lagoon currently is oligotrophic but is in a state of transition to become a mesotrophic system. Molar dissolved inorganic nitrogen:dissolved inorganic phosphorus (DIN/DIP) varied between 2.2:1 and 659:1 with a volume-weighted average of 22:1. The high DIN/DIP ratio contrasts with that found in nearby lagoons, suggesting that phytoplankton primary production is limited by phosphorus in Lagoa de Araruama. The major loss of DIP is apparently driven by biological assimilation and diagenic reactions in the sediments. Calculations indicate that the lagoon is slightly net autotrophic at +0.9 mol C m−2 yr−1. This suggests that the biomass of the primary producers is restricted by phosphorus availability. Phosphorus retention in the sediment and the hypersaline state of the lagoon prevent changes in autotrophic communities and the formation of eutrophic conditions. 相似文献
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The Bayesian detection of discontinuities in a polynomial regression and its application to the cycle-slip problem 总被引:4,自引:1,他引:3
Maria Clara de Lacy Mirko Reguzzoni Fernando Sansò Giovanna Venuti 《Journal of Geodesy》2008,82(9):527-542
This paper deals with the problem of detecting and correcting cycle-slips in Global Navigation Satellite System (GNSS) phase
data by exploiting the Bayesian theory. The method is here applied to undifferenced observations, because repairing cycle-slips
already at this stage could be a useful pre-processing tool, especially for a network of permanent GNSS stations. If a dual
frequency receiver is available, the cycle-slips can be easily detected by combining two phase observations or phase and range
observations from a single satellite to a single receiver. These combinations, expressed in a distance unit form, are completely
free from the geometry and depend only on the ionospheric effect, on the electronic biases and on the initial integer ambiguities;
since these terms are expected to be smooth in time, at least in a short period, a cycle-slip in one or both the two carriers
can be modelled as a discontinuity in a polynomial regression. The proposed method consists in applying the Bayesian theory
to compute the marginal posterior distribution of the discontinuity epoch and to detect it as a maximum a posteriori (MAP)
in a very accurate way. Concerning the cycle-slip correction, a couple of simultaneous integer slips in the two carriers is
chosen by maximazing the conditional posterior distribution of the discontinuity amplitude given the detected epoch. Numerical
experiments on simulated and real data show that the discontinuities with an amplitude 2 or 3 times larger than the noise
standard deviation are successfully identified. This means that the Bayesian approach is able to detect and correct cycle-slips
using undifferenced GNSS observations even if the slip occurs by one cycle. A comparison with the scientific software BERNESE
5.0 confirms the good performance of the proposed method, especially when data sampled at high frequency (e.g. every 1 s or
every 5 s) are available. 相似文献
49.
Modelling Positional Uncertainty of Line Features by Accounting for Stochastic Deviations from Straight Line Segments 总被引:1,自引:0,他引:1
Sytze de Bruin 《Transactions in GIS》2008,12(2):165-177
The assessment of positional uncertainty in line and area features is often based on uncertainty in the coordinates of their elementary vertices which are assumed to be connected by straight lines. Such an approach disregards uncertainty caused by sampling and approximation of a curvilinear feature by a sequence of straight line segments. In this article, a method is proposed that also allows for the latter type of uncertainty by modelling random rectangular deviations from the conventional straight line segments. Using the model on a dense network of sub‐vertices, the contribution of uncertainty due to approximation is emphasised; the sampling effect can be assessed by applying it on a small set of randomly inserted sub‐vertices. A case study demonstrates a feasible way of parameterisation based on assumptions of joint normal distributions for positional errors of the vertices and the rectangular deviations and a uniform distribution of missed sub‐vertices along line segments. Depending on the magnitudes of the different sources of uncertainty, not accounting for potential deviations from straight line segments may drastically underestimate the positional uncertainty of line features. 相似文献
50.
In an earlier paper Arp, Bi, Chu and Zhu investigated various quasar samples and recognized a periodicity of remarkable degree in them. Their conclusion was that the existence of such a periodicity is a counterevidence against the cosmological origin of quasar redshifts. Since this question is of great importance in a cosmological context, here we reanalyze some of the samples together with a galaxy sample of the pencil-beam survey of Broadhurstet al. Our result is that on the plane of cosmological parameters (0, 0) there is a non-negligible region where two quasar samples and the galaxy sample are simultaneously fairly periodic. Pure periodicity is still compatible with cosmological principles, at least on length scales much longer than the period length. So the regularities can fit into a cosmological context. 相似文献