An Experimental Study of Nepheline-Kalsilite Exsolution

The nepheline-kalsilite exsolution reaction was studied isothermallybetween 400 and 700°C. Under nonaqueous conditions the mechanisminvolves nucleation of kalsilite and growth by diffusion ofthe alkalis. As predicted by simple nucleation theory, the nucleationrate and hence the over-all exsolution rate are strongly dependenton the supersaturation of the nepheline. A decrease in temperatureat constant composition increases the supersaturation and therebythe nucleation rate. This increased nucleation rate is opposedby the decrease in the growth rate due to slower volume diffusion.At a supersaturation of more than 8–10 mole per cent thenumber of nuclei is large and the over-all exsolution rate isdetermined primarily by the growth rate. The activation energyfor growth is 28 kcal/mole. An increase of two kilobars in thehydrostatic pressure has little effect on the kinetics of thereaction. Under nonhydrostatic conditions the exsolution rateincreases significantly because the nucleation rate is faster. Under hydrothermal conditions the ‘exsolution’ rateis approximately two orders of magnitude faster due to a modificationin the mechanism. Partial dissolution of the original solidsolution in distilled water creates a condition of nonequilibriumin which the fluid is sodium-rich. Rapid alkali exchange eliminatesthis condition but produces the equilibrium compositions ofthe solids because kalsilite nucleates and grows in contactwith the fluid. The experimental evidence for this mechanismincludes X-ray diffraction data showing a gradual change inthe composition of the initial supersaturated solid, essentiallyidentical activation energies for growth under aqueous and nonaqueousconditions, and a lower percentage of oxygen isotope exchangethan ‘exsolution’ in the same experiment.     

Alkali Picrites Formed by Melting of Old Metasomatized Lithospheric Mantle: Manitdlat Member, Vaigat Formation, Palaeocene of West Greenland

Alkaline picrites and basalts constitute 20–200 m of lavaflows and hyaloclastites in the middle part of an     

Timing of Late Quaternary glaciation along the southwestern slopes of the Qilian Shan, Tibet

Moraines along the southwestern slopes of the Qilian Shan were dated using cosmogenic radionuclide (CRN) surface exposure techniques to help define the timing of glaciation in northernmost Tibet. The CRN data show glaciers extending 5–10 km beyond their present positions during the global Last Glacial Maximum (LGM) and probably maintained at their maximum extent until the Lateglacial. These data help support the view that glaciers throughout Tibet and the Himalaya were maintained at or near their maximum LGM extent until the Lateglacial. An optically stimulated luminescence date of 11.8 ± 1.0 ka on silt that caps a latero-frontal moraine shows that glaciers had retreated significantly by the end of the Pleistocene and that loess was beginning to form in this region in response to the changing climate during and after the Younger Dryas Stade.     

强对流过程对大尺度模式洋面通量加强的参数化研究与进展

由于地球表面热通量直接决定着大气环流运动,在大气数值模式中如何准确描述地球表面热通量就变处得十分重要.洋面是地球表面最广泛分布的下垫面,它的表面热通量描述尤为被重视.尤其是西赤道太平洋暖池、东赤道太平洋冷舌、ITCZ及信风带等关键区域的洋面热通量的准确估计更是非常重要,这些区域的地表通量变化通常被认为是全球气候变化即ENSO现象的最重要的信号[1].众所周知,中尺度降水对流在以上关键海域频繁发生.中尺度降水对流系统往往有较强的下沉气流(downdraft)[2],这种下沉气流在中尺度降水对流系统与大尺度过程的相互作用中伴演着重要角色.     

WEATHERING BY WETTING AND DRYING: SOME EXPERIMENTAL RESULTS

A series of experiments on sandstone and dolerite was undertaken in an attempt to better understand the wetting and drying weathering process. As rock samples are frequently subjected to wet–dry cycles within the simulation of other weathering mechanisms (e.g. freeze–thaw), three common methods of moisture application were used and the influences of these evaluated. It was found that the method of moisture application could affect the nature of the weathering products resulting from wetting and drying. It was also observed that there were changes in the internal properties of the rock (e.g. porosity/microporosity) and that these could influence the synergistic operation of other weathering processes. Although not all of the observations could be explained, it is apparent that wetting and drying has both a direct and an indirect effect on the weathering of rock that has not been taken into account in simulations. Greater cognizance needs to be given to the role of this process both in the field and in laboratory simulations.     

Geomorphology of the eastern Badia basalt plateau, Jordan

The eastern Badia of the Hashemite Kingdom of Jordan is a landscape developed predominantly on late Tertiary and Quaternary basalt lava flows, which vary in age between 8.9 million and 0.1 million years. Pyroclastic deposits are associated with remnant volcanic cones. There is limited, seasonal rainfall. Natural vegetation regenerates during cool, damp months. Slopes, which range from concave to convex forms and have varying relief, can be related to different basalts and the time since emplacement. Much of the ground surface is mantled with boulders. In many places the continuity of boulder cover produces a desert pavement. Clasts show differing degrees of burial or exhumation, depending on the surrounding topography. Water and sediment movement are important to landscape development. Much sediment is deposited in pans, which evolve at topographic lows. The pans, known locally as Qa, vary in form depending on drainage network development. Transitional forms, known as Marab, develop where wadis widen out and sediments are deposited along ephemeral channels. Groundwater is significant, with three aquifers beneath much of the eastern Badia. Recharge of the upper aquifer is predominantly on the footslopes of the Druze Mountains, with north to south flow. Groundwater extraction has resulted in the expansion of agriculture, with consequent changes in soil and water quality.     

DIFFERENTIAL ROCK WEATHERING IN THE 'VALLEY OF THE BOULDERS', KÄRKEVAGGE, SWEDISH LAPLAND

Kärkevagge is an alpine valley in the low arctic of Swedish Lapland. It is named after, and famous for, its large deposit of immense (c. 10–15 m) boulders that almost fill the lower valley. Above the boulder deposit, on the flanks of the valley, are more recent and generally much smaller (c. 1–3 m) individual boulders that have fallen from the valley-wall cliff face, presumably from post-glacial valley-side unloading. Some of these smaller boulders are seemingly fresh and unweathered while others have been reduced to no more than mounds in the tundra. These boulders must be younger than the larger, lower giant boulder deposit, but are not particularly recent rockfalls as they are partially buried in colluvium. Comparisons of mineralogy and chemistry indicate that the possibility exists that the incompetent, 'rotten' rocks, if not considerably older than their competent neighbors, are inherently self-destructive. They have evidence of increased sulfur content, which is a proxy for pyrite, a known weathering accelerant in Kärkevagge.     

EFFECTS OF CLIMATE CHANGE ON INLAND WATERS OF THE PACIFIC COASTAL MOUNTAINS AND WESTERN GREAT BASIN OF NORTH AMERICA

The region designated as the Pacific Coastal Mountains and Western Great Basin extends from southern Alaska (64°N) to southern California (34°N) and ranges in altitude from sea level to 6200 m. Orographic effects combine with moisture-laden frontal systems originating in the Pacific Ocean to produce areas of very high precipitation on western slopes and dry basins of internal drainage on eastern flanks of the mountains. In the southern half of the region most of the runoff occurs during winter or spring, while in the northern part most occurs in summer, especially in glaciated basins. Analyses of long-term climatic and hydrological records, combined with palaeoclimatic reconstructions and simulations of future climates, are used as the basis for likely scenarios of climatic variations. The predicted hydrological response in northern California to a climate with doubled CO₂ and higher temperatures is a decrease in the amount of precipitation falling as snow, and substantially increased runoff during winter and less in late spring and summer. One consequence of the predicted earlier runoff is higher salinity in summer and autumn in San Francisco Bay. In saline lakes, the incidence of meromixis and the associated reduction in nutrient supply and algal abundance is expected to vary significantly as runoff fluctuates. In subalpine lakes, global warming will probably will lead to increased productivity. Lacustrine productivity can also be altered by changes in wind regimes, drought-enhanced forest fires and maximal or minimal snowpacks associated with atmospheric anomalies such as El Niño–Southern Oscillation (ENSO) events. Reduced stream temperature from increased contributions of glacial meltwater and decreased channel stability from changed runoff patterns and altered sediment loads has the potential to reduce the diversity of zoobenthic communities in predominately glacier-fed rivers. Climatic warming is likely to result in reduced growth and survival of sockeye salmon in freshwater, which would, in turn, increase marine mortality. Further research activities should include expanded studies at high elevations and of glacier mass balances and glacial runoff, applications of remote sensing to monitor changes, further refinement of regional climatic models to improve forecasts of future conditions and continued analyses of long-term physical, chemical and biological data to help understand responses to future climates. © 1997 John Wiley & Sons, Ltd.     

POTENTIAL EFFECTS OF CLIMATE CHANGES ON AQUATIC SYSTEMS: LAURENTIAN GREAT LAKES AND PRECAMBRIAN SHIELD REGION

The region studied includes the Laurentian Great Lakes and a diversity of smaller glacial lakes, streams and wetlands south of permanent permafrost and towards the southern extent of Wisconsin glaciation. We emphasize lakes and quantitative implications. The region is warmer and wetter than it has been over most of the last 12000 years. Since 1911 observed air temperatures have increased by about 0·11°C per decade in spring and 0·06°C in winter; annual precipitation has increased by about 2·1% per decade. Ice thaw phenologies since the 1850s indicate a late winter warming of about 2·5°C. In future scenarios for a doubled CO₂ climate, air temperature increases in summer and winter and precipitation decreases (summer) in western Ontario but increases (winter) in western Ontario, northern Minnesota, Wisconsin and Michigan. Such changes in climate have altered and would further alter hydrological and other physical features of lakes. Warmer climates, i.e. 2 × CO₂ climates, would lower net basin water supplies, stream flows and water levels owing to increased evaporation in excess of precipitation. Water levels have been responsive to drought and future scenarios for the Great Lakes simulate levels 0·2 to 2·5 m lower. Human adaptation to such changes is expensive. Warmer climates would decrease the spatial extent of ice cover on the Great Lakes; small lakes, especially to the south, would no longer freeze over every year. Temperature simulations for stratified lakes are 1–7°C warmer for surface waters, and 6°C cooler to 8°C warmer for deep waters. Thermocline depth would change (4 m shallower to 3·5 m deeper) with warmer climates alone; deepening owing to increases in light penetration would occur with reduced input of dissolved organic carbon (DOC) from dryer catchments. Dissolved oxygen would decrease below the thermocline. These physical changes would in turn affect the phytoplankton, zooplankton, benthos and fishes. Annual phytoplankton production may increase but many complex reactions of the phytoplankton community to altered temperatures, thermocline depths, light penetrations and nutrient inputs would be expected. Zooplankton biomass would increase, but, again, many complex interactions are expected. Generally, the thermal habitat for warm-, cool- and even cold-water fishes would increase in size in deep stratified lakes, but would decrease in shallow unstratified lakes and in streams. Less dissolved oxygen below the thermocline of lakes would further degrade stratified lakes for cold water fishes. Growth and production would increase for fishes that are now in thermal environments cooler than their optimum but decrease for those that are at or above their optimum, provided they cannot move to a deeper or headwater thermal refuge. The zoogeographical boundary for fish species could move north by 500–600 km; invasions of warmer water fishes and extirpations of colder water fishes should increase. Aquatic ecosystems across the region do not necessarily exhibit coherent responses to climate changes and variability, even if they are in close proximity. Lakes, wetlands and streams respond differently, as do lakes of different depth or productivity. Differences in hydrology and the position in the hydrological flow system, in terrestrial vegetation and land use, in base climates and in the aquatic biota can all cause different responses. Climate change effects interact strongly with effects of other human-caused stresses such as eutrophication, acid precipitation, toxic chemicals and the spread of exotic organisms. Aquatic ecological systems in the region are sensitive to climate change and variation. Assessments of these potential effects are in an early stage and contain many uncertainties in the models and properties of aquatic ecological systems and of the climate system. © 1997 John Wiley & Sons, Ltd.