Assessing herbicide concentrations in the saturated and unsaturated zone of a Chalk aquifer in southern England

The behavior of the herbicides isoproturon (IPU) and chlortoluron (CTU) in ground water and shallow unsaturated zone sediments were evaluated at a site situated on the Chalk in southern England. Concentrations of IPU in ground water samples varied from < 0.05 to 0.23 microgram/L over a five-year period of monitoring, and were found to correlate with application of the pesticide. Concentrations of pesticides in ground water samples collected during periods of rising water table were significantly higher than pumped samples and suggest that rapidly infiltrating recharge water contains higher herbicide concentrations than the native ground water. Significant variations in herbicide concentrations were observed over a three-month period in ground water samples collected by an automated system, with concentrations of IPU ranging from 0.1 to 0.5 microgram/L, and concentrations of a recent application of CTU ranging from 0.2 to 0.8 microgram/L. Different extraction methods were used to assess pore water concentrations of herbicides in the unsaturated zone, and samples were analyzed by standard HPLC analysis and immunoassay (ELISA) methods. These data indicated highly variable concentrations of herbicide ranging from 4 to 200 g/ha for HPLC and 0.01 to 0.04 g/ha for ELISA, but indicate a general pattern of decreasing concentrations with depth. The results of this study indicate that transport of IPU and CTU through the unsaturated zone to shallow ground water occurs and that this transport increases immediately following herbicide application. Measured concentrations of herbicides are generally lower than specified by the European Union Drinking Water Directive, but are observed to spike above this limit. These results imply that, while delivery of pesticides to ground water can occur as a result of normal agricultural practices, the impact on potable supplies is likely to be negligible due to the potential for degradation during the relatively long travel time through the unsaturated zone and high degree of dilution that occurs within the aquifer. As a result of the wide variation in concentrations detected by different techniques, it is suggested that for future site investigations more than one sampling strategy be employed to characterize the occurrence of pesticide residues and elucidate the transport mechanisms.     

Reconciling Spectroscopic Electron Temperature Measurements in the Solar Corona with In Situ Charge State Observations

We present new results on the recently discovered 69 ms X-ray pulsar AXS J161730-505505, the sixth youngest example of a rotation-powered pulsar. We have undertaken a comprehensive X-ray-observing campaign of AXS J161730-505505 with the ASCA, BeppoSAX, and RXTE observatories and follow its long-term spin-down history between 1989 and 1999 using these observations and archival Ginga and ASCA data sets. The spin-down is not simply described by a linear function as originally thought, but instead we find evidence of a giant glitch (DeltaP&solm0;P greater, similar10-6) between 1993 August and 1997 September, perhaps the largest yet observed from a young pulsar. The glitch is well described by steps in P and P&d2; accompanied by a persistent P&d3; similar to those seen in the Vela pulsar. The pulse profile of AXS J161730-505505 presents a single asymmetric peak that is maintained over all observation epochs. The energy spectrum is also steady over time, characterized by a highly absorbed power law with a photon index Gamma=1.4+/-0.2, consistent with that found for other young rotation powered pulsars.     

Natural attenuation of septic system nitrogen by anammox

On-site disposal of sewage in septic systems can lead to groundwater plumes with NO(3)(-)-N concentrations exceeding the common drinking water limit of 10 mg/L. Currently, denitrification is considered as the principal natural attenuation process. However, at a large seasonal-use septic system in Ontario (256 campsites), a suboxic zone exists where nitrogen removal of up to 80% occurs including removal of NH(4)(+)-N. This zone has both NO(3)(-)-N and NH(4)(+)-N at >5 mg/L each. In the distal NH(4)(+)-rich zone, NH(4)(+)-N concentrations (8.1 ± 8.0 mg/L) are lower than in the proximal zone (48 ± 36 mg/L) and NH(4)(+)-N is isotopically enriched (concentration-weighted mean δ(15)N of +15.7‰) compared to the proximal zone (+7.8‰). Furthermore, δ(15)N-NH(4)(+) isotopic enrichment increases with depth in the distal zone, which is opposite to what would result if nitrification along the water table zone was the mechanism causing NH(4)(+) depletion. Bacterial community composition was assessed with molecular (DNA-based) analysis and demonstrated that groundwater bacterial populations were predominantly composed of bacteria from two Candidatus genera of the Planctomycetales (Brocadia and Jettenia). Together, these data provide strong evidence that anaerobic ammonium oxidation (anammox) plays an important role in nitrogen attenuation at this site.     

中伊朗盆地库姆组层序充填与新特提斯海演化

中伊朗盆地形成和发展受特提斯洋张力以及阿拉伯板块和伊朗板块边缘聚力的复合控制, 其演化经历了基底裂谷(Z1)、被动边缘(Z2-T2)、裂谷盆地(T3)、弧后前陆(J-N11)、陆内坳陷—挤压改造(N12-Q)等不同阶段, 层序充填包括1个一级层序、3个二级层序, 显示明显的纵向叠加、横向复合的复式特点。作为中伊朗盆地弧后前陆演化阶段沉积产物, 库姆组层序充填总体呈现碳酸盐岩、火山岩-火山碎屑岩、陆源碎屑岩“混积”的特点。库姆组包括S1、S2、S3、S4 4个三级层序, 其充填演化经历了Chattian期、Aquitanian早期、Aquitanian晚期、Burdigalian期4次三级海平面变化事件, 最大海平面时期(mfs)位于Burdigalian早期。     

Oil spill treatment products approval: the UK approach and potential application to the Gulf region

The environmental threat from oil spills remains significant across the globe and particularly in regions of high oil production and transport such as the Gulf. The ultimate damage caused can be limited by mitigation actions that responders deploy. The responsible and appropriate use of oil spill treatment products (e.g. dispersants, sorbents etc.) can offer response options that can result in substantial net environmental benefit. However, the approval and choice of what products to use needs careful consideration. The United Kingdom has had in place a statutory approval scheme for oil spill treatment products for 30 years. It is based on measures of efficiency and environmental acceptability. Two toxicity tests form an integral part of the assessment, the Sea test and the Rocky Shore test, and work on the premise that approved products will not make the situation significantly worse when added to spilled oil. This paper outlines the UK approach and how its rationale might be applied to the approval of products specific for the Gulf region. Issues such as species choice, higher temperatures and salinity and regional environmental conditions are considered.     

Is it possible to assess the ecological status of highly stressed natural estuarine environments using macroinvertebrates indices?

Several biotic indices have been proposed for the assessment of the ecological status of benthic macroinvertebrates in marine waters, although none have been generally accepted. When it comes to assessing highly stressed natural environments, such as estuaries, the controversy and uncertainty is much higher than for any given normal index. In this article, we test the behavior and suitability of different biotic indices proposed under the perspective of the Water Framework Directive (S, H, AMBI, M-AMBI, BQI, W-statistic, Taxonomic distinctness) for the assessment of estuaries in northern Spain. The low species richness and dominance of a few tolerant species in the characteristic community of these estuaries presented a challenge to the application of the biotic indices tested. Combined approaches that integrate different aspects of water quality and ecosystem functionality could increase the reliability of the ecological assessment of these transitional waters.