Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.     

Vertical structure of the field of current velocities in the northwest part of the Black Sea based on the <Emphasis Type="Italic">LADCP</Emphasis> data for May 2004

The profiles of absolute current velocity obtained by using a lowered acoustic doppler current profiler (LADCP) are presented. In the course of the BSERP-3 expedition, the measurements were carried out in the regions of the Rim Current, anticyclonic eddy, and northwest shelf. In the core of the Rim Current, a unidirectional motion of waters is traced in layers below the main pycnocline down to depths greater than 500 m. Its characteristic velocity can be as high as 0.08 m/sec. It is shown that the direct action of the eddy is detected in the shelf region at distances larger than 20 km from the outer edge of the shelf in the zone bounded by an isobath of 100 m. The formation of multilayer vertical structures in the field of current velocities is revealed in the region of interaction of the anticyclonic eddy with irregularities of the bottom on the side of the shelf. A two-layer structure of currents with specific features in the layer of formed seasonal pycnocline is observed in the region of the shelf down to an isobath of 100 m. The profiles of the moduli of vertical shears of currents averaged over the casts ensemble are presented for the abyssal and shelf parts of the sea. It is shown that the shears induced by the geostrophic currents and wave processes in the region of the main pycnocline are comparable. Below the pycnocline, the shears are mainly determined by the wave processes. Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 25–37, November–December, 2008.     

On the reliability of millennial reconstructions of variations in surface air temperature in the Northern Hemisphere

The reliability of the recently published reconstructions of the surface air temperature variability in the Northern Hemisphere over the past 2000 yr is discussed. For this purpose, the power spectra of the two best known reconstructions (Mann et al.[10–12] and Moberg et al. [13]) are calculated and compared to the spectra of the 150-yr temperature series based on instrumental observations and simulated 1000-yr series. It is found that the Mann et al. reconstruction drastically underestimates low-frequency temperature variations, whereas the Moberg et al. reconstruction reproduces them much better, although with a certain underestimation rather than overestimation, as Mann et al. have recently argued.     

Wave diffraction and near-trapping by a multi-column gravity-based structure

This paper is concerned with the diffraction of water waves by offshore structures, with the ultimate aim of proposing tools for guiding airgap design. The diffraction of monochromatic waves by an array of four bottom mounted cylinders and a gravity-based structure is studied in detail using linear and second order theory. The phenomenon of near-trapping is investigated, allowing guidelines for airgap design to be established. When contemplating airgap design, however, it is crucially important that consideration is given to the largest waves in a sea state. Therefore, in this study a design wave, called NewWave, is proposed as a realistic model for large ocean waves and is used as the incident wave field in the wave-structure diffraction analysis.     

Detecting environmental change in estuaries: Nutrient and heavy metal distributions in sediment cores in estuaries from the Gulf of Finland,Baltic Sea

Historical sediment nutrient concentrations and heavy metal distributions were studied in four estuaries in the Gulf of Finland, Baltic Sea to examine the response of these estuaries to temporal changes in human activities. Cores were collected using a 1-m Mackereth corer and dated using ²¹⁰Pb and ¹³⁷Cs. The cores were analyzed for total carbon (TC), total nitrogen (TN), total phosphorus (TP), organic phosphorus (OP), inorganic phosphorus (IP), biogenic silica (BSi), loss-on-ignition (LOI), Cu, Zn, Al, Fe, Mn, K, Ca, Mg and Na. Principal component analysis (PCA) was used to summarize the trends in the chemical variables and to compare the trends at the different sites. Applying the 1986 ¹³⁷Cs date as a reference point, ²¹⁰Pb chronologies were constructed for the sites using either the CRS model or a composite model (using both CIC and CRS). Significant increases were observed in sedimentation rates, TP and TN concentrations in all of the cores. Copper showed clear increases from 1850 towards present at all sites. Furthermore, redundancy analysis (RDA) was used to correlate environmental variables (catchment land use, catchment size, estuary surface area, depth and lake percentage) to sediment geochemistry. Based on redundancy analysis (RDA), the percentage of agriculture in the catchment was the most important factor affecting the sediment accumulation rate. Urban land-use types and industry correlate well with sediment Cu and Ca concentrations. Forest areas were related to high sediment BSi concentrations. Catchment land use was the most significant factor affecting sediment geochemical composition and sediment accumulation rates in these coastal embayments. Our results demonstrate that the coastal estuaries of the Gulf of Finland respond to the increased nutrient loading with the increased sedimentation and nutrient accumulation rates.     

Geoacoustic Inversions of Horizontal and Vertical Line Array Acoustic Data From a Surface Ship Source of Opportunity

The application of an inversion methodology produces the first demonstration of a simultaneous solution for geoacoustic and source track parameters from acoustic data collected in a shallow-water, sandy sediment environment. Inversion solutions from data collected in the 2006 Shallow Water Experiment (SW06) are extracted from noise measurements of a surface ship source on an L-array. The methodology includes a screening algorithm to determine a set of frequencies for the inversion data. In addition, the methodology assesses the accuracy of the inversion solution and incorporates an estimation of parameter value uncertainties. The solution from the inversion of the horizontal component of the L-array data from the surface ship source before its closest point of approach (CPA) is used to construct modeled propagation loss for comparison with observed received level (RL) structure as the source departs from CPA. Inversion of the data from a single element in the vertical component of the L-array produces a solution that agrees with the solution obtained from the inversion of horizontal subaperture data. Also, modeled transmission loss (TL) structure obtained from the single-element inversion solution reproduces the depth dependence of the RL structure observed at other elements of the vertical component of the L-array.      

Large bio-geographical shifts in the north-eastern Atlantic Ocean: From the subpolar gyre, via plankton, to blue whiting and pilot whales

Pronounced changes in fauna, extending from the English Channel in the south to the Barents Sea in the north-east and off Greenland in the north-west, have occurred in the late 1920s, the late 1960s and again in the late 1990s. We attribute these events to exchanges of subarctic and subtropical water masses in the north-eastern North Atlantic Ocean, associated with changes in the strength and extent of the subpolar gyre. These exchanges lead to variations in the influence exerted by the subarctic or Lusitanian biomes on the intermediate faunistic zone in the north-eastern Atlantic. This strong and persistent bottom-up bio-physical link is demonstrated using a numerical ocean general circulation model and data on four trophically connected levels in the food chain – phytoplankton, zooplankton, blue whiting, and pilot whales. The plankton data give a unique basin-scale depiction of these changes, and a long pilot whale record from the Faroe Islands offers an exceptional temporal perspective over three centuries. Recent advances in simulating the dynamics of the subpolar gyre suggests a potential for predicting the distribution of the main faunistic zones in the north-eastern Atlantic a few years into the future, which might facilitate a more rational management of the commercially important fisheries in this region.     

Simulation of the quasi-biennial oscillations of the zonal wind in the equatorial stratosphere: Part II. Atmospheric general circulation models

The problem of simulating quasi-biennial oscillations (QBOs) of zonal velocity in the equatorial stratosphere in atmospheric general circulation models is considered. In accordance with the results from Part I of this study on the basis of the models developed at the Institute of Numerical Mathematics of the Russian Academy of Sciences (INM RAS), the possibility of implementing (in these models) mechanisms of QBO excitation through both the interaction of planetary waves with the mean flow and breaking of short gravity waves is investigated. A new high-resolution 2° × 2.5° × 80 version of the INM RAS model is designed, a climate simulation with the two 2° × 2.5° × 39 and 2° × 2.5° × 80 versions of the INM RAS model is briefly described, results of spectral analysis of equatorial wave activity are presented, and the QBO formation processes in these models are considered in detail. For the new 2° × 2.5° × 80 model, realistic QBOs of zonal wind are obtained as the result of the action of both mechanisms.     

A Probabilistic Model for Fatigue Crack Propagation Analysis

A simple probabilistic model for predicting crack growth behavior under random loading is pre-sented.In the model,the parameters c and m in the Paris-Erdogan Equation are taken as random variables,and their stochastic characteristic values are obtained through fatigue crack propagation tests on an offshorestructural steel under constant amplitude loading.Furthermore,by using the Monte Carlo simulation tech-nique,the fatigue crack propagation life to reach a given crack length is predicted.The tests are conducted toverify the applicability of the theoretical prediction of the fatigue crack propagation.