TRACING BY GRAVITY OF A NARROW BURIED GRABEN STRUCTURE,DETECTED BY SEISMIC REFRACTION,FOR GROUND-WATER INVESTIGATIONS IN NORTH CHILE*

In the Andes mountains of North Chile seismic refraction measurements revealed the existence of a buried graben structure. The special geological environment permitted the deduction, by detailed analyses of diffraction patterns and delayed arrival times, of a low velocity layer underneath a high velocity ignimbritic sheet. The gravity method was chosen as an economic secondary aid to trace the course of the buried structure. This unusual combination of detailed gravity measurements following a general seismic survey was not only successful in detecting and tracing a buried structure, but also provided complementary data about the deeper subsurface conditions.     

Temporal variability in the maternal environment and its effect on seed size and seed quality in Flourensia cernua DC. (Asteraceae).

The biological phenomenon commonly referred to as maternal effect occurs whenever the environment exerts an influence upon the mother that is later expressed in characteristics of her offsprings. For example, the environmental conditions experienced by a mother plant during flowering and fruiting can modify the quality of her descendants (seeds), and even interrupt their development. Between-year variation in minimum temperature and the classic, between-year variation in precipitation represent an unpredictable environment for winter blooming plants in arid zones. In this study, we investigated the effect of maternal environment (temperature and precipitation) on seed size and seed quality in F. cernua, over a 5-year period. Results indicated that the proportion of filled seeds, as well as their size, increased with higher absolute minimum temperatures during seed formation, and that, to a lesser extent, both the precipitation occurred during the same period and the annual precipitation also have a positive influence on seed size. In this way, environmental conditions prevailing during seed formation exerted a strong maternal effect on the size and quality of seeds produced and, probably also, in the developmental possibilities of F. cernua seedlings. This effect was subject to important, between-year variation.     

The British Tertiary igneous province: palaeomagnetism of the dyke swarm along the Sleat coast of Skye

Summary. A palaeomagnetic investigation has been made of a swarm of more than 400 dykes along the south coast of Skye, Scotland, by the Sound of Sleat.
Seven red lamprophyre dykes have palaeomagnetic directions inconsistent with Tertiary age, and not inconsistent with their previously held Caledonian age. The remaining 409 dykes have palaeomagnetic directions that are consistent with a Lower Tertiary age. We present evidence suggesting that the Tertiary dykes might have been emplaced during a short time, over which the geomagnetic polarity occupied as few as three polarity intervals (NRN or RNR).
Certain 'intermediate' directions of magnetization have also been found, and are presented here.     

Effects of grazing by Daphnia on algal carotenoids: Implications for paleolimnology

Reverse-phase thin layer chromatography was used to quantify algal carotenoid degradation resulting from grazing by Daphnia magna in suspensions of lyophilized Oscillatoria utermöhlii, O. limnetica, Anabaena flos-aquae and Synechococcus sp. Three samples were removed every 24 h from 0 h to 144 h and the carotenoid, carbon and nitrogen content of the remaining algal-fecal mixture was determined. Grazing by Daphnia reduced carotenoid concentrations by 30%–80% after 144 h, with myxoxanthophyll being the most labile pigment in experiments with filamentous cyanophytes. However, as a group, the carotenoids were more resistant to the combined effects of grazing by Daphnia and bacterial action than were particulate algal carbon (78% to 82% lost by 144 h) or nitrogen (86%–90%) during the period in which easily digestible material remained. The maximal extent of carotenoid enrichment relative to particulate carbon ranged from 150% to 300% of initial pigment concentrations but declined with repeated coprophagy. On the basis of these results and published pigment budgets, we conclude both that fecal transportation of pigments may be an important determinant of carotenoid accumulation rates and that carotenoid stratigraphies should record predator-mediated changes in zooplankton community structure, especially in oligotrophic conditions.     

Space-time interaction amongst clusters of mining induced seismicity

Elementary cluster analysis of induced seismicity in a South African gold mine has shown that there is a clear interaction amongst the clusters; and that the level of the interaction is a function of the distance. The clusering algorithm used is an adaptation of the single-link cluster analysis which considers both three-dimensional space and time. A high level of interaction between the clusters is demonstrated from the cross-correlation analysis of seismic activity rates and radiated energy. A distinct decrease in the value of correlation coefficients was detectable as distance increased. This was somewhat surprising, considering the simplicity of the technique used. Since no attempt is made to study the physical mechanisms of interaction, these results are very preliminary, but interesting from an observational point of view.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.