激光剥蚀等离子质谱微区分析在固体地球科学中的应用进展

当前分析化学技术正向着痕量微区方向发展。这使得我们能够用更小更少的样品直接得到更多的地球化学信息。在诸多微区测试技术中,激光剥蚀等离子质谱（LA-ICPMS）技术发展最快。其地质应用较广,激光探针等离子体质谱能够进行固体样品的微区微量元素和同位素的分析,具有灵敏度高、简便、快速的特点,同样具有在同位素定年上的潜力。近年来又研制出激光剥蚀多道接收等离子质谱（LA-MC-ICPMS）仪,使得微区同位素分析开始了新的革命。而多种微区技术综合应用为近几年分析地球化学新的趋势。     

The distribution, sources and toxicity risks of polycyclic aromatic hydrocarbons and n-alkanes in riverine and estuarine core sediments from the Daliao River watershed

The burial characteristics and toxicity risks associated with n-alkanes and polycyclic aromatic hydrocarbons (PAHs) in the riverine and estuarine sediments of the Daliao River watershed were investigated based on three sediment cores. The sum of the n-alkane and PAH concentrations, normalized to organic carbon (OC), ranged from 0.27 to 63.09 μg g^?1OC^?1 and 6.60 to 366.20 μg g^?1OC^?1, respectively. The features and the history of industrial activities, such as the oil and chemical industries and port activities near the river and estuary, resulted in different distributions and sources of hydrocarbons. The sources of pollution were identified based on n-alkane indexes and on diagnostic ratios of PAHs. The diagnostic ratios indicated that the n-alkanes were derived from both biogenic and petrogenic sources in different proportions and that the PAHs were derived primarily from petrogenic combustion sources. A hierarchical cluster analysis grouped the core samples into two clusters. The first cluster, river sediments, corresponded to industrial activities; the second cluster, estuarine sediments, corresponded to port shipping activities. The toxic potency of the PAHs in the cores was assessed in terms of toxic equivalents (TEQs) of dibenzo[a,h]anthracene and benzo[a]pyrene. The top layer of the sediment in the cores had a relatively high toxicity. The TEQ values for benzo(a)pyrene (TEQ_BaP) and dioxins (TEQ_TCDD) furnished a consistent assessment of the PAHs in the sediment cores.     

新疆西准噶尔发现早泥盆世埃达克岩:大地构造及成矿意义

新疆西准噶尔博什库尔-成吉斯(Boshchekul-Chingiz)岩浆弧南缘,额敏县东南约100km的阿克乔克含铜花岗闪长岩和花岗闪长斑岩,其锆石U-Pb年龄为410.5±2.9Ma,形成于泥盆世早期.岩石具有埃达克岩的地球化学特征,表现为高钾钙碱性-钙碱性,SiO2含量在61％～66％之间,具高Al(Al2O3=15.67％ ～ 16.87％)、Sr(475×10-6 ～ 879×10-6)及高Sr/Y比值(36 ～77),低Y(9.87×10-6～14.46×10-6)、Yb(0.96×10-6～ 1.49×10-6),富钠贫钾(Na2O =4.25％ ～5.58％,K2O=2.26％ ～3.27％,Na2O/K2O=1.40～ 2.47),MgO=1.51％ ～2.58％,Mg#=41～48,并显示富集强不相容元素(Ba、Rb、Sr、Th、U)和LREE,(La/Yb)N=6.0～10.2,强烈亏损高场强元素(Nb-Ta、Ti),Y/Yb=10,无Eu异常(Eu/Eu*≈1.0)和HREE呈平坦型的配分特点,以及与环太平洋新生代埃达克岩相当的Rb/Sr(0.04 ～0.07)和La/Ce(0.42 ～0.51)比值,但偏低的Nb/U比值可能与俯冲沉积物加入有关.阿克乔克花岗闪长岩及花岗闪长斑岩是早泥盆世早期库吉拜-和布克赛尔(Kujibai-Hebukesaier)及洪古勒楞蛇绿岩带所代表的古大洋向南俯冲的玄武质洋壳部分熔融的产物,源区残留相主要为角闪石+辉石+石榴石,源岩应为石榴角闪岩;阿克乔克早泥盆世埃达克岩及谢米斯台-赛尔山晚志留世-早泥盆世A-型花岗岩(422～405 Ma,Chen et al.,2010)构造岩浆岩带可东延至扎河坝-阿尔曼太蛇绿岩带之北的岛弧带,构成一条贯穿东、西准噶尔北部的巨型构造带;阿克乔克埃达克岩伴有斑岩型Cu成矿作用,因此,在东、西准噶尔博什库尔-成吉斯-达拉特-巴依塔格巨型岩浆弧带有可能存在与埃达克岩有关的Cu-Au矿带.     

Assessment of physical vulnerability to agricultural drought in China

Food security has drawn great attention from both researchers and practitioners in recent years. Global warming and its resultant extreme drought events have become a great challenge to crop production and food price stability. This study aimed to establish a preliminary theoretical methodology and an operational approach for assessing the physical vulnerability of two wheat varieties (“Yongliang #4” and “Wenmai #6”) to agricultural drought using Environmental Policy Integrated Climate model (EPIC). Drought hazard index was set up based on output variables of the EPIC water stress (WS), including the magnitude and duration of WS during the crop-growing period. The physical vulnerability curves of two wheat varieties to drought were calculated by the simulated drought hazard indexes and loss ratios. And the curve’s effect on drought disaster risk was defined as A, B and C sections, respectively. Our analysis results showed that (a) physical vulnerability curves varied between two wheat varieties, which were determined by genetic parameters of crops; (b) compared with spring wheat “Yongliang 4#” winter wheat “Wenmai 6#” was less vulnerable to drought under the same drought hazard intensity scenario; (c) the wheat physical vulnerability curve to drought hazard displayed a S shape, suggesting a drought intensity–dependent magnifying or reducing effect of the physical vulnerability on drought disasters; (d) the reducing effect was mainly in the low-value area of vulnerability curve, whereas the magnifying effect was in the middle-value area, and the farming-pastoral zone and the Qinling Mountain–Huaihe River zone formed important spatial division belts.     

双粒子联合冲击破岩仿真研究

单粒子冲击破岩与粒子冲击钻井的真实工况有一定的差异,因此,需要研究多粒子联合冲击破岩的规律。在双粒子联合冲击破岩条件下,利用LS-DYNA的参数化设计语言,采用无量纲化分析方法,选择粒子间距、直径、初速度和入射角度为设计变量,建立了它们与岩石破碎体积和侵入深度之间的关系,并绘制了它们之间的变化关系曲线图。进一步分析这些曲线图的变化规律后发现：间距为0.25个左右的基准直径、粒子直径取0.8~1个基准直径、冲击初速度取每秒32 000~40 000个基准直径、入射角度为0°~40°,粒子冲击破碎岩石效果达到最佳或接近最佳。这些结果可以作为深入研究多粒子联合冲击破岩的参考依据。     

Heat flow and thermal modeling of the Yinggehai Basin, South China Sea

Geothermal gradients are estimated to vary from 31 to 43 °C/km in the Yinggehai Basin based on 99 temperature data sets compiled from oil well data. Thirty-seven thermal conductivity measurements on core samples were made and the effects of porosity and water saturation were corrected. Thermal conductivities of mudstone and sandstone range from 1.2 to 2.7 W/m K, with a mean of 2.0±0.5 W/m K after approximate correction. Heat flow at six sites in the Yinggehai Basin range from 69 to 86 mW/m², with a mean value of 79±7 mW/m². Thick sediments and high sedimentation rates resulted in a considerable radiogenic contribution, but also depressed the heat flow. Measurements indicate the radiogenic heat production in the sediment is 1.28 μW/m³, which contributes 20% to the surface heat flow. After subtracting radiogenic heat contribution of the sediment, and sedimentation correction, the average basal heat flow from basement is about 86 mW/m².Three stages of extension are recognized in the subsidence history, and a kinematic model is used to study the thermal evolution of the basin since the Cenozoic era. Model results show that the peak value of basal heat flow was getting higher and higher through the Cenozoic. The maximum basal heat flow increased from 65 mW/m² in the first stage to 75 mW/m² in the second stage, and then 90 mW/m² in the third stage. The present temperature field of the lithosphere of the Yinggehai Basin, which is still transient, is the result of the multistage extension, but was primarily associated with the Pliocene extension.     

路面基层压实度现场测试中的非理想因素分析--以广东西部沿海高速公路新会段为例

通过对广东西部沿海高速公路路面基层现场压实度检测过程的详细观察，并在不同的条件下反复进行试验、分析比较，找出了影响压实度现场检测精度的主要非理想因素，即标准砂密度、试样含水量和路面基层平整度，并提出了解决方法。     

塔里木盆地巴楚隆起寒武系及奥陶系白云岩类型及形成机理

采用染色薄片鉴定、阴极发光显微镜观察、微量元素分析、碳氧稳定同位素测定及包体侧温等手段，对塔里木盆地巴楚断隆区寒武系和奥陶系白云岩的特征及成因进行了研究，共划分出四种类型的白云岩：①泥粉晶白云岩，其m(Ca)/m(Mg)平均为3-10，Sr含量高（>300×10-6 ），m(Sr)/m(Ba)>>1，?13C值较高（-1‰-+1‰），₁₈O值较低（-5‰--8‰），沉积环境为潮上带云坪，为准同生作用阶段潮上萨布哈白云化作用形成。②含雾心亮边白云石的细晶白云岩，其m(Ca)/m(Mg)较低（1-2），Sr含量中等（100×10-6-200×10-6），m(Sr)/m(Ba) >1，?13C值在-2‰左右，₁₈O值低，在-7‰左右，沉积环境为开阔台地浅滩，为准同生或早期成岩作用阶段回流渗透白云化作用形成。③含明亮白云石晶体及钙质残余的钙质白云岩，其m(Ca)/m(Mg)较低（1左右），Sr含量最低（100×10-6左右），m(Sr)/m(Ba) < 1，?13C值最低（-1‰--3‰），?18O值较低（-6‰左右），沉积环境为灰坪、云坪及开阔台地，为准同生或早期成岩作用阶段混合水白云化作用形成。④砂糖状白云岩，其m(Ca)/m(Mg)较低（1-2），Sr含量低（<100×10-6），m(Sr)/m(Ba)<1，?13C值较高（-1‰-+3‰），₁₈O值较低（-5‰--8‰），沉积环境多为浅滩，为晚期成岩作用阶段埋藏白云化作用形成。     

汶川地震地表破裂面形貌特征

准确描述破裂面形貌对于我们理解地震断层作用是非常重要的,破裂面的形貌特征包含许多关于地震和断层机制的有用信息。在Mw7.9 2008汶川地震中断层活动产生了两个新鲜的破裂面,八角庙破裂面和沙坝破裂面。我们使用3D便携式激光扫描仪(Tri mble GX)对两个破裂表面进行测量,在野外微观尺度上研究了破裂面形貌特征。通过能谱密度和均方值两个方法分析破裂面形貌,新鲜的破裂面表现为自相仿性,能谱密度和均方值均与剖面长度存在幂律关系。在能谱密度与空间频率的对数图中,能谱密度曲线存在明显的拐点,该拐点所对应的波长称为"特征波长",表明单一分形不能准确描述破裂面形貌。八角庙破裂面在平行滑动方向上的特征波长为7 mm,在垂直方向上特征波长略大一些(区域Ⅰ为10 mm,区域Ⅱ为9 mm);沙坝破裂面在平行滑动方向上的特征波长为8 mm,但垂直方向上特征波长略小(6 mm)。均方值曲线的最小二乘拟合直线的斜率为Hurst指数,该指数依赖于剖面线方向并描述破裂面形貌的各向异性,H指数的最小值和最大值分别与平行擦痕和垂直擦痕方向对应,这与野外断层面擦痕测量结果一致。沙坝破裂面的H指数极坐标图中存在次级H指数峰值(对应剖面线方向为85°和160°),这揭示破裂面上存在一组隐匿擦痕。该组隐匿擦痕为汶川地震之前断层活动中形成的,但这还不足以推测上一次断层活动的时间和规模。另外,通过比较新鲜节理面和破裂面表明H指数是否大于0.8反映了断层类型。在整个空间频率域上,能谱密度曲线斜率(-α)和均方值曲线斜率(H)的线性拟合关系为α=1.22+1.72H,并不严格满足两者之间理论关系式,α=1+2H。这个差异是由于测量信号噪音、破裂面的多分形性和分析方法的差异造成的。     

Adsorption of antimony(V) on kaolinite as a function of pH,ionic strength and humic acid

The present work investigated the adsorption and mobility (desorption) of Sb(V) on kaolinite using batch experiments. The adsorption of Sb(V) on kaolinite was studied as a function of contact time, pH, ionic strength, humic acid (HA), initial Sb(V) concentration and temperature. Kinetic studies suggest that the equilibrium is achieved within 24 h. The adsorption of Sb(V) was strongly affected by changes in I at low ionic strength and unaffected at high ionic strength. The adsorption is weakly dependent on the presence of humic acid, but is strongly dependent on pH. Within the range tested, the optimal pH for Sb(V) adsorption is 3.6, and close to 75% removal can be achieved. Desorption is dependent on the original suspension pH. The addition sequence of Sb(V)/HA do not influence the adsorption of Sb(V) on kaolinite. The adsorption data fit both the Freundlich and Langmuir isotherm. The thermodynamic parameters (ΔH ⁰, ΔS ⁰ and ΔG ⁰) were calculated from the temperature dependence, and the results suggest the endothermic and spontaneous nature of the process.