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Polycyclic aromatic hydrocarbons (PAH) and alkylphenols (AP) that are present in routine discharges of produced water (PW) from the offshore industry continue to cause concern. The suitability of biological methods and chemical based passive samplers to determine exposure to these compounds was tested by deploying them around an oil installation and at reference locations in the North Sea. PAH and AP were analysed either as parent compounds in passive samplers and mussel tissue or as metabolites in fish bile. Generally the pattern of exposure relative to proximity to the discharge was represented by mussels, SPMDs and fish for PAH. Fish and SPMDs showed good correlation for PAH accumulations, whereas some differences were apparent between mussels and SPMDs. POCIS was the only technique tested that could accurately measure the most abundant AP in PW. The advantages of biologically independent measures of exposure for inclusion in discharge monitoring studies are outlined. 相似文献
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Ribeiro AP Figueira RC Martins CC Silva CR França EJ Bícego MC Mahiques MM Montone RC 《Marine pollution bulletin》2011,62(1):192-196
Admiralty Bay (Antarctica) hosts three scientific stations (Ferraz, Arctowski and Macchu Picchu), which require the use of fossil fuel as an energy source. Fossil fuels are also considered the main source of pollution in the area, representing important inputs of major pollutants (organic compounds) and trace metals and metalloids of environmental interest. Accordingly, this work presents the results of As, Cd, Cr, Cu, Ni, Pb and Zn in sediment profiles from Admiralty Bay. The sediment results from Ferraz station were slightly higher than the other sampling sites. The highest contents were observed for Cu and Zn (from 44 to 89 mg kg−1). Otherwise, by using enrichment factors and geochronology analysis, the most relevant enrichment was observed for As in the samples collected close to the Ferraz station, indicating that increasing As content may be associated with the activities associated with this site. 相似文献
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采用地质调查和显微镜下观察方法,研究了辽南小黑山区太古宙岩石组成和构造变形特征。小黑山区太古宙岩石包括上壳岩、古老片麻岩和变基性岩脉,它们在小黑山变质岩体中呈包体出现。上壳岩由黑云变粒岩、条带状闪石磁铁石英岩组成;古老片麻岩为条带状角闪黑云斜长片麻岩、条带状角闪斜长片麻岩,原岩为英云闪长岩;变基性岩脉为斜长角闪岩和角闪石岩。上壳岩堆积之后有英云闪长岩侵位,基性脉侵位于上壳岩和英云闪长岩(古老片麻岩)。小黑山区太古宙岩石经历了2幕变形:D1幕变形主要表现为褶皱构造(DF1)、与褶皱轴面平行的面理(DS1)、矿物线理(DL1);D2幕变形在叠加褶皱作用下形成斜歪倾伏褶皱(DF2),面理和线理不发育。小黑山区太古宙变质岩中发育的变形序列、构造特征、变形特征、变质条件表明,这2幕构造形迹群属于中部构造相。D1幕变形形成逆冲推覆构造,D2幕变形形成第Ⅲ型叠加褶皱,它们都是在同方向的水平挤压应力作用下的产物。 相似文献
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Sundt RC Ruus A Jonsson H Skarphéðinsdóttir H Meier S Grung M Beyer J Pampanin DM 《Marine pollution bulletin》2012,64(1):144-152
Biological markers of produced water (PW) exposure were studied in Atlantic cod (Gadus morhua) in both laboratory and field experiments, using authentic PW from a North Sea oil field. In the laboratory study, the PW exposure yielded significantly elevated levels of metabolites of polycyclic aromatic hydrocarbons (PAHs) and alkylphenols (APs) in bile even at the lowest exposure dose (0.125% PW). Other biomarkers (hepatic CYP1A induction and DNA adduct formation) responded at 0.25% and 0.5% PW concentrations. In the field study, bile metabolite markers and hepatic CYP1A were clearly increased in fish caged close to the PW outfall. Induction of plasma vitellogenin was not found in laboratory or field exposures, suggesting that the levels of oestrogen agonists (such as APs) might not have been sufficient to elicit induction, under the present conditions. The applicability of the biomarkers for use in water column biomonitoring programs is discussed. 相似文献
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The occurrence of persistent organic pollutants (POPs) as polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs) and polybrominated diphenyl ethers (PBDE) in crabs Hepatus pudibundus and Callinectesdanae was assessed from two different places inside of the Santos Bay and Moela Island near one of the most economically important metropolitan areas in Southern Brazil. Among POPs analyzed, ∑PCBs (222-923 ng g(-1)lipid weight) and ∑DDTs (154-410 ng g(-1)lw) exhibited the highest concentrations in the crabs. ∑HCHs ranged from 10.3 to 30.9 ng g(-1)lw and were found in all individuals. Other OCPs found in lower concentration was Mirex (7.6-41.6 ng g(-1)lw) and HCB (5.83-16.9 ng g(-1)lw). ∑PBDEs (24.1 ng g(-1)lw) were only found in one male individual from the species C. danae collected near to the submarine sewage of Santos. Male crabs showed higher POP concentrations than female crabs for those two species. 相似文献
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在缺乏构造迁移情况下,解释地壳中部深成岩体的侵位和上升过程中最使人感兴趣的机理就是底辟作用。不过本文认为这种底辟作用机理的关键问题所在还存在重要分歧。构造研究趋向性的结果就是花岗岩底辟为了上升必须受到充分结晶作用,而机械模式的结果却总结出相矛盾的结论,因为在这种模式中岩浆的上升、岩浆必是重要流体,以达到对流循环的目的。的确,与底辟作用有关的热量逃逸是如此之多以致使整体岩浆上升受到明显限制。这些大不相同观点的出现似乎是反映火山岩上升/侵位在整体上看来具有不同岩相。 相似文献