Open-system degassing of sulfur from Krakatau 1883 magma

We present the first sulfur and oxygen isotopic data for tephra from the catastrophic 1883 eruption of Krakatau. Sulfur isotopic ratios in unaltered Krakatau tephra erupted August 26–27, 1883 are markedly enriched in ³⁴S relative to mantle sulfur. High δ³⁴S values of +6.3 to +16.4‰ can best be explained by open-system or multi-stage degassing of SO₂ from the oxidized rhyodacitic and gray dacitic magmas with ³⁴S enrichment of SO²⁻₄ remaining in the melt. Lower whole-rock δ³⁴S values of +2.6‰ and +4.0‰ in two oxidized gray dacitic samples indicate more primitive subarc mantle sulfur in the 1883 magma chamber. Initial δ³⁴S of the rhyodacitic magma was probably in the +1.5‰ to +4.0‰ range and similar to δ³⁴S values measured in arc volcanic rocks from the Mariana Arc.     

Climate–surface–pore‐water interactions on a salt crusted playa: implications for crust pattern and surface roughness development measured using terrestrial laser scanning

Sodium accumulating playas (also termed sodic or natric playas) are typically covered by polygonal crusts with different pattern characteristics, but little is known about the short‐term (hours) dynamics of these patterns or how pore water may respond to or drive changing salt crust patterning and surface roughness. It is important to understand these interactions because playa‐crust surface pore‐water and roughness both influence wind erosion and dust emission through controlling erodibility and erosivity. Here we present the first high resolution (10^?3 m; hours) co‐located measurements of changing moisture and salt crust topography using terrestrial laser scanning (TLS) and infra‐red imagery for Sua Pan, Botswana. Maximum nocturnal moisture pattern change was found on the crests of ridged surfaces during periods of low temperature and high relative humidity. These peaks experienced non‐elastic expansion overnight, of up to 30 mm and up to an average of 1.5 mm/night during the 39 day measurement period. Continuous crusts however showed little nocturnal change in moisture or elevation. The dynamic nature of salt crusts and the complex feedback patterns identified emphasize how processes both above and below the surface may govern the response of playa surfaces to microclimate diurnal cycles. © 2015 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

High resolution mapping of supra‐glacial drainage pathways reveals link between micro‐channel drainage density,surface roughness and surface reflectance

This paper reports on the use of a small unmanned aerial vehicle (sUAV) carrying a standard compact camera, to construct a high resolution orthomosaic (OM) and digital elevation model (DEM) over the lower reaches of the glacier Midtre Lovénbreen, Svalbard. Structure from Motion (SfM) techniques were used to build the OM and DEM, and together these reveal insights into the nature of supra‐glacial drainage. Major meandering supra‐glacial drainage pathways show clear dynamism, via meander cutoffs and abandoned channels. In addition, the imagery reveals a very extensive network of smaller channels that may well carry substantial amounts of water. This network of channels is in part controlled by the structure of the glacier, but in turn, these channels have a significant impact on the ice surface. Roughness of the ice surface is higher where channels are most extensive. In addition, we find a relationship between channel density and surface reflectance, such that greater channel density is associated with lower reflectance values. Given the role of surface reflectance and roughness in the energy balance of glaciers, it is therefore apparent that extensive networks of small supra‐glacial channels across such glaciers have the potential to have an important impact on energy exchanges between the atmosphere and the ice surface. Copyright © 2015 John Wiley & Sons, Ltd.     

A Permanent Multilevel Monitoring and Sampling System in the Coastal Groundwater Mixing Zones

To study the spatial and temporal variability of water dynamics and chemical reactions within the coastal groundwater mixing zones (CGMZs), high‐resolution periodical and spatial groundwater sampling within CGMZs is needed. However, current samplers and sampling systems may require heavy driving machines to install. There is also possible contamination from the metal materials for current samplers and sampling systems. Here, a permanent multilevel sampling system is designed to sample coastal groundwater within CGMZs. This cost‐effective system consists of metal‐free materials and can be installed easily. The system is tested in Po Sam Pai and Tingkok, Tolo Harbor and Hong Kong. Major ions, nutrients, stable isotopes and radium and radon isotopes were analyzed and the data provided scientific information to study the fresh‐saltwater interface fluctuations, and temporal variations and spatial heterogeneity of geochemical processes occurred within CGMZs. The reliable spatial and temporal data from the sampling system demonstrate that the system functions well and can provide scientific data for coastal aquifer studies.     

An estimation of the average lifetime of the latest model of APEX floats

Estimating the average lifetime of floats is very important for Argo, because the total cost of maintaining the monitoring network largely depends on float lifetime. However, the actual lifetime of floats used in Argo is currently unknown. An estimate can be made by examining past float survival, but this is complicated by floats still operating at sea and continuous improvements in float hardware. Because APEX (Autonomous Profiling Explorer) floats are the most widely deployed type of float in the world oceans, in this study we estimate the lifetime of the latest model of APEX powered by alkaline batteries. The expected lifetime is estimated with a statistical method that allows for floats that are still active and that failed because of a known and now fixed hardware fault that should not cause failure in the latest model of floats. As an example, we analyzed the APEX fleets managed by the Japan Agency for Marine-Earth Science and Technology (JAMSTEC), because we have access to a JAMSTEC database in which the causes of float failure have been carefully correlated to known hardware problems. Analysis of the JAMSTEC fleet (n = 571, as of 7 May 2008) indicated that the expected lifetime of the latest model of APEX is 134.6 (127.6–141.5, considering standard errors) cycles, equivalent to 3.7 years of 10-day cycles. We conclude that the annual deployment of 813 (773–859) APEX floats is needed to maintain the Argo observational network of 3000 floats. Floats with different hardware configurations (e.g., lithium batteries) or different mission programs (e.g., shallower profiling, deeper profiling every several cycles) may be expected to have an even longer lifetime.     

基于Clementine和ULCN2005的月球测图研究

为使用嫦娥一号三线阵光学影像进行月球测图,本文研究月球测图的特殊性问题及其解决方案,提出基于Cle-mentine卫星影像数据和ULCN 2005月球控制网进行月球测图的方法,应用商业数字摄影测量软件和自主研发的辅助软件系统进行了月球测图实验.该实验选择了月球近南极的一块区域(W109.7°～W163.4°,S69.3°～S84.2°,面积约1.5×105km2),采用10个轨道的60景Clementine的UVVIS影像、408个ULCN 2005控制点(其中56个作为检查点)和1 337个连接点,建立该区的DTM和地形图,水平中误差和垂直中误差分别为98.639 m(0.19pixel)和1 003.751 m(1.93pixel).论证基于嫦娥数据生成月球DTM和地形图的可行性.     

The evolution of polycyclic aromatic hydrocarbons under simulated inner asteroid conditions

Large polycyclic aromatic hydrocarbons (PAHs) are an important component of the interstellar medium. PAHs have been identified in the soluble and insoluble matter of carbonaceous chondrites (CCs). Here, we study the evolution of PAHs under conditions relevant to the interiors of asteroids and compare our results to PAHs observed in CCs. We have performed long‐term and short‐term hydrothermal experiments, in which we exposed PAH‐mineral mixture analogs of meteorites to temperature conditions representative of those predicted for asteroids interiors. Our results show that small PAHs with melting points within the aqueous alteration temperature of CCs form carbonaceous spherules in the presence of water. In this work, we describe the microstructure and morphology of these spherules. We discuss the similarities and differences compared to globules isolated from CCs.     

Petrology and oxygen isotopic compositions of calcium‐aluminum‐rich inclusions in primitive CO3.0‐3.1 chondrites

The petrologic and oxygen isotopic characteristics of calcium‐aluminum‐rich inclusions (CAIs) in CO chondrites were further constrained by studying CAIs from six primitive CO3.0‐3.1 chondrites, including two Antarctic meteorites (DOM 08006 and MIL 090010), three hot desert meteorites (NWA 10493, NWA 10498, and NWA 7892), and the Colony meteorite. The CAIs can be divided into hibonite‐bearing inclusions (spinel‐hibonite spherules, monomineralic grains, hibonite‐pyroxene microspherules, and irregular/nodular objects), grossite‐bearing inclusions (monomineralic grains, grossite‐melilite microspherules, and irregular/nodular objects), melilite‐rich inclusions (fluffy Type A, compact type A, monomineralic grains, and igneous fragments), spinel‐pyroxene inclusions (fluffy objects resembling fine‐grained spinel‐rich inclusions in CV chondrites and nodular/banded objects resembling those in CM chondrites), and pyroxene‐anorthite inclusions. They are typically small (98.4 ± 54.4 µm, 1SD) and comprise 1.54 ± 0.43 (1SD) area% of the host chondrites. Melilite in the hot desert and Colony meteorites was extensively replaced by a hydrated Ca‐Al‐silicate during terrestrial weathering and converted melilite‐rich inclusions into spinel‐pyroxene inclusions. The CAI populations of the weathered COs are very similar to those in CM chondrites, suggesting that complete replacement of melilite by terrestrial weathering, and possibly parent body aqueous alteration, would make the CO CAIs CM‐like, supporting the hypothesis that CO and CM chondrites derive from similar nebular materials. Within the CO3.0‐3.1 chondrites, asteroidal alteration significantly resets oxygen isotopic compositions of CAIs in CO3.1 chondrites (?¹⁷O: ?25 to ?2‰) but left those in CO3.0‐3.05 chondrites mostly unchanged (?¹⁷O: ?25 to ?20‰), further supporting the model whereby thermal metamorphism became evident in CO chondrites of petrologic type ≥3.1. The resistance of CAI minerals to oxygen isotope exchange during thermal metamorphism follows in the order: melilite + grossite < hibonite + anorthite < spinel + diopside + forsterite. Meanwhile, terrestrial weathering destroys melilite without changing the chemical and isotopic compositions of melilite and other CAI minerals.