The chemical changes of DOM from black waters to coastal marine waters by HPLC combined with ultrahigh resolution mass spectrometry

How dissolved organic matter (DOM) undergoes chemical changes during its transit from river to ocean remains a challenge due to its complex structure. In this study, DOM along a river transect from black waters to marine waters is characterized using an offline combination of reversed-phase high performance liquid chromatography (RP-HPLC) coupled to electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS), as well as tandem ESI-FTICR-MS. In addition, a water extract from degraded wood that mainly consists of lignins is used for comparison to the DOM from this transect. The HPLC chromatograms of all DOM samples and the wood extract show two major well-separated components; one is hydrophilic and the other is hydrophobic, based on their elution order from the C₁₈ column. From the FTICR-MS analysis of the HPLC fractions, the hydrophilic components mainly contain low molecular weight compounds (less than 400 Da), while the hydrophobic fractions contain the vast majority of compounds of the bulk C₁₈ extracted DOM. The wood extract and the DOM samples from the transect of black waters to coastal marine waters show strikingly similar HPLC chromatograms, and the FTICR-MS analysis further indicates that a large fraction of molecular formulas from these samples are the same, existing as lignin-like compounds. Tandem mass spectrometry experiments show that several representative molecules from the lignin-like compounds have similar functional group losses and fragmentation patterns, consistent with modified lignin structural entities in the wood extract and these DOM samples. Taken together, these data suggest that lignin-derived compounds may survive the transit from the river to the coastal ocean and can accumulate there because of their refractory nature.     

On the occurrence of convective motions in the upper photosphere

We have examined whether the motion field in the photosphere in the range of optical depths 0.25< ₀< 0.6 is dominated by thermal convection or by vibrations. The observed asymmetries of infrared Fraunhofer lines indicate the presence of motions, and the fact that the asymmetry is zero for lines of low excitation and increases with the excitation potential shows that these motions are chiefly convective in this part of the photosphere: upward moving elements appear to be hotter than downward moving ones.Assuming furthermore that the photosphere can be described by a three-column model, with temperature differences as given by Edmonds (1967), we find that in the range of optical depths given above, where T seems to vary between 80 and 160 °K, average convective velocities of 2.3 to 3.2 km/sec should occur. This result is in numerical agreement with (a) a previous one by the present authors (1967) derived from the variation of line asymmetry with depth in lines of one multiplet, (b) a finding by Lambert and Mallia (1968) deduced from absolute wavelength measurements of Fraunhofer lines, and (c) a recent result of Beckers (1968) found from a comparison of two granulation pictures obtained simultaneously with a narrow-band filter centred on the two wings of a faint line.     

Submerged cylinder wave energy device: theory and experiment

Linearized water wave theory is used to show that a submerged long circular cylinder suitably constrained by springs and dampers to make small harmonic oscillations, can be extremely efficient in absorbing the energy in an incident regular wave whose crests are parallel to the axis of the cylinder. Experimental results are described which confirm the theory for small amplitude waves and which suggest that the device can still be fairly efficient in waves of moderate amplitude.     

Hybrid control of seismic-excited bridge structures

Recently, several hybrid protective systems have been explored for applications to seismic-excited bridge structures. In particular, two types of aseismic hybrid protective systems have been shown to be quite effective: (i) rubber bearings and variable dampers (or actuators), and (ii) sliding bearings and actuators. In this paper, control methods are presented for these hybrid protective systems. The control methods are based on the theory of variable structure system (VSS) or sliding mode control (SMC). Emphasis is placed on the static (direct) output feedback controllers using only the information measured from a few sensors without an observer. Simulation results demonstrate that the control methods presented are robust with respect to system parametric uncertainties and the performance is quite remarkable. Sensitivity studies are conducted to evaluate the effectiveness of hybrid protective systems and passive sliding isolators for reducing the response of seismic-excited bridge structures. The advantages of each protective system are demonstrated by simulation results for a wide range of earthquake intensities.     

Geochemical surveillance of active volcanoes: data on the fumaroles of Vulcano (Aeolian Islands,Italy)

Temperature and chemical composition of condensates of higher temperature fumaroles, located on the rim of the crater of Vulcano, were studied over a period of one year. Maximum temperature changed from 216°C (June 1977) to 291°C (May 1978). HCl is the main constituent of condensates which, in comparison with data from fumaroles of other volcanoes, contain also noteworthy quantities of boron and bromine. Since these chemical characteristics suggested the possible inflow of water of marine origin into the volcanic conduit, experimental data on seawater-rock reactions at high temperatures and pressures were taken into account. A model is drafted for the volcanic system, in which the occurrence of an aquifer interposed between the magma chamber and the surface is considered. The vaporization of this aquifer would feed the fumaroles giving rise, through different mixing processes with surface waters, to the observed differences in temperature and chemical composition. However, data available at present are not sufficient to support the proposed model, which must be mainly considered as a working hypothesis.     

Background of ground penetrating radar measurements

Characterization of the shallow subsurface (0.25 to 10 m) is of growing importance for engineering activities, solutions of environmental problems, and archaeological investigations. Ground-penetrating radar (GPR) is an appropriate technique considering the depth range of interest, the strength of electric and magnetic contrasts between different subsurface layers and buried objects, and the required resolution. GPR surveys can detect subsurface structures by recording electromagnetic reflections from discontinuities. The detectability of objects and the delineation of subsurface structures increases with increasing wave velocity and conductivity differences between the object and its surroundings or between adjacent layers. However, unwanted reflections from objects above the surface influence the images. Shielded antennas can be used to avoid strong reflections from these objects. The data thus obtained are, however, more difficult to interpret. The fundamentals of GPR and two different acquisition setups for a GPR system are discussed. Basic interpretation tools for travel-time and velocity estimation are described, and finally, case studies are presented, followed by conclusions.     

Partial melting in the Inzie Head gneisses: the role of water and a petrogenetic grid in KFMASH applicable to anatectic pelitic migmatites

A sequence of prograde isograds is recognized within the Dalradian Inzie Head gneisses where pelitic compositions have undergone variable degrees of partial melting via incongruent melting reactions consuming biotite. Three leucosome types are identified. At the lowest grades, granitic leucosomes containing porphyroblasts of cordierite (CRD‐melt) are abundant. At intermediate grades, CRD‐melt mingles with garnetiferous leucosomes (GT‐melt). At the highest grades, CRD‐melt coexists with orthopyroxene‐bearing leucosomes (OPX‐melt), while garnet is conspicuously absent. The prograde metamorphic field gradient is constrained to pressures of 2–3 kbar below the CRD‐melt isograd, and no greater than 4.5 kbar at the highest grade around Inzie Head. A petrogenetic grid, calculated using thermocalc , is presented for the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) system for the phases orthopyroxene, garnet, cordierite, biotite, sillimanite, H₂O and melt with quartz and K‐feldspar in excess. For the implied field gradient, the reaction sequence predicted by the grid is consistent with the successive prograde development of each leucosome type. Compatibility diagrams suggest that, as anatexis proceeded, bulk compositions may have been displaced towards higher MgO content by the removal of (relatively) ferroan granitic leucosome. An isobaric (P = 4 kbar) T–a_H2O diagram shows that premigmatization fluids must have been water‐rich (a_H2O > 0.85) and suggests that, following the formation of small volumes of CRD‐melt, the system became fluid‐absent and melting reactions buffered a_H2O to lower values as temperatures rose. GT‐ and OPX‐melt formed by fluid‐absent melting reactions, but a maximum of 7–11% CRD‐melt fraction can be generated under fluid‐absent conditions, much less than the large volumes observed in the field. There is strong evidence that the CRD‐melt leucosomes could not have been derived by buoyantly aided upwards migration from levels beneath the migmatites. Their formation therefore required a significant influx of H₂O‐rich fluid, but in a quantity insufficient to have exhausted the buffering capacity of the solid assemblage plus melt. Fluid : rock ratios cannot have exceeded 1 : 30. The fluid was channelled through a regionally extensive shear zone network following melt‐induced failure. Such an influx of fluid at such depths has obvious consequences for localized crustal magma production and possibly for cordierite‐bearing granitoids in general.     

Spatially resolved spectral observations of Asteroid 951 Gaspra

On October 29, 1991 the Galileo spacecraft encountered Asteroid 951 Gaspra with a telescopic CCD camera and a near infrared mapping spectrometer that provided the first optically resolved views of any asteroid. Data from these two sensors were combined to detect the spectral signature of iron bearing minerals on this S-type asteroid. A minimum of two spectral units were identified on 951 Gaspra, both containing a higher relative abundance of olivine than those found in ordinary chondrites. These data indicate that this S asteroid is an object that has undergone igneous differentiation processes. A 2.7 μm spectral feature was also detected on the surface of 951 Gaspra and may be due to the presence of structural OH.