Using δ15N in Fish Larvae as an Indicator of Watershed Sources of Anthropogenic Nitrogen: Response at Multiple Spatial Scales

There is growing interest in applying ??¹⁵N in biota as an indicator of anthropogenic nutrient inputs to coastal environments because changes in ??¹⁵N correlate to inputs of land-based nutrients. In complex coastal receiving waters, however, land-use effects on biota ??¹⁵N may be masked by local hydrologic processes, especially exchange with coastal waters of different geochemical character. We examined ??¹⁵N differences among larval fish, a novel biotic indicator, in coastal receiving waters at both among and within watershed scales. Our goal was to characterize how hydrologic processes within coastal river mouths and embayments mediate the effect of land-based N sources on larval fish ??¹⁵N. We sampled three Lake Superior river-embayment systems from watersheds that span a large population density gradient. Over all stations, mean fish ??¹⁵N ranged from 2.7??? to 10.8???. Within each system, we found a different pattern in ??¹⁵N across the river?Clake transition zone. Correlations between fish ??¹⁵N and water quality, particularly NH ₄ ⁺ and total nitrogen, were highly significant and corresponded to known differences in sewage waste water inputs. A multivariate model that included both watershed-based population density and NH ₄ ⁺ was found to provide the best fit to the ??¹⁵N data among a series of multi- and univariate candidate models. These results demonstrate that: (1) fish larvae ??¹⁵N responded at within watershed scales, and (2) within coastal receiving waters, fish larvae ??¹⁵N was related to waste water inputs at the watershed scale; however, expression at specific locations within a coastal system was strongly influenced by local hydrologic processes.     

Magnitudes of departures from equilibrium during regional metamorphism of porphyroblastic rocks

Numerical models of diffusion‐controlled nucleation and growth of garnet crystals, which successfully replicate diverse textures in 13 porphyroblastic rocks, yield quantitative estimates of the magnitudes of departures from equilibrium during crystallization. These estimates are derived from differences in chemical potential between subvolumes containing stable product assemblages and those containing persistent but metastable reactant assemblages. The magnitude of disequilibrium is evaluated in terms of the thermal overstepping, which is commonly referenced to the garnet‐in isograd; the reaction affinity in the intergranular fluid at the site and time of each nucleation event, and on average throughout the rock, and the ‘latent energy of reaction’ per unit volume, a measure of the average unreacted capacity of the bulk rock, which describes its overall metastability. Across all of the models, the first crystals nucleate after 5–67 °C of thermal overstepping (correspondingly, 0.7–5.8 kJ mol^?1 of 12‐oxygen garnet); the maximum reaction affinity averaged across the intergranular fluid is between 4.7 and 16.0 kJ mol^?1 of 12‐oxygen garnet; and the maximum latent energy of reaction ranges from 7.3 to 51.7 J cm^?3. These results demonstrate that impediments to crystallization significantly delay nucleation and retard reaction, with the consequence that nucleation of new crystals extends throughout nearly the entire crystallization interval. This potential for protracted reaction during prograde metamorphism, with reactions continuing to temperatures and pressures well beyond equilibrium conditions, suggests the likelihood of overstepping of multiple – possibly competing – reactions that can progress simultaneously. Isograds and ranges of stability for metamorphic assemblages along a metamorphic field gradient may therefore be significantly offset from the positions predicted from calculations based on equilibrium assumptions, which poses a substantial challenge to accurate interpretations of metamorphic conditions and processes.     

Estimating traveler populations at airport and cruise terminals for population distribution and dynamics

In recent years, uses of high-resolution population distribution databases are increasing steadily for environmental, socioeconomic, public health, and disaster-related research and operations. With the development of daytime population distribution, temporal resolution of such databases has been improved. However, the lack of incorporation of transitional population, namely business and leisure travelers, leaves a significant population unaccounted for within the critical infrastructure networks, such as at transportation hubs. This paper presents two general methodologies for estimating passenger populations in airport and cruise port terminals at a high temporal resolution which can be incorporated into existing population distribution models. The methodologies are geographically scalable and are based on, and demonstrate how, two different transportation hubs with disparate temporal population dynamics can be modeled utilizing publicly available databases including novel data sources of flight activity from the Internet which are updated in near-real time. The airport population estimation model shows great potential for rapid implementation for a large collection of airports on a national scale, and the results suggest reasonable accuracy in the estimated passenger traffic. By incorporating population dynamics at high temporal resolutions into population distribution models, we hope to improve the estimates of populations exposed to or at risk to disasters, thereby improving emergency planning and response, and leading to more informed policy decisions.     

Constraints on rigid zones and other distinct layers at the top of the outer core using CMB underside reflected PKKP waves

Clear PKKP, a P wave reflects off the core-mantle boundary on the core side, is recorded by the transcontinental USArray from two deep earthquakes occurred in South America and Tonga, and one intermediate-depth earthquake in the Hindu Kush region. We compare the PKKP waveforms with the direct P waves to investigate the fine structures near the core-mantle boundary, with a primary focus on the core side. We find no evidence for the existence of a sedimentary layer of lighter elements with a thickness above a few hundreds of meters beneath the reflection points of the two deep events, which are located at the Ninety-East Ridge and South Africa. On the other hand the PKKP wave duration of the Hindu Kush event is almost twice as long as that of the P wave, suggesting that multiple reflections may be occurring at the core-mantle boundary located beneath the Antarctic, which is located inside the so-called tangent cylinder of the outer core. The tangent cylinder is an imaginary cylindrical region suggested by geodynamics studies, which has different flow pattern and may have a higher concentration in lighter elements as compared to the rest of the outer core. One possible explanation of the elongated PKKP is a thin distinct layer with a thickness of a few kilometers at the top of the outer core, suggesting that precipitation of lighter elements may occur at the core-mantle boundary. Our data also indicate an extremely low Q_P of 312, approximately 40% of the PREM average (~780), within the large-scale low-velocity anomaly in the lowermost mantle beneath Pacific.     

Explaining global patterns and trends in marine protected area (MPA) development

The relative paucity and heterogeneous distribution of marine protected areas (MPAs) indicates the need for better understanding of factors that foster MPA establishment at local, sub-national, and national levels. The relationship between national-level MPA establishment and geographic, ecological, social, and political factors that may drive patterns and trends in MPA establishment were assessed. A country's coastline length is the strongest predictor of both the number and spatial extent of MPAs. Controlling for coastline, the Human Development Index (HDI) and spatial overlap with designated conservation priority areas are positively correlated with MPA establishment. Surprisingly, some factors influencing MPA establishment in case studies, such as percentage of fishers within a population, were not correlated with MPA establishment on a national scale. These national dynamics explain a relatively small proportion of variation, however, indicating that other biological or social factors, as well as sub-national processes, also influence MPA establishment. Positive and negative outliers illuminate the importance of policy engagement at both national and local levels. Ensuring a supportive enabling environment at the national or even multi-national level can enhance success at the local level.     

Effect of 3-D viscoelastic structure on post-seismic relaxation from the 2004 M= 9.2 Sumatra earthquake

The 2004 M = 9.2 Sumatra–Andaman earthquake profoundly altered the state of stress in a large volume surrounding the ∼1400 km long rupture. Induced mantle flow fields and coupled surface deformation are sensitive to the 3-D rheology structure. To predict the post-seismic motions from this earthquake, relaxation of a 3-D spherical viscoelastic earth model is simulated using the theory of coupled normal modes. The quasi-static deformation basis set and solution on the 3-D model is constructed using: a spherically stratified viscoelastic earth model with a linear stress–strain relation; an aspherical perturbation in viscoelastic structure; a 'static' mode basis set consisting of Earth's spheroidal and toroidal free oscillations; a "viscoelastic" mode basis set; and interaction kernels that describe the coupling among viscoelastic and static modes. Application to the 2004 Sumatra–Andaman earthquake illustrates the profound modification of the post-seismic flow field at depth by a slab structure and similarly large effects on the near-field post-seismic deformation field at Earth's surface. Comparison with post-seismic GPS observations illustrates the extent to which viscoelastic relaxation contributes to the regional post-seismic deformation.     

An early Paleogene sponge fauna,Chatham Island,New Zealand

A late Paleocene‐early Eocene (c. 60–53 Ma) poriferan fauna, comprising hexactinellids (Class Hexactinellida), astrophorids (Class Demospongiae: Family Astrophorida), and lithistids ("lithistid” Demospongiae) has been identified from the Tutuiri Greensand outcropping on the north coast of Chatham Island, New Zealand. Most of the fossils are hexactinellids, comprising extremely delicate siliceous networks embedded in friable sandstone. The sediment matrix within and around these skeletons contains numerous siliceous demosponge spicules, many of which are exceptionally well preserved. The soft friable matrix of the Tutuiri Greensand has made extraction a relatively simple process, making taxonomic identification of the material, and comparison with adjacent Recent and other New Zealand Eocene faunas possible. These sponge body fossils and spicule microfossils indicate a fauna that was once dominated by hexactinellids, lithistid, and astrophorid demosponges. A qualitative comparison of the abundance and diversity of the Tutuiri Greensand sponge fauna with the present‐day Chatham Rise sponge fauna indicates that the late Paleocene‐early Eocene fauna is as diverse as the Recent fauna, for the hexactinellid sponges and astrophorid demosponges, and much more diverse for lithistid sponges. The paleoecology of the Tutuiri Greensand has been interpreted as inner to mid shelf water depths (50–250 m) but the poriferan fauna described here is more like that of the present‐day soft sediment benthic environment of the Chatham Rise at 800–1200 m.     

New insights into slide processes and seafloor geology revealed by side-scan imagery of the massive Hinlopen Slide, Arctic Ocean margin

The submarine Hinlopen Slide, located along the Arctic Ocean margin, is one of the largest known mass movements on Earth. The slide scar has several unusual morphometric characteristics, including headwalls up to 1,500 m high and spectacularly large, steep-sided rafted megablocks. The slide processes and continental margin properties that produced these features are not well known. A new high-resolution TOBI (towed ocean bottom instrument) side-scan sonar dataset reveals information about the detailed seafloor morphology and, therefore, slide dynamics during the final stages of sliding. First, the headwall area was efficiently and almost completely evacuated of slide debris, which is unusual for large submarine slides. Second, features relating to the propagation of extension to the shelf behind the headwall are absent, suggesting “strong” cohesive shelf material here or that a very stable shelf configuration was reached, possibly defined by NE-SW-trending faults. Third, there is little evidence for the translation of shelf material, again uncommon for submarine slides. Taken together with the occurrence of massive megablocks in the slide debris, Hinlopen Slide is distinct because of the juxtaposition of apparently “stronger” shelf material that has remained intact (headwalls, megablocks), and “weaker” shelf material that disaggregated fully during slope failure. Nevertheless, there is sonograph evidence of variable post-slide disintegration of the megablocks. Contrary to previous interpretations, this suggests that the blocks comprise sedimentary lithologies that are prone to failure, a key aspect awaiting confirmation.