MicroRaman spectroscopy of anomalous planar microstructures in quartz from Mt. Oikeyama: Discovery of a probable impact crater in Japan

Abstract– Planar deformation features (PDFs) and planar fractures (PFs) have been found and confirmed by optical microscope observations and microRaman spectroscopy in quartz grains from Mt. Oikeyama (Akaishi Mountains, Central Japan), for which the semicircular topographic feature of the ridge suggests a crater formed by an impact event. According to the optical microscope observations, a low shock pressure (8–10 GPa) is estimated by the occurrence of basal or ω PDFs leading to lack of multiple sets of PDFs. In addition, a new type of planar microstructure was found in several quartz grains. The microRaman characteristics of PDFs in quartz from Mt. Oikeyama show the amorphous state indicating the presence of weak broad bands at 400 and 800 cm^?1 peak positions. These characteristics are indicative of PDFs that are limited to shocked quartz. This indicates an impact origin for distinct planar microstructures in quartz from Mt. Oikeyama.     

Do landslides follow landslides? Insights in path dependency from a multi-temporal landslide inventory

Landslides are a major category of natural disasters, causing loss of lives, livelihoods and property. The critical roles played by triggering (such as extreme rainfall and earthquakes), and intrinsic factors (such as slope steepness, soil properties and lithology) have previously successfully been recognized and quantified using a variety of qualitative, quantitative and hybrid methods in a wide range of study sites. However, available data typically do not allow to investigate the effect that earlier landslides have on intrinsic factors and hence on follow-up landslides. Therefore, existing methods cannot account for the potentially complex susceptibility changes caused by landslide events. In this study, we used a substantially different alternative approach to shed light on the potential effect of earlier landslides using a multi-temporal dataset of landslide occurrence containing 17 time slices. Spatial overlap and the time interval between landslides play key roles in our work. We quantified the degree to which landslides preferentially occur in locations where landslides occurred previously, how long such an effect is noticeable, and how landslides are spatially associated over time. We also investigated whether overlap with previous landslides causes differences in landslide geometric properties. We found that overlap among landslides demonstrates a clear legacy effect (path dependency) that has influence on the landslide affected area. Landslides appear to cause greater susceptibility for follow-up landslides over a period of about 10  years. Follow-up landslides are on average larger and rounder than landslides that do not follow earlier slides. The effect of earlier landslides on follow-up landslides has implications for understanding of the landslides evolution and the assessment of landslide susceptibility.     

Controlled-source marine electromagnetic 2-D modeling gas hydrate studies

Research on gas hydrate has increased recently as an alternative to fossil fuel. This study of marine controlled source electromagnetics (CSEM) is motivated by this increase, particularly in deep waters, and examines representative models. We present 2D models and test their efficacy in detection and characterization of gas hydrates. Earlier modeling studies used a horizontal transmitter to study the CSEM response??two electrical and one magnetic component??for resistive subsurface layers. Here we use six components??three electrical and three magnetic??and show that the proposed method reduces ambiguity in interpretation. Additionally, we show results utilizing the transmitter dipole in a borehole and receivers at the sea bottom. We found that CSEM response from a vertical transmitter helps us characterize resistive layers more confidently than from a transmitter moving horizontally at sea bottom. We conclude that in a complex environment, combining horizontal and vertical movements of the transmitter with sea-bottom receivers helps us delineate the subsurface structure more clearly and may help reduce drilling costs. Our models closely match the gas hydrate region in the Gulf of Mexico??Walker Ridge Block-313. Although this study examines gas hydrate, the methodology is applicable to other areas??for example, in monitoring gas diffusion at subsurface depths, which may help in CO₂ sequestration.     

Impact of model development,calibration and validation decisions on hydrological simulations in West Lake Erie Basin

Watershed simulation models are used extensively to investigate hydrologic processes, landuse and climate change impacts, pollutant load assessments and best management practices (BMPs). Developing, calibrating and validating these models require a number of critical decisions that will influence the ability of the model to represent real world conditions. Understanding how these decisions influence model performance is crucial, especially when making science‐based policy decisions. This study used the Soil and Water Assessment Tool (SWAT) model in West Lake Erie Basin (WLEB) to examine the influence of several of these decisions on hydrological processes and streamflow simulations. Specifically, this study addressed the following objectives (1) demonstrate the importance of considering intra‐watershed processes during model development, (2) compare and evaluated spatial calibration versus calibration at outlet and (3) evaluate parameter transfers across temporal and spatial scales. A coarser resolution (HUC‐12) model and a finer resolution model (NHDPlus model) were used to support the objectives. Results showed that knowledge of watershed characteristics and intra‐watershed processes are critical to produced accurate and realistic hydrologic simulations. The spatial calibration strategy produced better results compared to outlet calibration strategy and provided more confidence. Transferring parameter values across spatial scales (i.e. from coarser resolution model to finer resolution model) needs additional fine tuning to produce realistic results. Transferring parameters across temporal scales (i.e. from monthly to yearly and daily time‐steps) performed well with a similar spatial resolution model. Furthermore, this study shows that relying solely on quantitative statistics without considering additional information can produce good but unrealistic simulations. Copyright © 2015 John Wiley & Sons, Ltd.     

Single-grain OSL dating of glaciofluvial quartz constrains Reid glaciation in NW Canada to MIS 6

Improved chronological control on the penultimate advance of the Cordilleran Ice Sheet in northwest Canada (the Reid glaciation) is required for a better understanding of late Quaternary palaeoclimatic and palaeoenvironmental change in eastern Beringia. However, reliable dating of glaciation events beyond the last glacial maximum is commonly hindered by a lack of directly dateable material. In this study we (i) provide the first combined minimum and maximum age constraint on the Reid glaciation at Ash Bend, its reference locale in the Stewart River valley, northwestern Canadian Cordillera, using single-grain optically stimulated luminescence dating of quartz; and (ii) compare the timing of the Reid glaciation with other penultimate ice sheet advances in the region with the aim of establishing improved glacial reconstructions in eastern Beringia. We obtain ages of 158 ± 18 ka and 132 ± 18 ka for glaciofluvial sands overlying and underlying the Reid till, respectively. These ages indicate that the Reid advance, at its reference locale, occurred during MIS 6. This precludes an earlier MIS 8 age, and suggests that the Reid advance may have been synchronous with the Delta glaciation of central Alaska, and is likely correlative with the Mirror Creek glaciation in southern Yukon.     

A Dutch multi-date land use database: Identification of real and methodological changes

Land cover and land use are important information sources for environmental issues. One of the most important changes at the Earth's surface concerns land cover and land use. Knowledge about the location and type of these changes is essential for environmental modeling and management. Remote sensing data in combination with additional spatial data are recognized as an important source of information to detect these land cover and land use changes.     

Identification of the uranium speciation in an underground acid mine drainage environment

The subsurface acid mine drainage (AMD) environment of an abandoned underground uranium mine in Königstein/Saxony/Germany, currently in the process of remediation, is characterized by low pH, high sulfate concentrations and elevated concentrations of heavy metals, in particular uranium. Acid streamers thrive in the mine drainage channels and are heavily coated with iron precipitates. These precipitates are biologically mediated iron precipitates and related to the presence of Fe-oxidizing microorganisms forming copious biofilms in and on the Fe-precipitates. Similar biomineralisations were also observed in stalactite-like dripstones, called snottites, growing on the gallery ceilings.The uranium speciation in these solutions of underground AMD waters flowing in mine galleries as well as dripping from the ceiling and forming stalactite-like dripstones were studied by time resolved laser-induced fluorescence spectroscopy (TRLFS). The fluorescence lifetime of uranium species in both AMD water environments were best described with a mono-exponential decay, indicating the presence of one major species. The detected positions of the emission bands and by comparing it in a fingerprinting procedure with spectra obtained for acid sulfate reference solutions, in particular Fe(III) - SO₄²⁻ - UO₂²⁺ reference solutions, indicated that the uranium speciation in the AMD environment of Königstein is dominated in the pH range of 2.5-3.0 by the highly mobile aquatic uranium sulfate species UO₂SO_4(aq) and formation of uranium precipitates is rather unlikely as is retardation by sorption processes. The presence of iron in the AMD reduces the fluorescence lifetime of the UO₂SO_4(aq) species from 4.3 μs, found in iron-free uranium sulfate reference solutions, to 0.7 μs observed in both AMD waters of Königstein and also in the iron containing uranium sulfate reference solutions.Colloids were not observed in both drainage water and dripping snottite water as photon correlation spectroscopy analyses and centrifugation experiments at different centrifugal accelerations between 500g and 46000g revealed. Thus transport and uranium speciation at the investigated AMD sites is neither influenced by U(IV) or U(VI) eigencolloids nor by uranium adsorbed on colloidal particles.This study shows that TRLFS is a suitable spectroscopic technique to identify the uranium speciation in bulk solutions of AMD environments.