Deformation structures and an alteration zone linked to deposition of volcanogenic sulphate in an ancient playa (Oligocene of Nebraska, USA)

Historic, sulphur-rich volcanic eruptions have altered global climate for as much as five years, and much larger events are known from the geologic record. At Scotts Bluff, Nebraska, Early Oligocene strata of the lower Arikaree Group contain a tephra bed with abundant calcite pseudomorphs after gypsum. Previous work has shown sulphate from the pseudomorphs in this tephra bears a high ¹⁷O anomaly indicative of oxidation of sulphur gases by ozone or hydrogen peroxide in the atmosphere. Possible sources of the tephra were caldera eruptions at about 28 Ma in the San Juan volcanic field of south-western Colorado (∼500 km SW of the study site) and the eastern Great Basin (∼1000 km WSW). The present sedimentological study shows that tephra and volcanogenic sulphate were deposited and preserved within a small, surface-discharging playa that developed on the irregular upper surface of aeolian siltstones of the subjacent White River Group. Sulphate solutions (including perhaps sulphuric acid) percolated downward within the vadose zone, dissolving early formed smectite cement within underlying volcaniclastic sandstones, reddening these rocks along an irregular alteration front. Preserved fine-scale stratification within the sandstones precludes the possibility that reddening took place during pedogenesis. Displacive growth of gypsum at the playa centre folded tephra beds and forced tephra into underlying sandstones, forming elongate cones. The large mass fraction of gypsum (now replaced by calcite) in the playa sediments suggests a huge, long-distance delivery of sulphate aerosols. Some of the sulphate and tephra may have come from the same eruption, or the fine-grained tephra may simply have aided preservation of dry-fog sulphate derived from an unrelated, effusive eruption of lava.     

DAM IMPACTS ON AND RESTORATION OF AN ALLUVIAL RIVER-RIO GRANDE, NEW MEXICO

1 INTRODUCTION The construction of more than 75,000 dams and reservoirs on rivers in the United States (Graf, 1999) has resulted in alteration of the hydrology, geometry, and sediment flow in many of the river channels downstream of dams. Additionally, hydrologic and geomorphic impacts lead to changes in the physical habitat affecting both the flora and fauna of the riparian and aquatic environments. Legislation for protection of endangered species as well as heightened interest in ma…     

Structure of a silica diagenetic transformation zone: the Gjallar Ridge,offshore Norway

Three‐dimensional seismic data from the Gjallar Ridge were used together with X‐ray diffraction data, scientific boreholes and wireline logs to analyse the seismic structure of a silica diagenetic transformation zone. The following features were identified: (i) an interval some 150 to 300 m thick that contains anomalously high‐amplitude reflections; (ii) a strong reflection event at the top of this interval which cross‐cuts stratigraphy, interpreted as the transformation boundary between opal‐A‐rich and opal‐CT‐rich sediment; (iii) amplitude variations on stratigraphic reflections within the interval, attributed to variations in the proportions of opal‐A and opal‐CT; and (iv) a second, deeper, cross‐cutting reflection event within the interval, interpreted as the transformation boundary between opal‐CT‐rich and quartz‐rich sediment. The base of the interval containing the anomalously high‐amplitude reflections is interpreted as a stratigraphic reflection demarcating the base of the silica‐rich strata. On a stratigraphic reflection within the interval of high amplitudes, roughly circular regions of anomalously high amplitude with diameters of 0·8 to 2·5 km are separated by lower amplitude regions. This pattern is similar to the cells previously identified at the opal‐A to opal‐CT transformation boundary and probably results from more complete transformation of opal‐A to opal‐CT. All of these observations provide the first recognition from seismic data that silica diagenetic transformations are not always narrow boundaries represented by single cross‐cutting seismic reflection events, as implied previously, but can be heterogeneous and hundreds of metres in thickness, as observed at outcrop.     

Pb (II) Sorption with Calcite: A Radiotracer Study

A ²¹⁰Pb radiotracer was used to monitor Pb solid-aqueousphase partitioning in sorption experiments at ambient temperature, pH = 8.2, and atmospheric PCO₂ in 0.15 M NaNO₃ solutions. A 24 h isotherm is linear up to Pb concentrations of 4 × 10^-6 M, above which an increase in slope suggests precipitation. The effect of Pb concentration, calcite loading, and ionic strength on Pb sorption with time was monitored. Sorption kinetics are rapid, followed by a slower sorption step.At a constant calcite loading500 mg L^-1,fractional sorptiondecreases with increasing initialPb concentration. The reverse isobserved for surface coverage, with0.6, 5.6 and 40.2% of availableCa²⁺sites occupied at10^-8,10^-7 and10^-6 MPb after 96 h. At a constant Pb concentration of10^-6 M,fractional sorption increases with increasing particleloading, however surface coverage decrease with72.5 and 22.1%Ca²⁺sites occupied at 100 and200 mg L^-1calcite after 96 h.The adsorption coefficient (K_d) is approximately 10³,increases with initial Pb concentration, but remains unaffected by variable calcite loading. Absence of an ionic strength effect on Pb sorption is interpreted as the dominance of inner-sphere complexation. For desorption experiments conducted over a range of initial sorption times, an average desorption index > 0.8 but < 1 indicates that sorption is largely reversible, but is accompanied by slight incorporation. Solid-solution formation increases with time, as observed by slower initial desorption rates for samples with longer sorption times. These findings indicate that Pb may be effectively sequestered by calcite; however re-release via desorption is likely as Pb does not become significantly incorporated into the mineral structure.     

An Experimental Study of Nepheline-Kalsilite Exsolution

The nepheline-kalsilite exsolution reaction was studied isothermallybetween 400 and 700°C. Under nonaqueous conditions the mechanisminvolves nucleation of kalsilite and growth by diffusion ofthe alkalis. As predicted by simple nucleation theory, the nucleationrate and hence the over-all exsolution rate are strongly dependenton the supersaturation of the nepheline. A decrease in temperatureat constant composition increases the supersaturation and therebythe nucleation rate. This increased nucleation rate is opposedby the decrease in the growth rate due to slower volume diffusion.At a supersaturation of more than 8–10 mole per cent thenumber of nuclei is large and the over-all exsolution rate isdetermined primarily by the growth rate. The activation energyfor growth is 28 kcal/mole. An increase of two kilobars in thehydrostatic pressure has little effect on the kinetics of thereaction. Under nonhydrostatic conditions the exsolution rateincreases significantly because the nucleation rate is faster. Under hydrothermal conditions the ‘exsolution’ rateis approximately two orders of magnitude faster due to a modificationin the mechanism. Partial dissolution of the original solidsolution in distilled water creates a condition of nonequilibriumin which the fluid is sodium-rich. Rapid alkali exchange eliminatesthis condition but produces the equilibrium compositions ofthe solids because kalsilite nucleates and grows in contactwith the fluid. The experimental evidence for this mechanismincludes X-ray diffraction data showing a gradual change inthe composition of the initial supersaturated solid, essentiallyidentical activation energies for growth under aqueous and nonaqueousconditions, and a lower percentage of oxygen isotope exchangethan ‘exsolution’ in the same experiment.     

Managing the transition to climate stabilization

It is becoming increasingly clear that economically efficient climate policies are unlikely to be implemented in the near term. Therefore an analysis is warranted that considers the implications of certain suboptimal transition policies. This analysis constructs a transition scenario based on realistic assumptions about the current trends in policy-making. The transition is examined in the context of varying assumptions about the stringency of the target and the availability of low- or no-carbon energy technologies in the future. In addition to evaluating the effects of suboptimal policies, the transitional analysis offers new insights about the intrinsic uncertainty regarding both the appropriate stabilization target and technology.     

Long-distance transported Pinus pollen as a possible chronostratigraphic marker in the Scottish early postglacial

Peaks of Pinus pollen inseveraldetailed early postglacial (Flandrian) pollen diagrams from western Scotland are interpreted as the result of a change in the prevailing wind direction and intensity during climatic amelioration following the Loch Lomond Stadial (Younger Dryas). This origin implies a degree of syn-chroneity in this palynological feature, which if proven would be valuable in the poorly dated early postglacial. The absence of this palynological feature at many sites may be the result of poor sampling or stratigraphic resolution.     

Low-grade metamorphism

Diagenesis refers to those changes which take place in sediments after sedimentation but before lithification (the conversion to solid rock), while metamorphism is defined as the process whereby alterations to the composition, texture or mineralogy take place in consolidated rocks. However, the boundary between diagenesis and metamorphism is gradual/transitional and somewhat arbitrary; it cannot be sharply defined. A consequence of this is that studies of rocks affected by alteration at low temperatures and pressures have been neglected. Within the last decade, however, more attention has been focused on this type of alteration and significant advances have been made in the field of low-grade metamorphism, particularly over the last five years or so. The Caledonide rocks of Wales have been at the forefront of such investigations.     

Nature and palaeoenvironmental significance of a buried soil sequence from Magilligan Foreland, Northern Ireland

Soil horizons delimit three periods of sand deposition and subsequent topographic stability at Magilligan Foreland, Co. Londonderry. All the deposits are composed of texturally and mineralogically similar material. The earliest topography is a beach ridge plain; podzols cap the ridges and peats occur in the inter-ridge depressions, together comprising a buried palaeocatena. The podzols are visually distinct but chemically and mineralogically immature. Peat and podzol genesis probably began between 3,000 and 2,500 years B.P., and were terminated between c . 1,100 years B.P. and c . 600 years B.P. by burial under an extensive layer of aeolian sand. This sand was eroded to a planar surface before developing a sand-pararendzina, which represents a second period of surface stability. The third deposit, a discontinuous dune sand, is presently also developing a sand-pararendzina. Difficulties of using ¹⁴C dates to erect absolute chronologies are discussed.