Earthquake-induced Groundwater and Gas Changes

Active faults are commonly associated with spatially anomalously high concentrations of soil gases such as carbon dioxide and Rn, suggesting that they are crustal discontinuities with a relatively high vertical permeability through which crustal and subcrustal gases may preferably escape towards the earth's surface. Many earthquake-related hydrologic and geochemical temporal changes have been recorded, mostly along active faults especially at fault intersections, since the 1960s. The reality of such changes is gradually ascertained and their features well delineated and fairly understood. Some coseismic changes recorded in ``near field' are rather consistent with poroelastic dislocation models of earthquake sources, whereas others are attributable to near-surface permeability enhancement. In addition, coseismic (and postseismic) changes were recorded for many moderate to large earthquakes at certain relatively few ``sensitive sites' at epicentral distances too large (larger for larger earthquakes, up to 1000 km or more for magnitude 8) to be explained by the poroelastic models. They are probably triggered by seismic shaking. The sensitivity of different sites can be greatly different, even when separated only by meters. The sensitive sites are usually located on or near active faults, especially their intersections and bends, and characterized by some near-critical hydrologic or geochemical condition (e.g., permeability that can be greatly increased by a relatively small seismic shaking or stress increase). Coseismic changes recorded for different earthquakes at a sensitive site are usually similar, regardless of the earthquakes' location and focal mechanism. The sensitivity of a sensitive site may change with time. Also pre-earthquake changes were observed hours to years before some destructive earthquakes at certain sensitive sites, some at large epicentral distances, although these changes are relatively few and less certain. Both long-distance coseismic and preseismic changes call for more realistic models than simple elastic dislocation for explanation. Such models should take into consideration the heterogeneity of the crust where stress is concentrated at certain weak points (sensitive sites) along active faults such that the stress condition is near a critical level prior to the occurrence of the corresponding earthquakes. To explain the preseismic changes, the models should also assume a broad-scaled episodically increasing strain field.     

Influence of salinity and fish species on PAH uptake from dispersed crude oil

The use of chemical oil dispersants to minimize spill impacts causes a transient increase in hydrocarbon concentrations in water, which increases the risk to aquatic species if toxic components become more bioavailable. The risk of effects depends on the extent to which dispersants enhance the exposure to toxic components, such as polycyclic aromatic hydrocarbons (PAH). Increased salinities can reduce the solubility of PAH and the efficiency of oil dispersants. This study measured changes in the induction of CYP1A enzymes of fish to demonstrate the effect of salinity on PAH availability. Freshwater rainbow trout and euryhaline mummichog were exposed to water accommodated fractions (WAF), and chemically-enhanced water accommodated fractions (CEWAF) at 0 per thousand, 15 per thousand, and 30 per thousand salinity. For both species, PAH exposure decreased as salinity increased whereas dispersant effectiveness decreased only at the highest salinity. Hence, risks to fish of PAH from dispersed oil will be greatest in coastal waters where salinities are low.     

Methods for reactive oxygen species (ROS) detection in aqueous environments

This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): ¹O₂, O ₂ ^·? /HOO·, H₂O₂, HO·, and CO ₃ ^·? in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.     

Multivariate statistical analysis of hydrochemical data to assess alluvial aquifer–stream connectivity during drought and flood: Cressbrook Creek,southeast Queensland,Australia

A catchment-scale multivariate statistical analysis of hydrochemistry enabled assessment of interactions between alluvial groundwater and Cressbrook Creek, an intermittent drainage system in southeast Queensland, Australia. Hierarchical cluster analyses and principal component analysis were applied to time-series data to evaluate the hydrochemical evolution of groundwater during periods of extreme drought and severe flooding. A simple three-dimensional geological model was developed to conceptualise the catchment morphology and the stratigraphic framework of the alluvium. The alluvium forms a two-layer system with a basal coarse-grained layer overlain by a clay-rich low-permeability unit. In the upper and middle catchment, alluvial groundwater is chemically similar to streamwater, particularly near the creek (reflected by high HCO₃/Cl and K/Na ratios and low salinities), indicating a high degree of connectivity. In the lower catchment, groundwater is more saline with lower HCO₃/Cl and K/Na ratios, notably during dry periods. Groundwater salinity substantially decreased following severe flooding in 2011, notably in the lower catchment, confirming that flooding is an important mechanism for both recharge and maintaining groundwater quality. The integrated approach used in this study enabled effective interpretation of hydrological processes and can be applied to a variety of hydrological settings to synthesise and evaluate large hydrochemical datasets.     

Diurnal Evolution and Annual Variability of Boundary-Layer Height and Its Correlation to Other Meteorological Variables in California’s Central Valley

One year of observations from a network of five 915-MHz boundary-layer radar wind profilers equipped with radio acoustic sounding systems located in California’s Central Valley are used to investigate the annual variability of convective boundary-layer depth and its correlation to meteorological parameters and conditions. Results from the analysis show that at four of the sites, the boundary-layer height reaches its maximum in the late-spring months then surprisingly decreases during the summer months, with mean July depths almost identical to those for December. The temporal decrease in boundary-layer depth, as well as its spatial variation, is found to be consistent with the nocturnal low-level lapse rate observed at each site. Multiple forcing mechanisms that could explain the unexpected seasonal behaviour of boundary-layer depth are investigated, including solar radiation, precipitation, boundary-layer mesoscale convergence, low-level cold-air advection, local surface characteristics and irrigation patterns and synoptic-scale subsidence. Variations in solar radiation, precipitation and synoptic-scale subsidence do not explain the shallow summertime convective boundary-layer depths observed. Topographically forced cold-air advection and local land-use characteristics can help explain the shallow CBL depths at the four sites, while topographically forced low-level convergence helps maintain larger CBL depths at the fifth site near the southern end of the valley.     

Short-term endproducts of sulfate reduction in a salt marsh: Formation of acid volatile sulfides,elemental sulfur,and pyrite

Rates of sulfate reduction, oxygen uptake and carbon dioxide production in sediments from a short Spartina alterniflora zone of Great Sippewissett Marsh were measured simultaneously during late summer. Surface sediments (0–2 cm) were dominated by aerobic metabolism which accounted for about 45% of the total carbon dioxide production over 0–15 cm. Rates of sulfate reduction agreed well with rates of total carbon dioxide production below 2 cm depth indicating that sulfate reduction was the primary pathway for sub-surface carbon metabolism. Sulfate reduction rates were determined using a radiotracer technique coupled with a chromous chloride digestion and carbon disulfide extraction of the sediment to determine the extent of formation of radiolabelled elemental sulfur and pyrite during shortterm (48 hr) incubations. In the surface 10 cm of the marsh sediments investigated, about 50% of the reduced radiosulfur was recovered as dissolved or acid volatile sulfides, 37% as carbon disulfide extractable sulfur, and only about 13% was recovered in a fraction operationally defined as pyrite. Correlations between the extent of sulfate depletion in the marsh sediments and the concentrations of dissolved and acid volatile sulfides supported the results of the radiotracer work. Our data suggest that sulfides and elemental sulfur may be major short-term end-products of sulfate reduction in salt marshes.     

Edge-driven convection

We consider a series of simple calculations with a step-function change in thickness of the lithosphere and imposed, far-field boundary conditions to illustrate the influence of the lithosphere on mantle flow. We consider the effect of aspect ratio and far-field boundary conditions on the small-scale flow driven by a discontinuity in the thickness of the lithosphere. In an isothermal mantle, with no other outside influences, the basic small-scale flow aligns with the lithosphere such that there is a downwelling at the lithospheric discontinuity (edge-driven flow); however, the pattern of the small-scale flow is strongly dependent on the large-scale thermal structure of a much broader area of the upper mantle. Long-wavelength temperature anomalies in the upper mantle can overwhelm edge-driven flow on a short timescale; however, convective motions work to homogenize these anomalies on the order of 100 million years while cratonic roots can remain stable for longer time periods. A systematic study of the effect of the boundary conditions and aspect ratio of the domain shows that small-scale, and large-scale flows are driven by the lithosphere. Edge-driven flow produces velocities on the order of 20 mm/yr. This is comparable to calculations by others and we can expect an increase in this rate as the mantle viscosity is decreased.     

Magnetofossils in the sediment of Lake Baikal, Siberia

A multidisciplinary approach involving rock-magnetics, transmission electron microscopy, and X-ray diffraction was used to identify a biogenic magnetite component in the Lake Baikal, Siberia, sedimentary magnetic record. The distinctive biogenic component to the magnetic record occurs as chains of single-domain, elongate hexagonal and tear-drop cone-shaped magnetite particles. These magnetofossils are inferred to be magnetosomes produced by magnetotactic bacteria living in the surficial sediment throughout Lake Baikal. Postdepositional reduction diagenesis results in the loss of the fine-grained magnetofossils at depth. In addition, this study shows that the fine-grained magnetofossils are removed by the process of storage diagenesis during long periods (21 months) of core storage, which results in a change to a coarser grained, slightly higher coercivity bulk magnetic mineral assemblage. Although the Lake Baikal sedimentary magnetic record has several distinct and complex components, by determining their origin this study has shown that the sediments are well suited for environmental magnetic study.