Biotite and garnet compositional variation and mineral equilibria in Grenville gneisses of the Otter Lake area, Quebec

Garnet-biotite gneisses, some of which contain sillimanite or hornblende, are widespread within the Otter Lake terrain, a portion of the Grenville Province of the Canadian Shield. The metamorphic grade is upper amphibolite to, locally, lower granulite facies. The atomic ratio Fe²⁺/(Fe²⁺+ Fe³⁺) in biotite ranges from 0.79 to 0.89 (ferrous iron determinations in 10 highly pure separates), with a mean of 0.86. Mg and Fe²⁺ atoms occupy 67–78% of the octahedral sites, the remainder are occupied by Fe³⁺, Ti, and Al, and some are vacant. Mg/(Mg + Fe²⁺), denoted X, in the analysed samples ranges from 0.32 to 0.65. Garnet contains 1–24% grossular, 1–12% spessartine and X ranges from 0.07 to 0.34. Compositional variation in biotite and garnet is examined in relation to three mineral equilibria: (I) biotite + sillimanite + quartz = garnet + K-feldspar + H₂O; (II) pyrope + annite = almandine + phlogopite; (III) anorthite = grossular + sillimanite + quartz. Measurements of X (biotite) and X (garnet) are used to construct an illustrative model for equilibrium (I) which relates the observed variation in X to a temperature range of 70°C or a range in H₂O activity of 0.6; the latter interpretation is preferred. In sillimanite-free gneisses, the distribution of Mg and Fe²⁺ between garnet (low in Ca and Mn) and biotite is adequately described by a distribution coefficient (KD) of 4.1 (equilibrium II). The observed increase in the distribution coefficient with increasing Ca in garnet is ln K_D= 1.3 + 2.5 × 10^?2 [Ca] where [Ca] = 100 Ca/(Mg + Fe²⁺+ Mn + Ca). The distribution coefficient is apparently unaffected by the presence of up to 12% spessartine in garnet. In several specimens of garnet-sillimanite-plagioclase gneiss, the Ca contents of garnet and of plagioclase increase in unison, as required by equilibrium (III). The mean pressure calculated from these data (n= 17) is 5.9 kbar, and the 95% confidence limits are ±0.5 kbar.     

Application of Advanced Analytics and Visualization in Mineral Systems

正The key to answering many compelling and complex questions in Earth,planetary,and life science lies in breaking down the barriers between scientific fields and harnessing the integrated,multi-disciplinary power of Earth,planetary,and bioscience data resources.We have a unique opportunity to integrate large and rapidly expanding"big data"resources,to enlist powerful analytical and visualization methods,and to answer multi-disciplinary questions that cannot be addressed by one field alone.     

Spectral surface albedo over Morocco and its impact on radiative forcing of Saharan dust

In May–June 2006, airborne and ground-based solar (0.3–2.2 μm) and thermal infrared (4–42 μm) radiation measurements have been performed in Morocco within the Saharan Mineral Dust Experiment (SAMUM). Upwelling and downwelling solar irradiances have been measured using the Spectral Modular Airborne Radiation Measurement System (SMART)-Albedometer. With these data, the areal spectral surface albedo for typical surface types in southeastern Morocco was derived from airborne measurements for the first time. The results are compared to the surface albedo retrieved from collocated satellite measurements, and partly considerable deviations are observed. Using measured surface and atmospheric properties, the spectral and broad-band dust radiative forcing at top-of-atmosphere (TOA) and at the surface has been estimated. The impact of the surface albedo on the solar radiative forcing of Saharan dust is quantified. In the SAMUM case of 19 May 2006, TOA solar radiative forcing varies by 12 W m⁻² per 0.1 surface-albedo change. For the thermal infrared component, values of up to +22 W m⁻² were derived. The net (solar plus thermal infrared) TOA radiative forcing varies between −19 and +24 W m⁻² for a broad-band solar surface albedo of 0.0 and 0.32, respectively. Over the bright surface of southeastern Morocco, the Saharan dust always has a net warming effect.     

CLIMATIC CHANGE AND DEBRIS FLOWS IN HIGH MOUNTAIN REGIONS: THE CASE STUDY OF THE RITIGRABEN TORRENT (SWISS ALPS)

Debris flows in the region of Ritigraben (Valais, Swiss Alps), which generally occur in the months of August and September, have been analyzed in relation to meteorological and climatic factors. The principal trigger mechanisms for such debris flows are abundant rain on the one hand, and snow-melt and runoff on the other hand, or a combination of both. Debris flows linked to rain are likely to be triggered when total rainfall amount over a three-day period exceeds four standard deviations, i.e., a significant extreme precipitation event. An analysis of climatological data for the last three decades in the region of Ritigraben has highlighted the fact that the number of extreme rainfall events capable of triggering debris flows in August and September has increased. Similar trends are observed for the 20th Century in all regions of Switzerland. The general rise in temperature in a region of permafrost may also play a role in the response of slope stability to extreme precipitation. At the foot of the Ritigraben, warming trends of both minimum and maximum temperatures have been particularly marked in the last two decades.     

Climate effects on atmospheric carbon dioxide over the last century

The buildup of atmospheric CO₂ since 1958 is surprisingly well explained by the simple premise that 57% of the industrial emissions (fossil fuel burning and cement manufacture) has remained airborne. This premise accounts well for the rise both before and after 1980 despite a decrease in the growth rate of fossil fuel CO₂ emissions, which occurred at that time, and by itself should have caused the airborne fraction to decrease. In contrast, the buildup prior to 1958 was not simply proportional to cumulative fossil fuel emissions, and notably included a period during the 1940s when CO₂ growth stalled despite continued fossil fuel emissions. Here we show that the constancy of the airborne fraction since 1958 can be in part explained by decadal variations in global land air temperature, which caused a warming-induced release of CO₂ from the land biosphere to the atmosphere. We also show that the 1940s plateau may be related to these decadal temperature variations. Furthermore, we show that there is a close connection between the phenomenology producing CO₂ variability on multidecadal and El Niño timescales.     

Basic types of stratification in small eolian dunes

The thinnest recognizable strata in modern eolian dune sands can be grouped into six classes. They are herein named planebed laminae, rippleform laminae, ripple-foreset crosslaminae, climbing translatent strata, grainfall laminae, and sandflow cross-strata. Planebed laminae are formed by tractional deposition on smooth surfaces at high wind velocities. They are very rare in the deposits studied. Grainfall laminae are also formed on smooth surfaces, largely by grainfall deposition in zones of flow separation. They are much more common than planebed laminae, which they closely resemble. Eolian climbing-ripple structures are composed primarily of climbing trans-latent strata, each of which is the depositional product of a single climbing ripple. Climbing translatent strata that formed at relatively high or supercritical angles of ripple climb are typically accompanied by rippleform laminae, which are wavy layers parallel to the rippled depositional surfaces. Ripple-foreset crosslaminae, which are incomplete rippleform laminae produced when the angle of ripple climb is relatively low or subcritical, are rarely visible in eolian sands. Sandflow cross-strata are formed by the avalanching of noncohesive sand on dune slipfaces. Their form varies with slipface height and with other factors.     

Bedform climbing in theory and nature

Where bedforms migrate during deposition, they move upward (climb) with respect to the generalized sediment surface. Sediment deposited on each lee slope and not eroded during the passage of a following trough is left behind as a cross-stratified bed. Because sediment is thus transferred from bedforms to underlying strata, bedforms must decrease in cross-sectional area or in number, or both, unless sediment lost from bedforms during deposition is replaced with sediment transported from outside the depositional area. Where sediment is transported solely by downcurrent migration of two-dimensional bedforms, the mean thickness of cross-stratified beds is equal to the decrease in bedform cross-sectional area divided by the migration distance over which that size decrease occurs; where bedforms migrate more than one spacing while depositing cross-strata, bed thickness is only a fraction of bedform height. Equations that describe this depositional process explain the downcurrent decrease in size of tidal sand waves in St Andrew Bay, Florida, and the downwind decrease in size of transverse aeolian dunes on the Oregon coast. Using the same concepts, dunes that deposited the Navajo, De Chelly, and Entrada Sandstones are calculated to have had mean heights between several tens and several hundreds of metres.